Critérios mineralógicos, químicos e físicos para uso agronômico de pó de basalto hidrotermalizado no sul do Brasil

Detalhes bibliográficos
Autor(a) principal: Korchagin, Jackson
Data de Publicação: 2018
Tipo de documento: Tese
Idioma: por
Título da fonte: Biblioteca de teses e dissertações da Universidade de Passo Fundo (BDTD UPF)
Texto Completo: http://tede.upf.br:8080/jspui/handle/tede/1766
Resumo: The exploitation of amethyst geodes in the region of Ametista do Sul, Rio Grande do Sul state, southern Brazil, generates a large amount of hydrothermal basalt tailings, which accumulate alongside the mines. This material contains clay minerals such as smectite and celadonite types which makes it promising as a remineralizer for agricultural soils. The following objectives were established to evaluate the potential use of this material in agriculture: i) assessment of the mineralogical and geochemical variability of hydrothermal basalt in the horizontal profile of the main geode exploration lava flow, in the region of Ametista do Sul; ii) determination of the solubility of chemical elements of agricultural interest from the hydrothermal basalt powder by using different extraction methods; and iii) assessment of the chemical and mineralogical characteristics of a Ultisol under native field after applying hydrothermalized basalt powder, as well as pasture production and nutrient export by plants. Hydrothermal basalt consists of plagioclases, clinopyroxenes, opaque minerals and apatite as accessory mineral, and is significantly altered for clay minerals in the matrix or filling vesicles. The mineral assemblage and the geochemical composition of the hydrothermalized basalt are similar along the horizontal profile. However, the basalt located near geodes is slightly more altered into clay minerals than the basalt composing the rest of the flow. The identified clay minerals are predominantly of the smectite and celadonite types. Among the methods tested to evaluate ion solubilization, those using ion exchange or solubilization in water extracted low percentages of calcium, magnesium, phosphorus, potassium and sodium from the hydrothermalized basalt powder. The method using acidic extractors increased the solubilization of calcium, magnesium and phosphorus, but potassium and sodium contents in solution did not exceed 3% of the total contents. Phosphorus was the most solubilized element, with release of up to 60% of the total contents, and 2% citric acid was the most efficient reagent for ion solubilization. Field tests showed changes in soil chemical and mineralogical characteristics, but at low magnitude. The application of increasing doses of basalt powder was responsible for increased available levels of phosphorus and copper in the soil, increased water pH but reduced potential acidity and potential cation exchange capacity of the soil. According to the mineralogical analyzes, increase in amounts of vermiculite in the soil clay fraction, that received hydrothermalized basalt powder application, was presumed. Dry mass production from the pasture had a linear and positive increase with the application of basalt powder but the increase in productivity was generally of low magnitude for the periods evaluated. Lastly, according to the amount of nutrients exported by the pasture during the research period, the concentration of the main nutrients contained in basalt powder is enough to supply partially or completely plant needs and exportation without depleting soil mineral reserves.
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spelling Bortoluzzi, Edson Campanhola69335885053http://lattes.cnpq.br/967658497233829805592370903http://lattes.cnpq.br/7922074477894938Korchagin, Jackson2019-08-23T19:35:51Z2018-03-23KORCHAGIN, Jackson. Critérios mineralógicos, químicos e físicos para uso agronômico de pó de basalto hidrotermalizado no sul do Brasil. 2018. 172 f. Tese (Doutorado em Agronomia) - Universidade de Passo Fundo, Passo Fundo, RS, 2018.http://tede.upf.br:8080/jspui/handle/tede/1766The exploitation of amethyst geodes in the region of Ametista do Sul, Rio Grande do Sul state, southern Brazil, generates a large amount of hydrothermal basalt tailings, which accumulate alongside the mines. This material contains clay minerals such as smectite and celadonite types which makes it promising as a remineralizer for agricultural soils. The following objectives were established to evaluate the potential use of this material in agriculture: i) assessment of the mineralogical and geochemical variability of hydrothermal basalt in the horizontal profile of the main geode exploration lava flow, in the region of Ametista do Sul; ii) determination of the solubility of chemical elements of agricultural interest from the hydrothermal basalt powder by using different extraction methods; and iii) assessment of the chemical and mineralogical characteristics of a Ultisol under native field after applying hydrothermalized basalt powder, as well as pasture production and nutrient export by plants. Hydrothermal basalt consists of plagioclases, clinopyroxenes, opaque minerals and apatite as accessory mineral, and is significantly