Optical and structural properties of neodymium-doped KPO3-MoO3 glasses

Detalhes bibliográficos
Autor(a) principal: Galleani, Gustavo [UNESP]
Data de Publicação: 2017
Outros Autores: Santagneli, Silvia H. [UNESP], Ribeiro, Sidney J.L. [UNESP], Messaddeq, Younes [UNESP], Maia, Lauro J.Q., Nunes, Luiz A.O.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1016/j.jnoncrysol.2016.12.002
http://hdl.handle.net/11449/178491
Resumo: Glasses of composition (mol%) 75KPO3-(25-x)MoO3-xNd3 +, with 0 ≤ x ≤ 1.0, have been prepared and characterized. Thermal and structural properties of the glasses were studied by Differential Scanning Calorimetry (DSC) and Raman scattering spectroscopy. The thermal stability against crystallization on heating was evaluated. Absorption spectra in the visible and infrared regions were collected and analysed, and photoluminescence excitation and emission spectra were obtained under 804 nm diode laser excitations. Using the Judd-Ofelt formalism, the Ω2, Ω4, and Ω6 parameters and the radiative lifetime (τr) were calculated for the 4F3/2 excited state. A fluorescence quantum efficiency for this level (QE = τf / τr) of 58% was determined for glass with x = 0.6.
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spelling Optical and structural properties of neodymium-doped KPO3-MoO3 glassesLifetimeNd3 + ionsOptical propertiesPhosphate glassesGlasses of composition (mol%) 75KPO3-(25-x)MoO3-xNd3 +, with 0 ≤ x ≤ 1.0, have been prepared and characterized. Thermal and structural properties of the glasses were studied by Differential Scanning Calorimetry (DSC) and Raman scattering spectroscopy. The thermal stability against crystallization on heating was evaluated. Absorption spectra in the visible and infrared regions were collected and analysed, and photoluminescence excitation and emission spectra were obtained under 804 nm diode laser excitations. Using the Judd-Ofelt formalism, the Ω2, Ω4, and Ω6 parameters and the radiative lifetime (τr) were calculated for the 4F3/2 excited state. A fluorescence quantum efficiency for this level (QE = τf / τr) of 58% was determined for glass with x = 0.6.Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Fundação de Amparo à Pesquisa do Estado de GoiásFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Institute of Chemistry São Paulo State University/UNESP, CP355 Araraquara-SPInstitute of Physics Federal University of Goiás/UFGInstitute of Physics of São Carlos São Paulo University/USPInstitute of Chemistry São Paulo State University/UNESP, CP355 Araraquara-SPFAPESP: 08/53680-0Universidade Estadual Paulista (Unesp)Universidade Federal de Goiás (UFG)Universidade de São Paulo (USP)Galleani, Gustavo [UNESP]Santagneli, Silvia H. [UNESP]Ribeiro, Sidney J.L. [UNESP]Messaddeq, Younes [UNESP]Maia, Lauro J.Q.Nunes, Luiz A.O.2018-12-11T17:30:38Z2018-12-11T17:30:38Z2017-02-15info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article65-68application/pdfhttp://dx.doi.org/10.1016/j.jnoncrysol.2016.12.002Journal of Non-Crystalline Solids, v. 458, p. 65-68.0022-3093http://hdl.handle.net/11449/17849110.1016/j.jnoncrysol.2016.12.0022-s2.0-850063267942-s2.0-85006326794.pdfScopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Non-Crystalline Solids0,722info:eu-repo/semantics/openAccess2024-01-16T06:27:11Zoai:repositorio.unesp.br:11449/178491Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T23:07:57.828290Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Optical and structural properties of neodymium-doped KPO3-MoO3 glasses
title Optical and structural properties of neodymium-doped KPO3-MoO3 glasses
spellingShingle Optical and structural properties of neodymium-doped KPO3-MoO3 glasses
Galleani, Gustavo [UNESP]
Lifetime
Nd3 + ions
Optical properties
Phosphate glasses
title_short Optical and structural properties of neodymium-doped KPO3-MoO3 glasses
title_full Optical and structural properties of neodymium-doped KPO3-MoO3 glasses
title_fullStr Optical and structural properties of neodymium-doped KPO3-MoO3 glasses
title_full_unstemmed Optical and structural properties of neodymium-doped KPO3-MoO3 glasses
title_sort Optical and structural properties of neodymium-doped KPO3-MoO3 glasses
author Galleani, Gustavo [UNESP]
author_facet Galleani, Gustavo [UNESP]
Santagneli, Silvia H. [UNESP]
Ribeiro, Sidney J.L. [UNESP]
Messaddeq, Younes [UNESP]
Maia, Lauro J.Q.
Nunes, Luiz A.O.
author_role author
author2 Santagneli, Silvia H. [UNESP]
Ribeiro, Sidney J.L. [UNESP]
Messaddeq, Younes [UNESP]
Maia, Lauro J.Q.
Nunes, Luiz A.O.
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (Unesp)
Universidade Federal de Goiás (UFG)
Universidade de São Paulo (USP)
dc.contributor.author.fl_str_mv Galleani, Gustavo [UNESP]
Santagneli, Silvia H. [UNESP]
Ribeiro, Sidney J.L. [UNESP]
Messaddeq, Younes [UNESP]
Maia, Lauro J.Q.
Nunes, Luiz A.O.
dc.subject.por.fl_str_mv Lifetime
Nd3 + ions
Optical properties
Phosphate glasses
topic Lifetime
Nd3 + ions
Optical properties
Phosphate glasses
description Glasses of composition (mol%) 75KPO3-(25-x)MoO3-xNd3 +, with 0 ≤ x ≤ 1.0, have been prepared and characterized. Thermal and structural properties of the glasses were studied by Differential Scanning Calorimetry (DSC) and Raman scattering spectroscopy. The thermal stability against crystallization on heating was evaluated. Absorption spectra in the visible and infrared regions were collected and analysed, and photoluminescence excitation and emission spectra were obtained under 804 nm diode laser excitations. Using the Judd-Ofelt formalism, the Ω2, Ω4, and Ω6 parameters and the radiative lifetime (τr) were calculated for the 4F3/2 excited state. A fluorescence quantum efficiency for this level (QE = τf / τr) of 58% was determined for glass with x = 0.6.
publishDate 2017
dc.date.none.fl_str_mv 2017-02-15
2018-12-11T17:30:38Z
2018-12-11T17:30:38Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1016/j.jnoncrysol.2016.12.002
Journal of Non-Crystalline Solids, v. 458, p. 65-68.
0022-3093
http://hdl.handle.net/11449/178491
10.1016/j.jnoncrysol.2016.12.002
2-s2.0-85006326794
2-s2.0-85006326794.pdf
url http://dx.doi.org/10.1016/j.jnoncrysol.2016.12.002
http://hdl.handle.net/11449/178491
identifier_str_mv Journal of Non-Crystalline Solids, v. 458, p. 65-68.
0022-3093
10.1016/j.jnoncrysol.2016.12.002
2-s2.0-85006326794
2-s2.0-85006326794.pdf
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Journal of Non-Crystalline Solids
0,722
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 65-68
application/pdf
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1808129492419346432

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