Rationalizing the effect of accelerated carbonation and accelerated ageing on transition zone of cellulose fibers in cement based composites
Autor(a) principal: | |
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Data de Publicação: | 2015 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo de conferência |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://hdl.handle.net/11449/168615 |
Resumo: | The objective of the present work is to show the effect of accelerated carbonation on the transition zone of cellulose fibers in cement based composites. Accelerated carbonation increased the content of calcium carbonate (CaCO3) polymorphs and consumed the calcium hydroxide (Ca(OH)2), and other less stable cement phases. The scanning electron microscopy (SEM) images showed that absence of S - and Al-rich needles around the cellulose fibers in the carbonated composites, and confirmed by the energy dispersive spectrometry (EDS) mapping. The CaCO3 formed from the carbonation reaction is precipitated in the pore structure of the matrix, decreasing diffusion of Si, S an AI during curing and secondary hydration, because act as a binder and refine the pore size distribution. The interface between the cellulose fibers and the cement matrix in the carbonated composites was improved, decreasing the typical transition zone around the cellulose fibers that prejudice the fiber-cement performance at long term. Additionally, the consequence of carbonation at early age is the volume stabilization, as indicated by the lower drying shrinkage. The use of this technology during the fiber-cement production consists of an interesting procedure to prematurely decrease the alkalinity of the cement matrix, which is potentially harmful to those reinforcing fibers that are vulnerable to the alkali attack. It also improves the microstructure of the material and is an initiative to CO2sequestration and partial replacement of petroleum-based fibers as is the case of cellulose pulps. |
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Rationalizing the effect of accelerated carbonation and accelerated ageing on transition zone of cellulose fibers in cement based compositesA. FibersA. HybridB. Fiber/matrix bondE. cureF. interfaceThe objective of the present work is to show the effect of accelerated carbonation on the transition zone of cellulose fibers in cement based composites. Accelerated carbonation increased the content of calcium carbonate (CaCO3) polymorphs and consumed the calcium hydroxide (Ca(OH)2), and other less stable cement phases. The scanning electron microscopy (SEM) images showed that absence of S - and Al-rich needles around the cellulose fibers in the carbonated composites, and confirmed by the energy dispersive spectrometry (EDS) mapping. The CaCO3 formed from the carbonation reaction is precipitated in the pore structure of the matrix, decreasing diffusion of Si, S an AI during curing and secondary hydration, because act as a binder and refine the pore size distribution. The interface between the cellulose fibers and the cement matrix in the carbonated composites was improved, decreasing the typical transition zone around the cellulose fibers that prejudice the fiber-cement performance at long term. Additionally, the consequence of carbonation at early age is the volume stabilization, as indicated by the lower drying shrinkage. The use of this technology during the fiber-cement production consists of an interesting procedure to prematurely decrease the alkalinity of the cement matrix, which is potentially harmful to those reinforcing fibers that are vulnerable to the alkali attack. It also improves the microstructure of the material and is an initiative to CO2sequestration and partial replacement of petroleum-based fibers as is the case of cellulose pulps.Department of Forest Science Universidade Federal de Lavras, C.P. 3037Department of Bio-Systems Engineering Faculdade de Zootecnia e Engenharia de Alimentos Universidade de São Paulo (USP), Avenida Duque de Caxias Norte, 225Universidade Estadual Paulista Julio de Mesquita Filno - UNESPEduardo Torroja Institute for Construction Science (CSIC), C/Serrano Galvache, 4Universidade Estadual Paulista Julio de Mesquita Filno - UNESPUniversidade Federal de Lavras (UFLA)Universidade de São Paulo (USP)Universidade Estadual Paulista (Unesp)Institute for Construction Science (CSIC)Tonoli, G. H.D.Pizzol, V. D.Urea, G.Santos, S. F. [UNESP]Mendes, L. M.Santos, V.Frias, M.Savastano, H.2018-12-11T16:42:12Z2018-12-11T16:42:12Z2015-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObject547-5625th International Conference on Accelerated Carbonation for Environmental and Material Engineering 2015, p. 547-562.http://hdl.handle.net/11449/1686152-s2.0-84964871745Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPeng5th International Conference on Accelerated Carbonation for Environmental and Material Engineering 2015info:eu-repo/semantics/openAccess2021-10-23T21:47:02Zoai:repositorio.unesp.br:11449/168615Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T14:43:41.858444Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Rationalizing the effect of accelerated carbonation and accelerated ageing on transition zone of cellulose fibers in cement based composites |