altered for clay minerals in the matrix or filling vesicles. The mineral assemblage and the geochemical composition of the hydrothermalized basalt are similar along the horizontal profile. However, the basalt located near geodes is slightly more altered into clay minerals than the basalt composing the rest of the flow. The identified clay minerals are predominantly of the smectite and celadonite types. Among the methods tested to evaluate ion solubilization, those using ion exchange or solubilization in water extracted low percentages of calcium, magnesium, phosphorus, potassium and sodium from the hydrothermalized basalt powder. The method using acidic extractors increased the solubilization of calcium, magnesium and phosphorus, but potassium and sodium contents in solution did not exceed 3% of the total contents. Phosphorus was the most solubilized element, with release of up to 60% of the total contents, and 2% citric acid was the most efficient reagent for ion solubilization. Field tests showed changes in soil chemical and mineralogical characteristics, but at low magnitude. The application of increasing doses of basalt powder was responsible for increased available levels of phosphorus and copper in the soil, increased water pH but reduced potential acidity and potential cation exchange capacity of the soil. According to the mineralogical analyzes, increase in amounts of vermiculite in the soil clay fraction, that received hydrothermalized basalt powder application, was presumed. Dry mass production from the pasture had a linear and positive increase with the application of basalt powder but the increase in productivity was generally of low magnitude for the periods evaluated. Lastly, according to the amount of nutrients exported by the pasture during the research period, the concentration of the main nutrients contained in basalt powder is enough to supply partially or completely plant needs and exportation without depleting soil mineral reserves.L'exploitation des géodes d'améthyste dans la région d'Ametista do Sul, État du Rio Grande do Sul, dans le sud du Brésil, génère une grande quantité de déchets de basalte hydrotermalisé qui s'accumule à côté des mines. Ce matériau contient une quantité élevée de minéraux argileux comme la smectite et la céladonite, ce qui le rend prometteur pour l'utilisation pour reminéraliser des sols agricoles. Afin d'évaluer le potentiel pour l'utilisation de ce matériel dans l'agriculture les objectifs de ce travail sont les suivants : i) évaluer la variabilité minéralogique et géochimique du basalte hydrothermalisé dans le profil horizontal de la principale coulée d'exploitation des géodes dans la région d'Ametista do Sul ; ii) déterminer la solubilité des éléments chimiques d'intérêt agricole à partir de la poudre de basalte hydrothermalisé en utilisant différentes méthodes d'extraction ; iii) évaluer les caractéristiques chimiques et minéralogiques d'un Ultisol sous pâturages naturels après l'application de poudre de basalte hydrothermalisé, ainsi que la production du pâturage et l’exportation de nutriments par les plantes. Le basalte hydrothermalisé se compose de plagioclases, de pyroxènes, de minéraux opaques et d'apatite en tant que minéral accessoire. Le basalte est fortement altéré et comporte des minéraux argileux dans la matrice ou en remplissage des vésicules. L’assemblage minéralogique et la composition chimique du basalte hydrothermalisé sont similaires le long du profil horizontal. Cependant, le basalte situé près des géodes est légèrement plus altéré que le basalte qui compose le reste de la coulée. Les minéraux argileux identifiés sont principalement de type smectite et céladonite. Parmi les méthodes testées pour évaluer la solubilisation des ions, celles utilisant des mécanismes d'échange d'ions ou de solubilisation dans l'eau ont extrait de faibles pourcentages de calcium, magnésium, phosphore, potassium et sodium de la poudre de basalte hydrothermal. L'utilisation d'extracteurs acides augmente la solubilisation du calcium, du magnésium et du phosphore, cependant, les teneurs en potassium et en sodium en solution ne dépassent pas 3% de la teneur totale. Le phosphore était l'élément le plus solubilisé, avec une libération pouvant atteindre 60% du contenu total, et l'acide citrique 2% est le réactif le plus efficace pour la solubilisation des ions. Pour les essais sur le terrain, des améliorations ont été observées dans les caractéristiques chimiques et minéralogiques du sol, mais de faible ampleur. L'application de doses croissantes de poudre de basalte augmente les niveaux de phosphore et de cuivre disponibles dans le sol, le pH de l'eau et réduit l'acidité potentielle et la capacité potentielle d'échange de cations du sol. Selon les analyses minéralogiques, on suppose une augmentation des quantités de vermiculite dans la fraction argileuse du sol ayant reçu l’application de poudre de basalte hydrothermalisée. La production de matière sèche du pâturage a une augmentation linéaire et positive avec l'utilisation de la poudre de basalte, cependant, l'augmentation de la productivité est généralement de faible ampleur pour les périodes