Preaustinoid A: a meroterpene produced by Penicillium sp.

Detalhes bibliográficos
Autor(a) principal: Maganhi, Stella H.
Data de Publicação: 2009
Outros Autores: Fill, Taicia Pacheco, Rodrigues-Fo, Edson, Caracelli, Ignez [UNESP], Zukerman-Schpector, Julio
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1107/S1600536808043481
http://hdl.handle.net/11449/8534
Resumo: The title meroterpene preaustinoid A (systematic name: methyl 15-hydroxy-2,6,6,10,13,15-hexamethyl-17-methylene-7,14,16-trioxotetracyclo[11.3.1.0(2,11).0(5,10)] heptadecane-1-carboxylate), C(26)H(36)O(6), features a fused four-ring arrangement. Three rings are in different distorted chair conformations and the other is in a distorted boat conformation. The absolute configuration was established based on [alpha(D)] = -4.97 degrees (c = 1.10 g l(-1), CH(2)Cl(2)). In the crystal, the molecules are connected into supramolecular chains via O-H center dot center dot center dot O hydrogen bonds.
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spelling Preaustinoid A: a meroterpene produced by Penicillium sp.The title meroterpene preaustinoid A (systematic name: methyl 15-hydroxy-2,6,6,10,13,15-hexamethyl-17-methylene-7,14,16-trioxotetracyclo[11.3.1.0(2,11).0(5,10)] heptadecane-1-carboxylate), C(26)H(36)O(6), features a fused four-ring arrangement. Three rings are in different distorted chair conformations and the other is in a distorted boat conformation. The absolute configuration was established based on [alpha(D)] = -4.97 degrees (c = 1.10 g l(-1), CH(2)Cl(2)). In the crystal, the molecules are connected into supramolecular chains via O-H center dot center dot center dot O hydrogen bonds.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Univ Fed Sao Carlos, Dept Chem, BR-13565905 Sao Carlos, SP, BrazilUniv Estadual Paulista, BioMat Phys Dept, BR-17033360 Bauru, SP, BrazilUniv Estadual Paulista, BioMat Phys Dept, BR-17033360 Bauru, SP, BrazilWiley-Blackwell Publishing, IncUniversidade Federal de São Carlos (UFSCar)Universidade Estadual Paulista (Unesp)Maganhi, Stella H.Fill, Taicia PachecoRodrigues-Fo, EdsonCaracelli, Ignez [UNESP]Zukerman-Schpector, Julio2014-05-20T13:26:29Z2014-05-20T13:26:29Z2009-02-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleO221-U1228application/pdfhttp://dx.doi.org/10.1107/S1600536808043481Acta Crystallographica Section E-structure Reports Online. Malden: Wiley-blackwell Publishing, Inc, v. 65, p. O221-U1228, 2009.1600-5368http://hdl.handle.net/11449/853410.1107/S1600536808043481WOS:000263040700103WOS000263040700103.pdfWeb of Sciencereponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengActa Crystallographica Section E: Structure Reports Online0,138info:eu-repo/semantics/openAccess2024-04-25T17:40:00Zoai:repositorio.unesp.br:11449/8534Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-04-25T17:40Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Preaustinoid A: a meroterpene produced by Penicillium sp.
title Preaustinoid A: a meroterpene produced by Penicillium sp.
spellingShingle Preaustinoid A: a meroterpene produced by Penicillium sp.
Maganhi, Stella H.
title_short Preaustinoid A: a meroterpene produced by Penicillium sp.
title_full Preaustinoid A: a meroterpene produced by Penicillium sp.
title_fullStr Preaustinoid A: a meroterpene produced by Penicillium sp.
title_full_unstemmed Preaustinoid A: a meroterpene produced by Penicillium sp.
title_sort Preaustinoid A: a meroterpene produced by Penicillium sp.
author Maganhi, Stella H.
author_facet Maganhi, Stella H.
Fill, Taicia Pacheco
Rodrigues-Fo, Edson
Caracelli, Ignez [UNESP]
Zukerman-Schpector, Julio
author_role author
author2 Fill, Taicia Pacheco
Rodrigues-Fo, Edson
Caracelli, Ignez [UNESP]
Zukerman-Schpector, Julio
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universidade Federal de São Carlos (UFSCar)
Universidade Estadual Paulista (Unesp)
dc.contributor.author.fl_str_mv Maganhi, Stella H.
Fill, Taicia Pacheco
Rodrigues-Fo, Edson
Caracelli, Ignez [UNESP]
Zukerman-Schpector, Julio
description The title meroterpene preaustinoid A (systematic name: methyl 15-hydroxy-2,6,6,10,13,15-hexamethyl-17-methylene-7,14,16-trioxotetracyclo[11.3.1.0(2,11).0(5,10)] heptadecane-1-carboxylate), C(26)H(36)O(6), features a fused four-ring arrangement. Three rings are in different distorted chair conformations and the other is in a distorted boat conformation. The absolute configuration was established based on [alpha(D)] = -4.97 degrees (c = 1.10 g l(-1), CH(2)Cl(2)). In the crystal, the molecules are connected into supramolecular chains via O-H center dot center dot center dot O hydrogen bonds.
publishDate 2009
dc.date.none.fl_str_mv 2009-02-01
2014-05-20T13:26:29Z
2014-05-20T13:26:29Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1107/S1600536808043481
Acta Crystallographica Section E-structure Reports Online. Malden: Wiley-blackwell Publishing, Inc, v. 65, p. O221-U1228, 2009.
1600-5368
http://hdl.handle.net/11449/8534
10.1107/S1600536808043481
WOS:000263040700103
WOS000263040700103.pdf
url http://dx.doi.org/10.1107/S1600536808043481
http://hdl.handle.net/11449/8534
identifier_str_mv Acta Crystallographica Section E-structure Reports Online. Malden: Wiley-blackwell Publishing, Inc, v. 65, p. O221-U1228, 2009.
1600-5368
10.1107/S1600536808043481
WOS:000263040700103
WOS000263040700103.pdf
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Acta Crystallographica Section E: Structure Reports Online
0,138
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv O221-U1228
application/pdf
dc.publisher.none.fl_str_mv Wiley-Blackwell Publishing, Inc
publisher.none.fl_str_mv Wiley-Blackwell Publishing, Inc
dc.source.none.fl_str_mv Web of Science
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1803046791360282624

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