Quantificação eletroquímica de analitos de interesse ambiental e biológico, empregando novos materiais preparados a partir de silsesquioxanos funcionalizados

• Autor(a) principal: Fernandes, Daniela Silvestrini [UNESP]
• Data de Publicação: 2015
• Tipo de documento: Tese
• Idioma: por
• Título da fonte: Repositório Institucional da UNESP
• Texto Completo: http://hdl.handle.net/11449/128050; http://www.athena.biblioteca.unesp.br/exlibris/bd/cathedra/30-09-2015/000849854.pdf
• topic: Eletroquimica; Análise espectral; Ciência dos materiais; Electrochemistry

The present work describes the preparation and organofunctionalization of octa-(3- chloropropyl)octasilsesquioxane (SS) with 4,5-diphenyl-2-imidazolethiol (DIT), 4-amino-5- phenyl-4H-1,2,4-triazole-3-thiol (APhTT) groups and PAMAM dendrimer generation 0 (DP). The materials were characterized using different techniques, such as: Electronic Spectroscopy in the Ultraviolet and Visible Region (UV-Vis), Fourier Transform Infrared Spectroscopy (FT-IR), 13 C and 29 Si Nuclear Magnetic Resonance in the Solid State (NMR-solid), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray spectroscopy (EDX), Transmission Electron Microscopy (TEM) and Thermogravimetric Analysis (TGA). On a second stage, after the formation of hybrid composites with metal hexacyanoferrate complexes, there was a systematic study of the analytical properties of these materials, specifically those obtained from the interaction of cubic silsesquioxane formed with copper and potassium hexacyanoferrate, using different electrochemical techniques for this purpose (Cyclic Voltammetry - CV, Differential Pulse Voltammetry - DPV and Chronoamperometry - CA) using graphite paste electrodes. After catalytic electrooxidation tests on various substances of biological, medical and environmental interest, the graphite paste electrodes containing CuHSA and CuHSP were sensitive to the neurotransmitter L- Dopamine and Ascorbic Acid