évaluées. Enfin, selon la quantité d'éléments nutritifs exportés par le pâturage au cours de la période d'étude, la concentration des principaux éléments nutritifs contenus dans la poudre de basalte est suffisante pour fournir tout ou partie aux besoins des plantes, sans épuiser les réserves minérales du sol.A exploração de geodos de ametista na região de Ametista do Sul, estado do Rio Grande do Sul, no sul do Brasil, gera uma grande quantidade de rejeitos de basalto hidrotermalizado, que se acumulam ao lado das minas. Esse material possui uma quantidade considerável de argilominerais do tipo esmectita e celadonita, o que o torna promissor para uso como remineralizador de solos agrícolas. Para avaliar o potencial de uso desse material na agricultura, foram estabelecidos os seguintes objetivos: i) avaliar a variabilidade mineralógica e geoquímica do basalto hidrotermalizado no perfil horizontal do principal fluxo de exploração de geodos, na região de Ametista do Sul; ii) determinar a capacidade de solubilização de elementos químicos de interesse agrícola a partir do pó de basalto hidrotermalizado, utilizando diferentes métodos de extração e; iii) avaliar as características químicas e mineralógicas de um Argissolo Vermelho-Amarelo alumínico sob campo nativo após à aplicação de pó de basalto hidrotermalizado, bem como a produção de pastagem e a exportação de nutrientes pelas plantas. O basalto hidrotermalizado é constituído por plagioclásios, clinopiroxênios, minerais opacos e apatita como mineral acessório, e está bastante alterado para argilominerais na matriz ou preenchendo vesículas. A assembleia mineralógica e a composição geoquímica do basalto hidrotermalizado são semelhantes ao longo do perfil horizontal. No entanto, o basalto localizado próximo aos geodos é ligeiramente mais alterado para argilominerais do que o basalto que compõe o restante do fluxo. Os argilominerais identificados são predominantemente do tipo esmectita e celadonita. Entre os métodos testados para avaliar a solubilização de íons, os que usam mecanismos de troca iônica ou solubilização em água extraíram baixas quantidades de cálcio, magnésio, fósforo, potássio e sódio do pó de basalto hidrotermalizado. O uso dos extratores ácidos, aumentou a solubilização de cálcio, magnésio e fósforo, no entanto, os teores de potássio e sódio em solução não ultrapassaram 3% dos teores totais. Fósforo foi o elemento mais solubilizado, com liberação de até 60% dos teores totais, e ácido cítrico 2% foi o reagente mais eficiente para a solubilização de íons. Para os testes a campo, foram observadas melhorias nas características químicas e mineralógicas do solo, porém em baixa magnitude. A aplicação de doses crescentes de pó de basalto aumentou os teores de fósforo e cobre disponíveis no solo, o pH em água, e reduziu a acidez potencial e a capacidade de troca de cátions potencial do solo. De acordo com as análises mineralógicas, presume-se aumento nas quantidades de vermiculita na fração argila do solo que recebeu a aplicação de pó de basalto hidrotermalizado. A produção de massa seca da pastagem teve um aumento linear e positivo com o uso do pó de basalto, no entanto, o incremento em produtividade foi em geral de baixa magnitude nos períodos avaliados. Por fim, segundo as quantidades de nutrientes exportadas pela pastagem durante o período de estudo, a concentração dos principais nutrientes contidos no pó de basalto é suficiente para suprir total ou parcialmente a necessidade das plantas, sem esgotar as reservas minerais do solo.Submitted by Aline Rezende (alinerezende@upf.br) on 2019-08-23T19:35:51Z No. of bitstreams: 1 2019JacksonKorchagin.pdf: 3829838 bytes, checksum: 507bed84fff18c71225e88554c86362b (MD5)Made available in DSpace on 2019-08-23T19:35:51Z (GMT). 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dc.title.por.fl_str_mv Critérios mineralógicos, químicos e físicos para uso agronômico de pó de basalto hidrotermalizado no sul do Brasil
dc.title.alternative.eng.fl_str_mv Mineralogical, chemical and physical criteria for agronomic use of hydrothermalized basalt powder in southern Brazil
dc.title.alternative.fra.fl_str_mv Critères minéralogiques, chimiques et physiques pour l'utilisation agronomique de la poudre de basalte hydrothermalisée dans le sud du Brésil
title Critérios mineralógicos, químicos e físicos para uso agronômico de pó de basalto hidrotermalizado no sul do Brasil
spellingShingle Critérios mineralógicos, químicos e físicos para uso agronômico de pó de basalto hidrotermalizado no sul do Brasil
Korchagin, Jackson
Basalto
Minerais de argila
Mineralogia do solo
Solos - Produtividade
CIENCIAS AGRARIAS::AGRONOMIA
title_short Critérios mineralógicos, químicos e físicos para uso agronômico de pó de basalto hidrotermalizado no sul do Brasil
title_full Critérios mineralógicos, químicos e físicos para uso agronômico de pó de basalto hidrotermalizado no sul do Brasil
title_fullStr Critérios mineralógicos, químicos e físicos para uso agronômico de pó de basalto hidrotermalizado no sul do Brasil
title_full_unstemmed Critérios mineralógicos, químicos e físicos para uso agronômico de pó de basalto hidrotermalizado no sul do Brasil
