On the coexistence of ferroelectric and antiferroelectric polymorphs in NaNbO3 fibers at room temperature
Autor(a) principal: | |
---|---|
Data de Publicação: | 2023 |
Outros Autores: | , , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1039/d2tc04039e http://hdl.handle.net/11449/247218 |
Resumo: | Na2Nb2O6·H2O fibers were synthesized in a short time using a microwave-assisted hydrothermal method and later used as a precursor for obtaining NaNbO3 fibers with piezoelectric characteristics. The NaNbO3 fibers consist of a mix of antiferroelectric (Pbcm) and ferroelectric (P21ma) orthorhombic phases. The ferroelectric structure comprises about 87% wt of the sample, and a theoretical approach indicated that an electric field could induce an inversion in the relative stability between the most stable antiferroelectric structure and the ferroelectric one. Piezoresponse force microscopy showed that an individual fiber is composed of regions with ferroelectric domains and regions with no ferroelectric characteristics. |
id |
UNSP_f09f42ff833e265bf5fe100f4d07fadf |
---|---|
oai_identifier_str |
oai:repositorio.unesp.br:11449/247218 |
network_acronym_str |
UNSP |
network_name_str |
Repositório Institucional da UNESP |
repository_id_str |
2946 |
spelling |
On the coexistence of ferroelectric and antiferroelectric polymorphs in NaNbO3 fibers at room temperatureNa2Nb2O6·H2O fibers were synthesized in a short time using a microwave-assisted hydrothermal method and later used as a precursor for obtaining NaNbO3 fibers with piezoelectric characteristics. The NaNbO3 fibers consist of a mix of antiferroelectric (Pbcm) and ferroelectric (P21ma) orthorhombic phases. The ferroelectric structure comprises about 87% wt of the sample, and a theoretical approach indicated that an electric field could induce an inversion in the relative stability between the most stable antiferroelectric structure and the ferroelectric one. Piezoresponse force microscopy showed that an individual fiber is composed of regions with ferroelectric domains and regions with no ferroelectric characteristics.Universidade Federal de Goiás Instituto de Química, GOUnicamp Material Simulation Lab Institute of Chemistry State University of Campinas, SPCDMF-Universidade Federal de São Carlos, PO Box, 676 SPRenato Archer Information Technology Center, SPNanostructured Matter Laboratory Institute of Physics Belgrade University of Belgrade, Pregrevica 118Universidade Estadual Paulista Júlio de Mesquita Filho Instituto de Química, SPUniversidade Estadual Paulista Júlio de Mesquita Filho Instituto de Química, SPUniversidade Federal de Goiás (UFG)Universidade Estadual de Campinas (UNICAMP)Universidade Federal de São Carlos (UFSCar)Renato Archer Information Technology CenterUniversity of BelgradeUniversidade Estadual Paulista (UNESP)Teixeira, Guilhermina FerreiraSeleghini, Heitor SeccoBastos, Wagner BenícioJacomaci, NataliaStojadinović, BojanDohčević-Mitrović, ZoranaColmati, FlavioSan-Miguel, Miguel AngelLongo, ElsonZaghete, Maria Aparecida [UNESP]2023-07-29T13:09:53Z2023-07-29T13:09:53Z2023-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1039/d2tc04039eJournal of Materials Chemistry C.2050-7534http://hdl.handle.net/11449/24721810.1039/d2tc04039e2-s2.0-85153253388Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Materials Chemistry Cinfo:eu-repo/semantics/openAccess2023-07-29T13:09:53Zoai:repositorio.unesp.br:11449/247218Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T15:24:15.606364Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
On the coexistence of ferroelectric and antiferroelectric polymorphs in NaNbO3 fibers at room temperature |
title |
On the coexistence of ferroelectric and antiferroelectric polymorphs in NaNbO3 fibers at room temperature |
spellingShingle |
On the coexistence of ferroelectric and antiferroelectric polymorphs in NaNbO3 fibers at room temperature Teixeira, Guilhermina Ferreira |
title_short |
On the coexistence of ferroelectric and antiferroelectric polymorphs in NaNbO3 fibers at room temperature |
title_full |
On the coexistence of ferroelectric and antiferroelectric polymorphs in NaNbO3 fibers at room temperature |
title_fullStr |
On the coexistence of ferroelectric and antiferroelectric polymorphs in NaNbO3 fibers at room temperature |
title_full_unstemmed |
On the coexistence of ferroelectric and antiferroelectric polymorphs in NaNbO3 fibers at room temperature |
title_sort |
On the coexistence of ferroelectric and antiferroelectric polymorphs in NaNbO3 fibers at room temperature |
author |
Teixeira, Guilhermina Ferreira |
author_facet |
Teixeira, Guilhermina Ferreira Seleghini, Heitor Secco Bastos, Wagner Benício Jacomaci, Natalia Stojadinović, Bojan Dohčević-Mitrović, Zorana Colmati, Flavio San-Miguel, Miguel Angel Longo, Elson Zaghete, Maria Aparecida [UNESP] |
author_role |
author |
author2 |
Seleghini, Heitor Secco Bastos, Wagner Benício Jacomaci, Natalia Stojadinović, Bojan Dohčević-Mitrović, Zorana Colmati, Flavio San-Miguel, Miguel Angel Longo, Elson Zaghete, Maria Aparecida [UNESP] |
author2_role |
author author author author author author author author author |
dc.contributor.none.fl_str_mv |
Universidade Federal de Goiás (UFG) Universidade Estadual de Campinas (UNICAMP) Universidade Federal de São Carlos (UFSCar) Renato Archer Information Technology Center University of Belgrade Universidade Estadual Paulista (UNESP) |
dc.contributor.author.fl_str_mv |
Teixeira, Guilhermina Ferreira Seleghini, Heitor Secco Bastos, Wagner Benício Jacomaci, Natalia Stojadinović, Bojan Dohčević-Mitrović, Zorana Colmati, Flavio San-Miguel, Miguel Angel Longo, Elson Zaghete, Maria Aparecida [UNESP] |
description |
Na2Nb2O6·H2O fibers were synthesized in a short time using a microwave-assisted hydrothermal method and later used as a precursor for obtaining NaNbO3 fibers with piezoelectric characteristics. The NaNbO3 fibers consist of a mix of antiferroelectric (Pbcm) and ferroelectric (P21ma) orthorhombic phases. The ferroelectric structure comprises about 87% wt of the sample, and a theoretical approach indicated that an electric field could induce an inversion in the relative stability between the most stable antiferroelectric structure and the ferroelectric one. Piezoresponse force microscopy showed that an individual fiber is composed of regions with ferroelectric domains and regions with no ferroelectric characteristics. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023-07-29T13:09:53Z 2023-07-29T13:09:53Z 2023-01-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1039/d2tc04039e Journal of Materials Chemistry C. 2050-7534 http://hdl.handle.net/11449/247218 10.1039/d2tc04039e 2-s2.0-85153253388 |
url |
http://dx.doi.org/10.1039/d2tc04039e http://hdl.handle.net/11449/247218 |
identifier_str_mv |
Journal of Materials Chemistry C. 2050-7534 10.1039/d2tc04039e 2-s2.0-85153253388 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Journal of Materials Chemistry C |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1808128509704404992 |