Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1007/s10854-020-04244-3 http://hdl.handle.net/11449/199311 |
Resumo: | In the current study, the synthesis of hematite (α-Fe2O3) at different temperatures (750 and 900 °C), and reduced graphene oxide (rGO), obtained from an adaptation to the Hummers’s method, was evaluated. These materials were characterized by X-ray diffraction, Raman spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, among others. The deposition of samples on the conductive surface of tin-doped indium oxide coated glass substrate, was performed by the Layer-by-Layer technique. The films were prepared with 1- and 4-bilayers α-Fe2O3, using a cationic polyelectrolyte diallyldimethylammonium chloride (PDDA) or rGO. It was observed that the rGO/α-Fe2O3 films presented higher photocurrent and less resistivity when compared to the PDDA/α-Fe2O3 films. The largest photocurrent was obtained with the 4-bilayers rGO/α-Fe2O3 at 900 °C film, with 2.15 µA cm−2. In addition, a kinetic study for photoelectrocatalytic decolorization of the methylene blue dye under visible light was performed. The electrode that showed the greatest photoelectroactivity was the 4-bilayers rGO/α-Fe2O3 at 900 °C film, resulting in kobs = 11.90 × 10−3 min−1 and about 78% decolorization after 120 min. |
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Repositório Institucional da UNESP |
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spelling |
Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysisIn the current study, the synthesis of hematite (α-Fe2O3) at different temperatures (750 and 900 °C), and reduced graphene oxide (rGO), obtained from an adaptation to the Hummers’s method, was evaluated. These materials were characterized by X-ray diffraction, Raman spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, among others. The deposition of samples on the conductive surface of tin-doped indium oxide coated glass substrate, was performed by the Layer-by-Layer technique. The films were prepared with 1- and 4-bilayers α-Fe2O3, using a cationic polyelectrolyte diallyldimethylammonium chloride (PDDA) or rGO. It was observed that the rGO/α-Fe2O3 films presented higher photocurrent and less resistivity when compared to the PDDA/α-Fe2O3 films. The largest photocurrent was obtained with the 4-bilayers rGO/α-Fe2O3 at 900 °C film, with 2.15 µA cm−2. In addition, a kinetic study for photoelectrocatalytic decolorization of the methylene blue dye under visible light was performed. The electrode that showed the greatest photoelectroactivity was the 4-bilayers rGO/α-Fe2O3 at 900 °C film, resulting in kobs = 11.90 × 10−3 min−1 and about 78% decolorization after 120 min.Departamento de Química Universidade Estadual de LondrinaInstituto de Química Universidade de São PauloColégio Técnico Industrial Faculdade de Engenharia Universidade Estadual Paulista (UNESP)Departamento de Física Universidade Estadual de LondrinaColégio Técnico Industrial Faculdade de Engenharia Universidade Estadual Paulista (UNESP)Universidade Estadual de Londrina (UEL)Universidade de São Paulo (USP)Universidade Estadual Paulista (Unesp)Leão-Neto, Vanildo Souzada Silva, Aruã ClaytonCamargo, Luan PereiraDa Silva Pelissari, Marcelo Rodrigues [UNESP]da Silva, Paulo Rogério CatariniParreira, Paulo SergioSegatelli, Mariana GavaDall′Antonia, Luiz Henrique2020-12-12T01:36:23Z2020-12-12T01:36:23Z2020-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1007/s10854-020-04244-3Journal of Materials Science: Materials in Electronics.1573-482X0957-4522http://hdl.handle.net/11449/19931110.1007/s10854-020-04244-32-s2.0-85089959063Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Materials Science: Materials in Electronicsinfo:eu-repo/semantics/openAccess2021-10-23T07:07:20Zoai:repositorio.unesp.br:11449/199311Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462021-10-23T07:07:20Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis |
title |
Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis |
spellingShingle |
Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis Leão-Neto, Vanildo Souza |
title_short |
Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis |
title_full |
Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis |
title_fullStr |
Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis |
title_full_unstemmed |
Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis |
title_sort |
Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis |
author |
Leão-Neto, Vanildo Souza |
author_facet |
Leão-Neto, Vanildo Souza da Silva, Aruã Clayton Camargo, Luan Pereira Da Silva Pelissari, Marcelo Rodrigues [UNESP] da Silva, Paulo Rogério Catarini Parreira, Paulo Sergio Segatelli, Mariana Gava Dall′Antonia, Luiz Henrique |
author_role |
author |
author2 |
da Silva, Aruã Clayton Camargo, Luan Pereira Da Silva Pelissari, Marcelo Rodrigues [UNESP] da Silva, Paulo Rogério Catarini Parreira, Paulo Sergio Segatelli, Mariana Gava Dall′Antonia, Luiz Henrique |
author2_role |
author author author author author author author |
dc.contributor.none.fl_str_mv |
Universidade Estadual de Londrina (UEL) Universidade de São Paulo (USP) Universidade Estadual Paulista (Unesp) |
dc.contributor.author.fl_str_mv |
Leão-Neto, Vanildo Souza da Silva, Aruã Clayton Camargo, Luan Pereira Da Silva Pelissari, Marcelo Rodrigues [UNESP] da Silva, Paulo Rogério Catarini Parreira, Paulo Sergio Segatelli, Mariana Gava Dall′Antonia, Luiz Henrique |
description |
In the current study, the synthesis of hematite (α-Fe2O3) at different temperatures (750 and 900 °C), and reduced graphene oxide (rGO), obtained from an adaptation to the Hummers’s method, was evaluated. These materials were characterized by X-ray diffraction, Raman spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, among others. The deposition of samples on the conductive surface of tin-doped indium oxide coated glass substrate, was performed by the Layer-by-Layer technique. The films were prepared with 1- and 4-bilayers α-Fe2O3, using a cationic polyelectrolyte diallyldimethylammonium chloride (PDDA) or rGO. It was observed that the rGO/α-Fe2O3 films presented higher photocurrent and less resistivity when compared to the PDDA/α-Fe2O3 films. The largest photocurrent was obtained with the 4-bilayers rGO/α-Fe2O3 at 900 °C film, with 2.15 µA cm−2. In addition, a kinetic study for photoelectrocatalytic decolorization of the methylene blue dye under visible light was performed. The electrode that showed the greatest photoelectroactivity was the 4-bilayers rGO/α-Fe2O3 at 900 °C film, resulting in kobs = 11.90 × 10−3 min−1 and about 78% decolorization after 120 min. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-12-12T01:36:23Z 2020-12-12T01:36:23Z 2020-01-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1007/s10854-020-04244-3 Journal of Materials Science: Materials in Electronics. 1573-482X 0957-4522 http://hdl.handle.net/11449/199311 10.1007/s10854-020-04244-3 2-s2.0-85089959063 |
url |
http://dx.doi.org/10.1007/s10854-020-04244-3 http://hdl.handle.net/11449/199311 |
identifier_str_mv |
Journal of Materials Science: Materials in Electronics. 1573-482X 0957-4522 10.1007/s10854-020-04244-3 2-s2.0-85089959063 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Journal of Materials Science: Materials in Electronics |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1799964441380388864 |