title_sort Critérios mineralógicos, químicos e físicos para uso agronômico de pó de basalto hidrotermalizado no sul do Brasil
author Korchagin, Jackson
author_facet Korchagin, Jackson
author_role author
dc.contributor.advisor1.fl_str_mv Bortoluzzi, Edson Campanhola
dc.contributor.advisor1ID.fl_str_mv 69335885053
dc.contributor.advisor1Lattes.fl_str_mv http://lattes.cnpq.br/9676584972338298
dc.contributor.authorID.fl_str_mv 05592370903
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/7922074477894938
dc.contributor.author.fl_str_mv Korchagin, Jackson
contributor_str_mv Bortoluzzi, Edson Campanhola
dc.subject.por.fl_str_mv Basalto
Minerais de argila
Mineralogia do solo
Solos - Produtividade
topic Basalto
Minerais de argila
Mineralogia do solo
Solos - Produtividade
CIENCIAS AGRARIAS::AGRONOMIA
dc.subject.cnpq.fl_str_mv CIENCIAS AGRARIAS::AGRONOMIA
description The exploitation of amethyst geodes in the region of Ametista do Sul, Rio Grande do Sul state, southern Brazil, generates a large amount of hydrothermal basalt tailings, which accumulate alongside the mines. This material contains clay minerals such as smectite and celadonite types which makes it promising as a remineralizer for agricultural soils. The following objectives were established to evaluate the potential use of this material in agriculture: i) assessment of the mineralogical and geochemical variability of hydrothermal basalt in the horizontal profile of the main geode exploration lava flow, in the region of Ametista do Sul; ii) determination of the solubility of chemical elements of agricultural interest from the hydrothermal basalt powder by using different extraction methods; and iii) assessment of the chemical and mineralogical characteristics of a Ultisol under native field after applying hydrothermalized basalt powder, as well as pasture production and nutrient export by plants. Hydrothermal basalt consists of plagioclases, clinopyroxenes, opaque minerals and apatite as accessory mineral, and is significantly altered for clay minerals in the matrix or filling vesicles. The mineral assemblage and the geochemical composition of the hydrothermalized basalt are similar along the horizontal profile. However, the basalt located near geodes is slightly more altered into clay minerals than the basalt composing the rest of the flow. The identified clay minerals are predominantly of the smectite and celadonite types. Among the methods tested to evaluate ion solubilization, those using ion exchange or solubilization in water extracted low percentages of calcium, magnesium, phosphorus, potassium and sodium from the hydrothermalized basalt powder. The method using acidic extractors increased the solubilization of calcium, magnesium and phosphorus, but potassium and sodium contents in solution did not exceed 3% of the total contents. Phosphorus was the most solubilized element, with release of up to 60% of the total contents, and 2% citric acid was the most efficient reagent for ion solubilization. Field tests showed changes in soil chemical and mineralogical characteristics, but at low magnitude. The application of increasing doses of basalt powder was responsible for increased available levels of phosphorus and copper in the soil, increased water pH but reduced potential acidity and potential cation exchange capacity of the soil. According to the mineralogical analyzes, increase in amounts of vermiculite in the soil clay fraction, that received hydrothermalized basalt powder application, was presumed. Dry mass production from the pasture had a linear and positive increase with the application of basalt powder but the increase in productivity was generally of low magnitude for the periods evaluated. Lastly, according to the amount of nutrients exported by the pasture during the research period, the concentration of the main nutrients contained in basalt powder is enough to supply partially or completely plant needs and exportation without depleting soil mineral reserves.
publishDate 2018
dc.date.issued.fl_str_mv 2018-03-23
dc.date.accessioned.fl_str_mv 2019-08-23T19:35:51Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/doctoralThesis
format doctoralThesis
status_str publishedVersion
dc.identifier.citation.fl_str_mv KORCHAGIN, Jackson. Critérios mineralógicos, químicos e físicos para uso agronômico de pó de basalto hidrotermalizado no sul do Brasil. 2018. 172 f. Tese (Doutorado em Agronomia) - Universidade de Passo Fundo, Passo Fundo, RS, 2018.
dc.identifier.uri.fl_str_mv http://tede.upf.br:8080/jspui/handle/tede/1766
identifier_str_mv KORCHAGIN, Jackson. Critérios mineralógicos, químicos e físicos para uso agronômico de pó de basalto hidrotermalizado no sul do Brasil. 2018. 172 f. Tese (Doutorado em Agronomia) - Universidade de Passo Fundo, Passo Fundo, RS, 2018.
url http://tede.upf.br:8080/jspui/handle/tede/1766
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dc.publisher.program.fl_str_mv Programa de Pós-Graduação em Agronomia
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dc.publisher.department.fl_str_mv Faculdade de Agronomia e Medicina Veterinária – FAMV
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