Production of anhydrous ammonia and aqua ammonia enriched in 15N from (15NH4)2SO4
Autor(a) principal: | |
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Data de Publicação: | 2002 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Scientia Agrícola (Online) |
Texto Completo: | https://www.revistas.usp.br/sa/article/view/21773 |
Resumo: | In Brazil aqua ammonia is an important fertilizer for soil fertilization of the sugarcane crop. The efficiency of the use of nitrogen fertilizers (EUF) by crops is a factor that has influence on agricultural productivity. The isotope technique of 15N labeled fertilizer is used for EUF determinations. In this paper the methods for production, in a same system, of anhydrous ammonia (15NH3) and aqua ammonia (15NH3aq), both enriched in the heavy stable isotope of nitrogen, using ammonium sulfate (AS) labeled with 15N [(15NH4)2SO4 ] as raw material, are presented. The parameters evaluated in the processes were: temperature (60, 70 e 75°C); reaction time (90, 120, 150, 165, 210 e 255 minutes), flow of N2 carrier gas (140, 180 e 220 mL min-1) and mass of AS (40, 72.6, 106, 132 e 200 g). The best conditions related to the production of the 15NH3 e 15NH3aq, were obtained at a temperature of 70°C, flow of N2 carrier gas of 180 mL min-1 and a reaction time of 210 minutes. The N concentration of the 15NH3aq was between 15-20% (w/w), with the 15NH3aq production of 280 mL with concentrations around 15% (w/w) for each batch. The overall yield of the process ranged from 91 to 99% and was directly related to the mass of AS. The unrecovered 15NH3 was very low. |
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Production of anhydrous ammonia and aqua ammonia enriched in 15N from (15NH4)2SO4 Produção de amônia anidra e aquamônia enriquecida em 15N a partir de (15NH4)2SO4 ammonia-15Nnitrogen-15Nstable isotopeamônia-15Nnitrogênio-15isótopo estável In Brazil aqua ammonia is an important fertilizer for soil fertilization of the sugarcane crop. The efficiency of the use of nitrogen fertilizers (EUF) by crops is a factor that has influence on agricultural productivity. The isotope technique of 15N labeled fertilizer is used for EUF determinations. In this paper the methods for production, in a same system, of anhydrous ammonia (15NH3) and aqua ammonia (15NH3aq), both enriched in the heavy stable isotope of nitrogen, using ammonium sulfate (AS) labeled with 15N [(15NH4)2SO4 ] as raw material, are presented. The parameters evaluated in the processes were: temperature (60, 70 e 75°C); reaction time (90, 120, 150, 165, 210 e 255 minutes), flow of N2 carrier gas (140, 180 e 220 mL min-1) and mass of AS (40, 72.6, 106, 132 e 200 g). The best conditions related to the production of the 15NH3 e 15NH3aq, were obtained at a temperature of 70°C, flow of N2 carrier gas of 180 mL min-1 and a reaction time of 210 minutes. The N concentration of the 15NH3aq was between 15-20% (w/w), with the 15NH3aq production of 280 mL with concentrations around 15% (w/w) for each batch. The overall yield of the process ranged from 91 to 99% and was directly related to the mass of AS. The unrecovered 15NH3 was very low. No Brasil, a aquamônia vem sendo utilizada como fertilizante nitrogenado, especialmente na cultura de cana de açúcar. Entre os fatores que influenciam a produtividade das culturas agrícolas, está a eficiência de utilização de fertilizantes nitrogenados (EUF), sendo a técnica isotópica com 15N empregada em investigações dessa natureza. Este trabalho procurou estabelecer métodos de produção de amônia anidra (15NH3) e aquosa (15NH3aq), enriquecidas em 15N, em um único sistema, a partir do sulfato de amônio previamente enriquecido no mesmo isótopo. O processo de produção de 15NH3 e 15NH3aq foi avaliado em função dos fatores: temperatura (60, 70 e 75ºC) e tempo de reação (90, 120, 150, 165, 210 e 255 minutos), fluxo de gás de arraste (140; 180 e 220 mL min-1 de N2) e massa de sulfato de amônio utilizada na reação (40; 72,6; 106; 132 e 200 g). As melhores condições com relação à produção de 15NH3 e 15NH3aq foram proporcionadas pela temperatura de 70ºC, fluxo de gás de arraste de 180 mL min-1 de N2 e tempo de reação de 210 minutos. O teor de N na 15NH3aq variou de 15 a 20% (m/m) e o sistema apresentou capacidade de produção de aproximadamente 280 mL de 15NH3aq com concentração de 15% (m/m) por batelada. O processo global apresentou rendimento na faixa de 91 a 99%, em função da massa de (15NH4)2SO4 utilizada, sendo as perdas de 15N desprezíveis. Universidade de São Paulo. Escola Superior de Agricultura Luiz de Queiroz2002-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://www.revistas.usp.br/sa/article/view/2177310.1590/S0103-90162002000300028Scientia Agricola; v. 59 n. 3 (2002); 595-603Scientia Agricola; Vol. 59 No. 3 (2002); 595-603Scientia Agricola; Vol. 59 Núm. 3 (2002); 595-6031678-992X0103-9016reponame:Scientia Agrícola (Online)instname:Universidade de São Paulo (USP)instacron:USPporhttps://www.revistas.usp.br/sa/article/view/21773/23797Copyright (c) 2015 Scientia Agricolainfo:eu-repo/semantics/openAccessBendassolli, José AlbertinoTrivelin, Paulo Cesar OcheuzeIgnoto, Raquel de Fátima2015-07-07T12:31:47Zoai:revistas.usp.br:article/21773Revistahttp://revistas.usp.br/sa/indexPUBhttps://old.scielo.br/oai/scielo-oai.phpscientia@usp.br||alleoni@usp.br1678-992X0103-9016opendoar:2015-07-07T12:31:47Scientia Agrícola (Online) - Universidade de São Paulo (USP)false |
