AIE Effect by Oxygen Clustering in Vegetable Oil-Based Polymers
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1002/slct.202100889 http://hdl.handle.net/11449/233437 |
Resumo: | Vegetable oil has been widely used to synthesize monomers and polymers in different fields. Some authors have found different polymers in maleinized vegetable oil; however, they have not described the luminescent properties of the polymers in an intensive way. This work aimed to synthesize new polymers from macadamia oil using diethylene glycol and glycerol as crosslinkers and their characterization The results obtained by spectroscopic analyses confirmed the incorporation of anhydride, as well as the reactions for the final polymers. Results from UV-Vis showed that maleinized macadamia oil presented an aggregation-induced emission effect with solvatochromic effect with absorption at 201.6 nm (ethanol) and 241.8 nm (chloroform), which was corroborated by theoretical calculations. Moreover, the luminescent property exhibited by both obtained polymers was kept even after the swelling test, and powdering the samples. Therefore, these polymers, synthetized in a fast way and without catalyst, open a new field of renewable and sustainable materials with luminescent properties that can be applied in technological fields, such as solar cells and fluorescent sensors. |
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AIE Effect by Oxygen Clustering in Vegetable Oil-Based PolymersClustering effectGreen ChemistryLuminescent polymerRenewable materialVegetable oilVegetable oil has been widely used to synthesize monomers and polymers in different fields. Some authors have found different polymers in maleinized vegetable oil; however, they have not described the luminescent properties of the polymers in an intensive way. This work aimed to synthesize new polymers from macadamia oil using diethylene glycol and glycerol as crosslinkers and their characterization The results obtained by spectroscopic analyses confirmed the incorporation of anhydride, as well as the reactions for the final polymers. Results from UV-Vis showed that maleinized macadamia oil presented an aggregation-induced emission effect with solvatochromic effect with absorption at 201.6 nm (ethanol) and 241.8 nm (chloroform), which was corroborated by theoretical calculations. Moreover, the luminescent property exhibited by both obtained polymers was kept even after the swelling test, and powdering the samples. Therefore, these polymers, synthetized in a fast way and without catalyst, open a new field of renewable and sustainable materials with luminescent properties that can be applied in technological fields, such as solar cells and fluorescent sensors.Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)School of Sciences Department of Chemistry UNESP- São Paulo State UniversityInstitute of Chemistry Department of Physical Chemistry UNICAMP-Campinas State University CampinasSchool of Sciences Department of Chemistry UNESP- São Paulo State UniversityCAPES: 011/2009CAPES: 024/2012Universidade Estadual Paulista (UNESP)Universidade Estadual de Campinas (UNICAMP)Alarcon, Rafael T. [UNESP]Gaglieri, Caroline [UNESP]dos Santos, Giovanny C. [UNESP]Moralles, Ana C.Morgon, Nelson H.de Souza, Aguinaldo R. [UNESP]Bannach, Gilbert [UNESP]2022-05-01T08:44:40Z2022-05-01T08:44:40Z2021-08-20info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article7838-7844http://dx.doi.org/10.1002/slct.202100889ChemistrySelect, v. 6, n. 31, p. 7838-7844, 2021.2365-6549http://hdl.handle.net/11449/23343710.1002/slct.2021008892-s2.0-85113426125Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengChemistrySelectinfo:eu-repo/semantics/openAccess2024-04-29T18:16:46Zoai:repositorio.unesp.br:11449/233437Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-04-29T18:16:46Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
AIE Effect by Oxygen Clustering in Vegetable Oil-Based Polymers |
title |
AIE Effect by Oxygen Clustering in Vegetable Oil-Based Polymers |
spellingShingle |
AIE Effect by Oxygen Clustering in Vegetable Oil-Based Polymers Alarcon, Rafael T. [UNESP] Clustering effect Green Chemistry Luminescent polymer Renewable material Vegetable oil |
title_short |
AIE Effect by Oxygen Clustering in Vegetable Oil-Based Polymers |
title_full |
AIE Effect by Oxygen Clustering in Vegetable Oil-Based Polymers |
title_fullStr |
AIE Effect by Oxygen Clustering in Vegetable Oil-Based Polymers |
title_full_unstemmed |
AIE Effect by Oxygen Clustering in Vegetable Oil-Based Polymers |
title_sort |
AIE Effect by Oxygen Clustering in Vegetable Oil-Based Polymers |
author |
Alarcon, Rafael T. [UNESP] |
author_facet |
Alarcon, Rafael T. [UNESP] Gaglieri, Caroline [UNESP] dos Santos, Giovanny C. [UNESP] Moralles, Ana C. Morgon, Nelson H. de Souza, Aguinaldo R. [UNESP] Bannach, Gilbert [UNESP] |
author_role |
author |
author2 |
Gaglieri, Caroline [UNESP] dos Santos, Giovanny C. [UNESP] Moralles, Ana C. Morgon, Nelson H. de Souza, Aguinaldo R. [UNESP] Bannach, Gilbert [UNESP] |
author2_role |
author author author author author author |
dc.contributor.none.fl_str_mv |
Universidade Estadual Paulista (UNESP) Universidade Estadual de Campinas (UNICAMP) |
dc.contributor.author.fl_str_mv |
Alarcon, Rafael T. [UNESP] Gaglieri, Caroline [UNESP] dos Santos, Giovanny C. [UNESP] Moralles, Ana C. Morgon, Nelson H. de Souza, Aguinaldo R. [UNESP] Bannach, Gilbert [UNESP] |
dc.subject.por.fl_str_mv |
Clustering effect Green Chemistry Luminescent polymer Renewable material Vegetable oil |
topic |
Clustering effect Green Chemistry Luminescent polymer Renewable material Vegetable oil |
description |
Vegetable oil has been widely used to synthesize monomers and polymers in different fields. Some authors have found different polymers in maleinized vegetable oil; however, they have not described the luminescent properties of the polymers in an intensive way. This work aimed to synthesize new polymers from macadamia oil using diethylene glycol and glycerol as crosslinkers and their characterization The results obtained by spectroscopic analyses confirmed the incorporation of anhydride, as well as the reactions for the final polymers. Results from UV-Vis showed that maleinized macadamia oil presented an aggregation-induced emission effect with solvatochromic effect with absorption at 201.6 nm (ethanol) and 241.8 nm (chloroform), which was corroborated by theoretical calculations. Moreover, the luminescent property exhibited by both obtained polymers was kept even after the swelling test, and powdering the samples. Therefore, these polymers, synthetized in a fast way and without catalyst, open a new field of renewable and sustainable materials with luminescent properties that can be applied in technological fields, such as solar cells and fluorescent sensors. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-08-20 2022-05-01T08:44:40Z 2022-05-01T08:44:40Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1002/slct.202100889 ChemistrySelect, v. 6, n. 31, p. 7838-7844, 2021. 2365-6549 http://hdl.handle.net/11449/233437 10.1002/slct.202100889 2-s2.0-85113426125 |
url |
http://dx.doi.org/10.1002/slct.202100889 http://hdl.handle.net/11449/233437 |
identifier_str_mv |
ChemistrySelect, v. 6, n. 31, p. 7838-7844, 2021. 2365-6549 10.1002/slct.202100889 2-s2.0-85113426125 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
ChemistrySelect |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
7838-7844 |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
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1799964582747308032 |