title |
Rationalizing the effect of accelerated carbonation and accelerated ageing on transition zone of cellulose fibers in cement based composites |
spellingShingle |
Rationalizing the effect of accelerated carbonation and accelerated ageing on transition zone of cellulose fibers in cement based composites Tonoli, G. H.D. A. Fibers A. Hybrid B. Fiber/matrix bond E. cure F. interface |
title_short |
Rationalizing the effect of accelerated carbonation and accelerated ageing on transition zone of cellulose fibers in cement based composites |
title_full |
Rationalizing the effect of accelerated carbonation and accelerated ageing on transition zone of cellulose fibers in cement based composites |
title_fullStr |
Rationalizing the effect of accelerated carbonation and accelerated ageing on transition zone of cellulose fibers in cement based composites |
title_full_unstemmed |
Rationalizing the effect of accelerated carbonation and accelerated ageing on transition zone of cellulose fibers in cement based composites |
title_sort |
Rationalizing the effect of accelerated carbonation and accelerated ageing on transition zone of cellulose fibers in cement based composites |
author |
Tonoli, G. H.D. |
author_facet |
Tonoli, G. H.D. Pizzol, V. D. Urea, G. Santos, S. F. [UNESP] Mendes, L. M. Santos, V. Frias, M. Savastano, H. |
author_role |
author |
author2 |
Pizzol, V. D. Urea, G. Santos, S. F. [UNESP] Mendes, L. M. Santos, V. Frias, M. Savastano, H. |
author2_role |
author author author author author author author |
dc.contributor.none.fl_str_mv |
Universidade Federal de Lavras (UFLA) Universidade de São Paulo (USP) Universidade Estadual Paulista (Unesp) Institute for Construction Science (CSIC) |
dc.contributor.author.fl_str_mv |
Tonoli, G. H.D. Pizzol, V. D. Urea, G. Santos, S. F. [UNESP] Mendes, L. M. Santos, V. Frias, M. Savastano, H. |
dc.subject.por.fl_str_mv |
A. Fibers A. Hybrid B. Fiber/matrix bond E. cure F. interface |
topic |
A. Fibers A. Hybrid B. Fiber/matrix bond E. cure F. interface |
description |
The objective of the present work is to show the effect of accelerated carbonation on the transition zone of cellulose fibers in cement based composites. Accelerated carbonation increased the content of calcium carbonate (CaCO3) polymorphs and consumed the calcium hydroxide (Ca(OH)2), and other less stable cement phases. The scanning electron microscopy (SEM) images showed that absence of S - and Al-rich needles around the cellulose fibers in the carbonated composites, and confirmed by the energy dispersive spectrometry (EDS) mapping. The CaCO3 formed from the carbonation reaction is precipitated in the pore structure of the matrix, decreasing diffusion of Si, S an AI during curing and secondary hydration, because act as a binder and refine the pore size distribution. The interface between the cellulose fibers and the cement matrix in the carbonated composites was improved, decreasing the typical transition zone around the cellulose fibers that prejudice the fiber-cement performance at long term. Additionally, the consequence of carbonation at early age is the volume stabilization, as indicated by the lower drying shrinkage. The use of this technology during the fiber-cement production consists of an interesting procedure to prematurely decrease the alkalinity of the cement matrix, which is potentially harmful to those reinforcing fibers that are vulnerable to the alkali attack. It also improves the microstructure of the material and is an initiative to CO2sequestration and partial replacement of petroleum-based fibers as is the case of cellulose pulps. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-01-01 2018-12-11T16:42:12Z 2018-12-11T16:42:12Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/conferenceObject |
format |
conferenceObject |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
5th International Conference on Accelerated Carbonation for Environmental and Material Engineering 2015, p. 547-562. http://hdl.handle.net/11449/168615 2-s2.0-84964871745 |
identifier_str_mv |
5th International Conference on Accelerated Carbonation for Environmental and Material Engineering 2015, p. 547-562. 2-s2.0-84964871745 |
url |
http://hdl.handle.net/11449/168615 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
5th International Conference on Accelerated Carbonation for Environmental and Material Engineering 2015 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
547-562 |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1808128409203638272 |