dc.title.none.fl_str_mv |
Production of anhydrous ammonia and aqua ammonia enriched in 15N from (15NH4)2SO4 Produção de amônia anidra e aquamônia enriquecida em 15N a partir de (15NH4)2SO4 |
title |
Production of anhydrous ammonia and aqua ammonia enriched in 15N from (15NH4)2SO4 |
spellingShingle |
Production of anhydrous ammonia and aqua ammonia enriched in 15N from (15NH4)2SO4 Bendassolli, José Albertino ammonia-15N nitrogen-15N stable isotope amônia-15N nitrogênio-15 isótopo estável |
title_short |
Production of anhydrous ammonia and aqua ammonia enriched in 15N from (15NH4)2SO4 |
title_full |
Production of anhydrous ammonia and aqua ammonia enriched in 15N from (15NH4)2SO4 |
title_fullStr |
Production of anhydrous ammonia and aqua ammonia enriched in 15N from (15NH4)2SO4 |
title_full_unstemmed |
Production of anhydrous ammonia and aqua ammonia enriched in 15N from (15NH4)2SO4 |
title_sort |
Production of anhydrous ammonia and aqua ammonia enriched in 15N from (15NH4)2SO4 |
author |
Bendassolli, José Albertino |
author_facet |
Bendassolli, José Albertino Trivelin, Paulo Cesar Ocheuze Ignoto, Raquel de Fátima |
author_role |
author |
author2 |
Trivelin, Paulo Cesar Ocheuze Ignoto, Raquel de Fátima |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Bendassolli, José Albertino Trivelin, Paulo Cesar Ocheuze Ignoto, Raquel de Fátima |
dc.subject.por.fl_str_mv |
ammonia-15N nitrogen-15N stable isotope amônia-15N nitrogênio-15 isótopo estável |
topic |
ammonia-15N nitrogen-15N stable isotope amônia-15N nitrogênio-15 isótopo estável |
description |
In Brazil aqua ammonia is an important fertilizer for soil fertilization of the sugarcane crop. The efficiency of the use of nitrogen fertilizers (EUF) by crops is a factor that has influence on agricultural productivity. The isotope technique of 15N labeled fertilizer is used for EUF determinations. In this paper the methods for production, in a same system, of anhydrous ammonia (15NH3) and aqua ammonia (15NH3aq), both enriched in the heavy stable isotope of nitrogen, using ammonium sulfate (AS) labeled with 15N [(15NH4)2SO4 ] as raw material, are presented. The parameters evaluated in the processes were: temperature (60, 70 e 75°C); reaction time (90, 120, 150, 165, 210 e 255 minutes), flow of N2 carrier gas (140, 180 e 220 mL min-1) and mass of AS (40, 72.6, 106, 132 e 200 g). The best conditions related to the production of the 15NH3 e 15NH3aq, were obtained at a temperature of 70°C, flow of N2 carrier gas of 180 mL min-1 and a reaction time of 210 minutes. The N concentration of the 15NH3aq was between 15-20% (w/w), with the 15NH3aq production of 280 mL with concentrations around 15% (w/w) for each batch. The overall yield of the process ranged from 91 to 99% and was directly related to the mass of AS. The unrecovered 15NH3 was very low. |
publishDate |
2002 |
dc.date.none.fl_str_mv |
2002-09-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://www.revistas.usp.br/sa/article/view/21773 10.1590/S0103-90162002000300028 |
url |
https://www.revistas.usp.br/sa/article/view/21773 |
identifier_str_mv |
10.1590/S0103-90162002000300028 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
https://www.revistas.usp.br/sa/article/view/21773/23797 |
dc.rights.driver.fl_str_mv |
Copyright (c) 2015 Scientia Agricola info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
Copyright (c) 2015 Scientia Agricola |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade de São Paulo. Escola Superior de Agricultura Luiz de Queiroz |
publisher.none.fl_str_mv |
Universidade de São Paulo. Escola Superior de Agricultura Luiz de Queiroz |
dc.source.none.fl_str_mv |
Scientia Agricola; v. 59 n. 3 (2002); 595-603 Scientia Agricola; Vol. 59 No. 3 (2002); 595-603 Scientia Agricola; Vol. 59 Núm. 3 (2002); 595-603 1678-992X 0103-9016 reponame:Scientia Agrícola (Online) instname:Universidade de São Paulo (USP) instacron:USP |
instname_str |
Universidade de São Paulo (USP) |
instacron_str |
USP |
institution |
USP |
reponame_str |
Scientia Agrícola (Online) |
collection |
Scientia Agrícola (Online) |
repository.name.fl_str_mv |
Scientia Agrícola (Online) - Universidade de São Paulo (USP) |
repository.mail.fl_str_mv |
scientia@usp.br||alleoni@usp.br |
_version_ |
1787713253242044416 |