Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis

Detalhes bibliográficos
Autor(a) principal: Leão-Neto, Vanildo Souza
Data de Publicação: 2020
Outros Autores: da Silva, Aruã Clayton, Camargo, Luan Pereira, Da Silva Pelissari, Marcelo Rodrigues [UNESP], da Silva, Paulo Rogério Catarini, Parreira, Paulo Sergio, Segatelli, Mariana Gava, Dall′Antonia, Luiz Henrique
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1007/s10854-020-04244-3
http://hdl.handle.net/11449/199311
Resumo: In the current study, the synthesis of hematite (α-Fe2O3) at different temperatures (750 and 900 °C), and reduced graphene oxide (rGO), obtained from an adaptation to the Hummers’s method, was evaluated. These materials were characterized by X-ray diffraction, Raman spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, among others. The deposition of samples on the conductive surface of tin-doped indium oxide coated glass substrate, was performed by the Layer-by-Layer technique. The films were prepared with 1- and 4-bilayers α-Fe2O3, using a cationic polyelectrolyte diallyldimethylammonium chloride (PDDA) or rGO. It was observed that the rGO/α-Fe2O3 films presented higher photocurrent and less resistivity when compared to the PDDA/α-Fe2O3 films. The largest photocurrent was obtained with the 4-bilayers rGO/α-Fe2O3 at 900 °C film, with 2.15 µA cm−2. In addition, a kinetic study for photoelectrocatalytic decolorization of the methylene blue dye under visible light was performed. The electrode that showed the greatest photoelectroactivity was the 4-bilayers rGO/α-Fe2O3 at 900 °C film, resulting in kobs = 11.90 × 10−3 min−1 and about 78% decolorization after 120 min.
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spelling Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysisIn the current study, the synthesis of hematite (α-Fe2O3) at different temperatures (750 and 900 °C), and reduced graphene oxide (rGO), obtained from an adaptation to the Hummers’s method, was evaluated. These materials were characterized by X-ray diffraction, Raman spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, among others. The deposition of samples on the conductive surface of tin-doped indium oxide coated glass substrate, was performed by the Layer-by-Layer technique. The films were prepared with 1- and 4-bilayers α-Fe2O3, using a cationic polyelectrolyte diallyldimethylammonium chloride (PDDA) or rGO. It was observed that the rGO/α-Fe2O3 films presented higher photocurrent and less resistivity when compared to the PDDA/α-Fe2O3 films. The largest photocurrent was obtained with the 4-bilayers rGO/α-Fe2O3 at 900 °C film, with 2.15 µA cm−2. In addition, a kinetic study for photoelectrocatalytic decolorization of the methylene blue dye under visible light was performed. The electrode that showed the greatest photoelectroactivity was the 4-bilayers rGO/α-Fe2O3 at 900 °C film, resulting in kobs = 11.90 × 10−3 min−1 and about 78% decolorization after 120 min.Departamento de Química Universidade Estadual de LondrinaInstituto de Química Universidade de São PauloColégio Técnico Industrial Faculdade de Engenharia Universidade Estadual Paulista (UNESP)Departamento de Física Universidade Estadual de LondrinaColégio Técnico Industrial Faculdade de Engenharia Universidade Estadual Paulista (UNESP)Universidade Estadual de Londrina (UEL)Universidade de São Paulo (USP)Universidade Estadual Paulista (Unesp)Leão-Neto, Vanildo Souzada Silva, Aruã ClaytonCamargo, Luan PereiraDa Silva Pelissari, Marcelo Rodrigues [UNESP]da Silva, Paulo Rogério CatariniParreira, Paulo SergioSegatelli, Mariana GavaDall′Antonia, Luiz Henrique2020-12-12T01:36:23Z2020-12-12T01:36:23Z2020-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1007/s10854-020-04244-3Journal of Materials Science: Materials in Electronics.1573-482X0957-4522http://hdl.handle.net/11449/19931110.1007/s10854-020-04244-32-s2.0-85089959063Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Materials Science: Materials in Electronicsinfo:eu-repo/semantics/openAccess2021-10-23T07:07:20Zoai:repositorio.unesp.br:11449/199311Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462021-10-23T07:07:20Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis
title Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis
spellingShingle Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis
Leão-Neto, Vanildo Souza
title_short Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis
title_full Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis
title_fullStr Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis
title_full_unstemmed Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis
title_sort Fabrication of rGO/α-Fe2O3 electrodes: characterization and use in photoelectrocatalysis
author Leão-Neto, Vanildo Souza
author_facet Leão-Neto, Vanildo Souza
da Silva, Aruã Clayton
Camargo, Luan Pereira
Da Silva Pelissari, Marcelo Rodrigues [UNESP]
da Silva, Paulo Rogério Catarini
Parreira, Paulo Sergio
Segatelli, Mariana Gava
Dall′Antonia, Luiz Henrique
author_role author
author2 da Silva, Aruã Clayton
Camargo, Luan Pereira
Da Silva Pelissari, Marcelo Rodrigues [UNESP]
da Silva, Paulo Rogério Catarini
Parreira, Paulo Sergio
Segatelli, Mariana Gava
Dall′Antonia, Luiz Henrique
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade Estadual de Londrina (UEL)
Universidade de São Paulo (USP)
Universidade Estadual Paulista (Unesp)
dc.contributor.author.fl_str_mv Leão-Neto, Vanildo Souza
da Silva, Aruã Clayton
Camargo, Luan Pereira
Da Silva Pelissari, Marcelo Rodrigues [UNESP]
da Silva, Paulo Rogério Catarini
Parreira, Paulo Sergio
Segatelli, Mariana Gava
Dall′Antonia, Luiz Henrique
description In the current study, the synthesis of hematite (α-Fe2O3) at different temperatures (750 and 900 °C), and reduced graphene oxide (rGO), obtained from an adaptation to the Hummers’s method, was evaluated. These materials were characterized by X-ray diffraction, Raman spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, among others. The deposition of samples on the conductive surface of tin-doped indium oxide coated glass substrate, was performed by the Layer-by-Layer technique. The films were prepared with 1- and 4-bilayers α-Fe2O3, using a cationic polyelectrolyte diallyldimethylammonium chloride (PDDA) or rGO. It was observed that the rGO/α-Fe2O3 films presented higher photocurrent and less resistivity when compared to the PDDA/α-Fe2O3 films. The largest photocurrent was obtained with the 4-bilayers rGO/α-Fe2O3 at 900 °C film, with 2.15 µA cm−2. In addition, a kinetic study for photoelectrocatalytic decolorization of the methylene blue dye under visible light was performed. The electrode that showed the greatest photoelectroactivity was the 4-bilayers rGO/α-Fe2O3 at 900 °C film, resulting in kobs = 11.90 × 10−3 min−1 and about 78% decolorization after 120 min.
publishDate 2020
dc.date.none.fl_str_mv 2020-12-12T01:36:23Z
2020-12-12T01:36:23Z
2020-01-01
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1007/s10854-020-04244-3
Journal of Materials Science: Materials in Electronics.
1573-482X
0957-4522
http://hdl.handle.net/11449/199311
10.1007/s10854-020-04244-3
2-s2.0-85089959063
url http://dx.doi.org/10.1007/s10854-020-04244-3
http://hdl.handle.net/11449/199311
identifier_str_mv Journal of Materials Science: Materials in Electronics.
1573-482X
0957-4522
10.1007/s10854-020-04244-3
2-s2.0-85089959063
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Journal of Materials Science: Materials in Electronics
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
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