A Simple and Fast Method for the Production and Characterization of Methylic and Ethylic Biodiesels from Tucum Oil via an Alkaline Route
Autor(a) principal: | |
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Data de Publicação: | 2011 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1155/2011/238474 http://hdl.handle.net/11449/25899 |
Resumo: | A simple, fast, and complete route for the production of methylic and ethylic biodiesel from tucum oil is described. Aliquots of the oil obtained directly from pressed tucum (pulp and almonds) were treated with potassium methoxide or ethoxide at 40 degrees C for 40 min. The biodiesel form was removed from the reactor and washed with 0.1 M HCl aqueous solution. A simple distillation at 100 degrees C was carried out in order to remove water and alcohol species from the biodiesel. The oxidative stability index was obtained for the tucum oil as well as the methylic and ethylic biodiesel at 6.13, 2.90, and 2.80 h, for storage times higher than 8 days. Quality control of the original oil and of the methylic and ethylic biodiesels, such as the amount of glycerin produced during the transesterification process, was accomplished by the TLC, GC-MS, and FT-IR techniques. The results obtained in this study indicate a potential biofuel production by simple treatment of tucum, an important Amazonian fruit. |
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Repositório Institucional da UNESP |
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spelling |
A Simple and Fast Method for the Production and Characterization of Methylic and Ethylic Biodiesels from Tucum Oil via an Alkaline RouteA simple, fast, and complete route for the production of methylic and ethylic biodiesel from tucum oil is described. Aliquots of the oil obtained directly from pressed tucum (pulp and almonds) were treated with potassium methoxide or ethoxide at 40 degrees C for 40 min. The biodiesel form was removed from the reactor and washed with 0.1 M HCl aqueous solution. A simple distillation at 100 degrees C was carried out in order to remove water and alcohol species from the biodiesel. The oxidative stability index was obtained for the tucum oil as well as the methylic and ethylic biodiesel at 6.13, 2.90, and 2.80 h, for storage times higher than 8 days. Quality control of the original oil and of the methylic and ethylic biodiesels, such as the amount of glycerin produced during the transesterification process, was accomplished by the TLC, GC-MS, and FT-IR techniques. The results obtained in this study indicate a potential biofuel production by simple treatment of tucum, an important Amazonian fruit.Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Financiadora de Estudos e Projetos (FINEP)Fundação de Amparo à Pesquisa do Estado de Minas Gerais (FAPEMIG)Univ São Paulo, Dept Quim, Fac Filosofia Ciencias & Letras Ribeirao Preto, BR-14040901 Ribeirao Preto, SP, BrazilUNESP, Dept Quim Analit, Inst Quim, BR-14800900 Araraquara, SP, BrazilUFU, LERMAP, BR-38302000 Ituiutaba, MG, BrazilUNESP, Dept Quim Analit, Inst Quim, BR-14800900 Araraquara, SP, BrazilHindawi Publishing CorporationUniversidade de São Paulo (USP)Universidade Estadual Paulista (Unesp)Universidade Federal de Uberlândia (UFU)de Oliveira, Marcelo FirminoVieira, Andressa Tironi [UNESP]Ferreira Batista, Antonio CarlosRodrigues, Hugo de SouzaStradiotto, Nelson Ramos [UNESP]2014-05-20T14:19:33Z2014-05-20T14:19:33Z2011-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article4application/pdfhttp://dx.doi.org/10.1155/2011/238474Journal of Biomedicine and Biotechnology. New York: Hindawi Publishing Corporation, p. 4, 2011.1110-7243http://hdl.handle.net/11449/2589910.1155/2011/238474WOS:000292405000001WOS000292405000001.pdf0072173018005712Web of Sciencereponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Biomedicine and Biotechnologyinfo:eu-repo/semantics/openAccess2023-12-20T06:23:52Zoai:repositorio.unesp.br:11449/25899Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T20:50:08.449211Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
