(-)-Kolavenic acid
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2008 |
| Outros Autores: | , , , |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Repositório Institucional da UNESP |
| DOI: | 10.1107/S1600536808014402 |
| Texto Completo: | http://dx.doi.org/10.1107/S1600536808014402 http://hdl.handle.net/11449/26164 |
Resumo: | In the two, almost identical, molecules in the asymmetric unit of the title compound [ systematic name: (E)-3-methyl-5-(1,2,4a, 5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1yl) pent-2-enoic acid], C20H32O2, the rings are trans fused. The cyclohexane ring has a chair conformation and the cyclohexene ring a distorted half-boat conformation. The two independent molecules are connected into a dimer via O-H center dot center dot center dot O hydrogen bonds. The dimers are associated into supramolecular chains along c via C-H center dot center dot center dot O contacts. |
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oai:repositorio.unesp.br:11449/26164 |
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Repositório Institucional da UNESP |
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2946 |
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(-)-Kolavenic acidIn the two, almost identical, molecules in the asymmetric unit of the title compound [ systematic name: (E)-3-methyl-5-(1,2,4a, 5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1yl) pent-2-enoic acid], C20H32O2, the rings are trans fused. The cyclohexane ring has a chair conformation and the cyclohexene ring a distorted half-boat conformation. The two independent molecules are connected into a dimer via O-H center dot center dot center dot O hydrogen bonds. The dimers are associated into supramolecular chains along c via C-H center dot center dot center dot O contacts.Univ Fed Sao Carlos, Dept Chem, BR-13565905 Sao Carlos, SP, BrazilUNESP, Inst Chem, BR-14801970 Araraquara, SP, BrazilUniv Texas San Antonio, Dept Chem, San Antonio, TX 78249 USAUNESP, Inst Chem, BR-14801970 Araraquara, SP, BrazilBlackwell PublishingUniversidade Federal de São Carlos (UFSCar)Universidade Estadual Paulista (Unesp)Univ Texas San AntonioZukerman-Schpector, JulioMadureira, Lucas SousaMessiano, Gisele B. [UNESP]Lopes, Lucia Maria Xavier [UNESP]Tiekink, Edward R. T.2014-05-20T14:20:31Z2014-05-20T14:20:31Z2008-06-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleO1114-U2480application/pdfhttp://dx.doi.org/10.1107/S1600536808014402Acta Crystallographica Section E-structure Reports Online. Oxford: Blackwell Publishing, v. 64, p. O1114-U2480, 2008.1600-5368http://hdl.handle.net/11449/2616410.1107/S1600536808014402WOS:000256441200236WOS000256441200236.pdf5981353442037051Web of Sciencereponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengActa Crystallographica Section E: Structure Reports Online0,138info:eu-repo/semantics/openAccess2023-12-01T06:12:45Zoai:repositorio.unesp.br:11449/26164Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T19:12:51.293551Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
| dc.title.none.fl_str_mv |
(-)-Kolavenic acid |
| title |
(-)-Kolavenic acid |
| spellingShingle |
(-)-Kolavenic acid (-)-Kolavenic acid Zukerman-Schpector, Julio Zukerman-Schpector, Julio |
| title_short |
(-)-Kolavenic acid |
| title_full |
(-)-Kolavenic acid |
| title_fullStr |
(-)-Kolavenic acid (-)-Kolavenic acid |
| title_full_unstemmed |
(-)-Kolavenic acid (-)-Kolavenic acid |
| title_sort |
(-)-Kolavenic acid |
| author |
Zukerman-Schpector, Julio |
| author_facet |
Zukerman-Schpector, Julio Zukerman-Schpector, Julio Madureira, Lucas Sousa Messiano, Gisele B. [UNESP] Lopes, Lucia Maria Xavier [UNESP] Tiekink, Edward R. T. Madureira, Lucas Sousa Messiano, Gisele B. [UNESP] Lopes, Lucia Maria Xavier [UNESP] Tiekink, Edward R. T. |
| author_role |
author |
| author2 |
Madureira, Lucas Sousa Messiano, Gisele B. [UNESP] Lopes, Lucia Maria Xavier [UNESP] Tiekink, Edward R. T. |
| author2_role |
author author author author |
| dc.contributor.none.fl_str_mv |
Universidade Federal de São Carlos (UFSCar) Universidade Estadual Paulista (Unesp) Univ Texas San Antonio |
| dc.contributor.author.fl_str_mv |
Zukerman-Schpector, Julio Madureira, Lucas Sousa Messiano, Gisele B. [UNESP] Lopes, Lucia Maria Xavier [UNESP] Tiekink, Edward R. T. |
| description |
In the two, almost identical, molecules in the asymmetric unit of the title compound [ systematic name: (E)-3-methyl-5-(1,2,4a, 5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1yl) pent-2-enoic acid], C20H32O2, the rings are trans fused. The cyclohexane ring has a chair conformation and the cyclohexene ring a distorted half-boat conformation. The two independent molecules are connected into a dimer via O-H center dot center dot center dot O hydrogen bonds. The dimers are associated into supramolecular chains along c via C-H center dot center dot center dot O contacts. |
| publishDate |
2008 |
| dc.date.none.fl_str_mv |
2008-06-01 2014-05-20T14:20:31Z 2014-05-20T14:20:31Z |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1107/S1600536808014402 Acta Crystallographica Section E-structure Reports Online. Oxford: Blackwell Publishing, v. 64, p. O1114-U2480, 2008. 1600-5368 http://hdl.handle.net/11449/26164 10.1107/S1600536808014402 WOS:000256441200236 WOS000256441200236.pdf 5981353442037051 |
| url |
http://dx.doi.org/10.1107/S1600536808014402 http://hdl.handle.net/11449/26164 |
| identifier_str_mv |
Acta Crystallographica Section E-structure Reports Online. Oxford: Blackwell Publishing, v. 64, p. O1114-U2480, 2008. 1600-5368 10.1107/S1600536808014402 WOS:000256441200236 WOS000256441200236.pdf 5981353442037051 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
Acta Crystallographica Section E: Structure Reports Online 0,138 |
| dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
O1114-U2480 application/pdf |
| dc.publisher.none.fl_str_mv |
Blackwell Publishing |
| publisher.none.fl_str_mv |
Blackwell Publishing |
| dc.source.none.fl_str_mv |
Web of Science reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
| instname_str |
Universidade Estadual Paulista (UNESP) |
| instacron_str |
UNESP |
| institution |
UNESP |
| reponame_str |
Repositório Institucional da UNESP |
| collection |
Repositório Institucional da UNESP |
| repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
| repository.mail.fl_str_mv |
|
| _version_ |
1822182366721867776 |
| dc.identifier.doi.none.fl_str_mv |
10.1107/S1600536808014402 |