Dimethacrylate polymers with different glycerol content: Thermal study, degree of conversion, and morphological features

Detalhes bibliográficos
Autor(a) principal: Alarcon, Rafael Turra [UNESP]
Data de Publicação: 2018
Outros Autores: Gaglieri, Caroline [UNESP], Bannach, Gilbert [UNESP]
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1007/s10973-018-7055-8
http://hdl.handle.net/11449/179601
Resumo: The objectives of this study were to verify thermal properties, degree of conversion, and morphological features of several dimethacrylate polymers with different glycerol content and obtain the better proportion system to decrease cost of final polymer. These polymers were synthesized by photopolymerization, which has economic and ecological advantages. The glycerol can be used as a coinitiator in photopolymerization and has the advantage of being inexpensive and non-toxic; thus, it is in the scope of the green chemistry principles. Simultaneous thermogravimetry–differential thermal analysis and derivative thermogravimetric, differential scanning calorimetry, middle infrared spectroscopy, and scanning electronic microscopy were used to determine thermal properties, degree of conversion, and morphological characteristics of polymers obtained. The thermoanalytical results showed that glycerol addition in the dimethacrylate system caused few modifications in the thermal stability of the polymer and thermal events when compared with pure polymers (without glycerol). Two dimethacrylate systems (UDMA/glycerol and Bis-GMA/glycerol) showed good results for conversion degree and morphological aspects when compared with pure systems.
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spelling Dimethacrylate polymers with different glycerol content: Thermal study, degree of conversion, and morphological featuresConversion degreeDimethacrylatesGlycerolPhotopolymerizationThermal analysisThe objectives of this study were to verify thermal properties, degree of conversion, and morphological features of several dimethacrylate polymers with different glycerol content and obtain the better proportion system to decrease cost of final polymer. These polymers were synthesized by photopolymerization, which has economic and ecological advantages. The glycerol can be used as a coinitiator in photopolymerization and has the advantage of being inexpensive and non-toxic; thus, it is in the scope of the green chemistry principles. Simultaneous thermogravimetry–differential thermal analysis and derivative thermogravimetric, differential scanning calorimetry, middle infrared spectroscopy, and scanning electronic microscopy were used to determine thermal properties, degree of conversion, and morphological characteristics of polymers obtained. The thermoanalytical results showed that glycerol addition in the dimethacrylate system caused few modifications in the thermal stability of the polymer and thermal events when compared with pure polymers (without glycerol). Two dimethacrylate systems (UDMA/glycerol and Bis-GMA/glycerol) showed good results for conversion degree and morphological aspects when compared with pure systems.Chemistry Department School of Science São Paulo State University (UNESP)Chemistry Department School of Science São Paulo State University (UNESP)Universidade Estadual Paulista (Unesp)Alarcon, Rafael Turra [UNESP]Gaglieri, Caroline [UNESP]Bannach, Gilbert [UNESP]2018-12-11T17:35:59Z2018-12-11T17:35:59Z2018-06-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article1579-1591application/pdfhttp://dx.doi.org/10.1007/s10973-018-7055-8Journal of Thermal Analysis and Calorimetry, v. 132, n. 3, p. 1579-1591, 2018.1588-29261388-6150http://hdl.handle.net/11449/17960110.1007/s10973-018-7055-82-s2.0-850422205412-s2.0-85042220541.pdfScopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Thermal Analysis and Calorimetry0,5870,587info:eu-repo/semantics/openAccess2023-11-06T06:12:08Zoai:repositorio.unesp.br:11449/179601Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462023-11-06T06:12:08Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Dimethacrylate polymers with different glycerol content: Thermal study, degree of conversion, and morphological features
title Dimethacrylate polymers with different glycerol content: Thermal study, degree of conversion, and morphological features
spellingShingle Dimethacrylate polymers with different glycerol content: Thermal study, degree of conversion, and morphological features
Alarcon, Rafael Turra [UNESP]
Conversion degree
Dimethacrylates
Glycerol
Photopolymerization
Thermal analysis
title_short Dimethacrylate polymers with different glycerol content: Thermal study, degree of conversion, and morphological features
title_full Dimethacrylate polymers with different glycerol content: Thermal study, degree of conversion, and morphological features
title_fullStr Dimethacrylate polymers with different glycerol content: Thermal study, degree of conversion, and morphological features
title_full_unstemmed Dimethacrylate polymers with different glycerol content: Thermal study, degree of conversion, and morphological features
title_sort Dimethacrylate polymers with different glycerol content: Thermal study, degree of conversion, and morphological features
author Alarcon, Rafael Turra [UNESP]
author_facet Alarcon, Rafael Turra [UNESP]
Gaglieri, Caroline [UNESP]
Bannach, Gilbert [UNESP]
author_role author
author2 Gaglieri, Caroline [UNESP]
Bannach, Gilbert [UNESP]
author2_role author
author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (Unesp)
dc.contributor.author.fl_str_mv Alarcon, Rafael Turra [UNESP]
Gaglieri, Caroline [UNESP]
Bannach, Gilbert [UNESP]
dc.subject.por.fl_str_mv Conversion degree
Dimethacrylates
Glycerol
Photopolymerization
Thermal analysis
topic Conversion degree
Dimethacrylates
Glycerol
Photopolymerization
Thermal analysis
description The objectives of this study were to verify thermal properties, degree of conversion, and morphological features of several dimethacrylate polymers with different glycerol content and obtain the better proportion system to decrease cost of final polymer. These polymers were synthesized by photopolymerization, which has economic and ecological advantages. The glycerol can be used as a coinitiator in photopolymerization and has the advantage of being inexpensive and non-toxic; thus, it is in the scope of the green chemistry principles. Simultaneous thermogravimetry–differential thermal analysis and derivative thermogravimetric, differential scanning calorimetry, middle infrared spectroscopy, and scanning electronic microscopy were used to determine thermal properties, degree of conversion, and morphological characteristics of polymers obtained. The thermoanalytical results showed that glycerol addition in the dimethacrylate system caused few modifications in the thermal stability of the polymer and thermal events when compared with pure polymers (without glycerol). Two dimethacrylate systems (UDMA/glycerol and Bis-GMA/glycerol) showed good results for conversion degree and morphological aspects when compared with pure systems.
publishDate 2018
dc.date.none.fl_str_mv 2018-12-11T17:35:59Z
2018-12-11T17:35:59Z
2018-06-01
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1007/s10973-018-7055-8
Journal of Thermal Analysis and Calorimetry, v. 132, n. 3, p. 1579-1591, 2018.
1588-2926
1388-6150
http://hdl.handle.net/11449/179601
10.1007/s10973-018-7055-8
2-s2.0-85042220541
2-s2.0-85042220541.pdf
url http://dx.doi.org/10.1007/s10973-018-7055-8
http://hdl.handle.net/11449/179601
identifier_str_mv Journal of Thermal Analysis and Calorimetry, v. 132, n. 3, p. 1579-1591, 2018.
1588-2926
1388-6150
10.1007/s10973-018-7055-8
2-s2.0-85042220541
2-s2.0-85042220541.pdf
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Journal of Thermal Analysis and Calorimetry
0,587
0,587
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 1579-1591
application/pdf
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1797789628658352128

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