A Simple and Fast Method for the Production and Characterization of Methylic and Ethylic Biodiesels from Tucum Oil via an Alkaline Route |
title |
A Simple and Fast Method for the Production and Characterization of Methylic and Ethylic Biodiesels from Tucum Oil via an Alkaline Route |
spellingShingle |
A Simple and Fast Method for the Production and Characterization of Methylic and Ethylic Biodiesels from Tucum Oil via an Alkaline Route de Oliveira, Marcelo Firmino |
title_short |
A Simple and Fast Method for the Production and Characterization of Methylic and Ethylic Biodiesels from Tucum Oil via an Alkaline Route |
title_full |
A Simple and Fast Method for the Production and Characterization of Methylic and Ethylic Biodiesels from Tucum Oil via an Alkaline Route |
title_fullStr |
A Simple and Fast Method for the Production and Characterization of Methylic and Ethylic Biodiesels from Tucum Oil via an Alkaline Route |
title_full_unstemmed |
A Simple and Fast Method for the Production and Characterization of Methylic and Ethylic Biodiesels from Tucum Oil via an Alkaline Route |
title_sort |
A Simple and Fast Method for the Production and Characterization of Methylic and Ethylic Biodiesels from Tucum Oil via an Alkaline Route |
author |
de Oliveira, Marcelo Firmino |
author_facet |
de Oliveira, Marcelo Firmino Vieira, Andressa Tironi [UNESP] Ferreira Batista, Antonio Carlos Rodrigues, Hugo de Souza Stradiotto, Nelson Ramos [UNESP] |
author_role |
author |
author2 |
Vieira, Andressa Tironi [UNESP] Ferreira Batista, Antonio Carlos Rodrigues, Hugo de Souza Stradiotto, Nelson Ramos [UNESP] |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
Universidade de São Paulo (USP) Universidade Estadual Paulista (Unesp) Universidade Federal de Uberlândia (UFU) |
dc.contributor.author.fl_str_mv |
de Oliveira, Marcelo Firmino Vieira, Andressa Tironi [UNESP] Ferreira Batista, Antonio Carlos Rodrigues, Hugo de Souza Stradiotto, Nelson Ramos [UNESP] |
description |
A simple, fast, and complete route for the production of methylic and ethylic biodiesel from tucum oil is described. Aliquots of the oil obtained directly from pressed tucum (pulp and almonds) were treated with potassium methoxide or ethoxide at 40 degrees C for 40 min. The biodiesel form was removed from the reactor and washed with 0.1 M HCl aqueous solution. A simple distillation at 100 degrees C was carried out in order to remove water and alcohol species from the biodiesel. The oxidative stability index was obtained for the tucum oil as well as the methylic and ethylic biodiesel at 6.13, 2.90, and 2.80 h, for storage times higher than 8 days. Quality control of the original oil and of the methylic and ethylic biodiesels, such as the amount of glycerin produced during the transesterification process, was accomplished by the TLC, GC-MS, and FT-IR techniques. The results obtained in this study indicate a potential biofuel production by simple treatment of tucum, an important Amazonian fruit. |
publishDate |
2011 |
dc.date.none.fl_str_mv |
2011-01-01 2014-05-20T14:19:33Z 2014-05-20T14:19:33Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1155/2011/238474 Journal of Biomedicine and Biotechnology. New York: Hindawi Publishing Corporation, p. 4, 2011. 1110-7243 http://hdl.handle.net/11449/25899 10.1155/2011/238474 WOS:000292405000001 WOS000292405000001.pdf 0072173018005712 |
url |
http://dx.doi.org/10.1155/2011/238474 http://hdl.handle.net/11449/25899 |
identifier_str_mv |
Journal of Biomedicine and Biotechnology. New York: Hindawi Publishing Corporation, p. 4, 2011. 1110-7243 10.1155/2011/238474 WOS:000292405000001 WOS000292405000001.pdf 0072173018005712 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Journal of Biomedicine and Biotechnology |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
4 application/pdf |
dc.publisher.none.fl_str_mv |
Hindawi Publishing Corporation |
publisher.none.fl_str_mv |
Hindawi Publishing Corporation |
dc.source.none.fl_str_mv |
Web of Science reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1808129256276885504 |