Photodegradation of Rhodamine B catalyzed by ZnO pellets
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Cerâmica (São Paulo. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132019000500047 |
Resumo: | Abstract This paper describes the development of ZnO semiconductors applied as photocatalysts for the degradation of water contaminants, with the shape of ceramic pellets thick enough to maintain their structures, prepared by slip casting and sintering. The samples presented porosities around 40% and densities around 3.4 g/cm3, which represented about 61% of the theoretical density of ZnO. After obtaining the ceramic samples, the degradation of Rhodamine B dye by photocatalysis was evaluated in six cycles of degradation. After the cycles, changes in the surface of the samples were verified, possibly due to leaching during photocatalysis since they presented mean grain sizes of 0.61 μm before and 0.36 μm after the photocatalysis. The ceramic ZnO samples were able to satisfactorily degrade Rhodamine B for several cycles, resulting in successful reuse of photocatalysts and increased facility of removing the photocatalysts from the medium after degradation compared to powders in suspensions. |
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Cerâmica (São Paulo. Online) |
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|
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Photodegradation of Rhodamine B catalyzed by ZnO pelletsslip castingsemiconductorsphotocatalysisRhodamine BZnOAbstract This paper describes the development of ZnO semiconductors applied as photocatalysts for the degradation of water contaminants, with the shape of ceramic pellets thick enough to maintain their structures, prepared by slip casting and sintering. The samples presented porosities around 40% and densities around 3.4 g/cm3, which represented about 61% of the theoretical density of ZnO. After obtaining the ceramic samples, the degradation of Rhodamine B dye by photocatalysis was evaluated in six cycles of degradation. After the cycles, changes in the surface of the samples were verified, possibly due to leaching during photocatalysis since they presented mean grain sizes of 0.61 μm before and 0.36 μm after the photocatalysis. The ceramic ZnO samples were able to satisfactorily degrade Rhodamine B for several cycles, resulting in successful reuse of photocatalysts and increased facility of removing the photocatalysts from the medium after degradation compared to powders in suspensions.Associação Brasileira de Cerâmica2019-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132019000500047Cerâmica v.65 suppl.1 2019reponame:Cerâmica (São Paulo. Online)instname:Universidade de São Paulo (USP)instacron:USP10.1590/0366-6913201965s12609info:eu-repo/semantics/openAccessRuellas,T. M. O.Domingos,G. H. S.Peçanha,L. O. O.Maestrelli,S. C.Giraldi,T. R.eng2019-03-18T00:00:00Zoai:scielo:S0366-69132019000500047Revistahttps://www.scielo.br/j/ce/PUBhttps://old.scielo.br/oai/scielo-oai.phpceram.abc@gmail.com||ceram.abc@gmail.com1678-45530366-6913opendoar:2019-03-18T00:00Cerâmica (São Paulo. Online) - Universidade de São Paulo (USP)false |
dc.title.none.fl_str_mv |
Photodegradation of Rhodamine B catalyzed by ZnO pellets |
title |
Photodegradation of Rhodamine B catalyzed by ZnO pellets |
spellingShingle |
Photodegradation of Rhodamine B catalyzed by ZnO pellets Ruellas,T. M. O. slip casting semiconductors photocatalysis Rhodamine B ZnO |
title_short |
Photodegradation of Rhodamine B catalyzed by ZnO pellets |
title_full |
Photodegradation of Rhodamine B catalyzed by ZnO pellets |
title_fullStr |
Photodegradation of Rhodamine B catalyzed by ZnO pellets |
title_full_unstemmed |
Photodegradation of Rhodamine B catalyzed by ZnO pellets |
title_sort |
Photodegradation of Rhodamine B catalyzed by ZnO pellets |
author |
Ruellas,T. M. O. |
author_facet |
Ruellas,T. M. O. Domingos,G. H. S. Peçanha,L. O. O. Maestrelli,S. C. Giraldi,T. R. |
author_role |
author |
author2 |
Domingos,G. H. S. Peçanha,L. O. O. Maestrelli,S. C. Giraldi,T. R. |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Ruellas,T. M. O. Domingos,G. H. S. Peçanha,L. O. O. Maestrelli,S. C. Giraldi,T. R. |
dc.subject.por.fl_str_mv |
slip casting semiconductors photocatalysis Rhodamine B ZnO |
topic |
slip casting semiconductors photocatalysis Rhodamine B ZnO |
description |
Abstract This paper describes the development of ZnO semiconductors applied as photocatalysts for the degradation of water contaminants, with the shape of ceramic pellets thick enough to maintain their structures, prepared by slip casting and sintering. The samples presented porosities around 40% and densities around 3.4 g/cm3, which represented about 61% of the theoretical density of ZnO. After obtaining the ceramic samples, the degradation of Rhodamine B dye by photocatalysis was evaluated in six cycles of degradation. After the cycles, changes in the surface of the samples were verified, possibly due to leaching during photocatalysis since they presented mean grain sizes of 0.61 μm before and 0.36 μm after the photocatalysis. The ceramic ZnO samples were able to satisfactorily degrade Rhodamine B for several cycles, resulting in successful reuse of photocatalysts and increased facility of removing the photocatalysts from the medium after degradation compared to powders in suspensions. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132019000500047 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132019000500047 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/0366-6913201965s12609 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Associação Brasileira de Cerâmica |
publisher.none.fl_str_mv |
Associação Brasileira de Cerâmica |
dc.source.none.fl_str_mv |
Cerâmica v.65 suppl.1 2019 reponame:Cerâmica (São Paulo. Online) instname:Universidade de São Paulo (USP) instacron:USP |
instname_str |
Universidade de São Paulo (USP) |
instacron_str |
USP |
institution |
USP |
reponame_str |
Cerâmica (São Paulo. Online) |
collection |
Cerâmica (São Paulo. Online) |
repository.name.fl_str_mv |
Cerâmica (São Paulo. Online) - Universidade de São Paulo (USP) |
repository.mail.fl_str_mv |
ceram.abc@gmail.com||ceram.abc@gmail.com |
_version_ |
1748936784629202944 |