Investigação dos efeitos das impurezas alcalinas e hidrogênio no quartzo submetido à eletrodifusão e radiação ionizante

• Autor(a) principal: Rosa, Rafael Augusto dos Anjos [UNESP]
• Data de Publicação: 2014
• Tipo de documento: Dissertação
• Idioma: por
• Título da fonte: Repositório Institucional da UNESP
• Texto Completo: http://hdl.handle.net/11449/113853
• topic: Quartzo; Eletrolise; Radiação ionizante; Fourier, Espectroscopia de infravermelho por transformada de; Espectroscopia de ultravioleta; Electrolysis

In the present study, we investigated the effects of alkali ions Na+ , Li+ replaced by ion H+ and Na+ in the center related to the aluminum that is a found naturally in motrices natural quartz. Measurements of optical absorption in the visible and ultraviolet region and measures infrared samples of natural quartz that have passed or not by electrodiffusion process were performed. An effect of browning in citrine quartz was investigated when exposed to the sun , correlating with the centers studied in this work, [ AlO4/H]0 , [ Li-OH ] and [Na-OH] , identifiable in the infrared region in the centers [AlO4]0 and E’ that are identifiable in the optical absorption spectrum. The existence of such centers, centers called impurities is facilitated by the presence of a structural channel quartz, which allows the entry of ions such as substitutional Al3+ substitutional and interstitial as Na+, Li+ and H+ along the crystal quartz chain . The samples were submitted to gamma radiation dose of approximately 20kGy , the outcome was analyzed based on the centers and the effects of electrodiffusion were analyzed by spectroscopy, UV- Vis and IR region. Infrared analysis indicated that the hydrogen electrodiffusion in citrine and hyaline quartz was successful , since there is an increase in the center [AlO4/H]0 and a decrease in the [Li-OH] , located in the band at 3484cm -1. The interaction between gamma radiation and quartz causes the centers related to the presence of hydrogen with aluminum increase , because the radiation to excite the atoms of the quartz network ultimately directly affect the centers whose compesator load are the alkali atoms Li+ , Na+ and K+ center [AlO4/M]0 , then there is compensation for hydrogen atoms , thus forming more centers [AlO4/H]0 . The appearance of bands at 430 and 620 nm associated to the center [AlO4]0 in the citrine and hyaline quatz after irradiation, enables us to state that ...