Photodegradation of Rhodamine B catalyzed by ZnO pellets

Detalhes bibliográficos
Autor(a) principal: Ruellas,T. M. O.
Data de Publicação: 2019
Outros Autores: Domingos,G. H. S., Peçanha,L. O. O., Maestrelli,S. C., Giraldi,T. R.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Cerâmica (São Paulo. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132019000500047
Resumo: Abstract This paper describes the development of ZnO semiconductors applied as photocatalysts for the degradation of water contaminants, with the shape of ceramic pellets thick enough to maintain their structures, prepared by slip casting and sintering. The samples presented porosities around 40% and densities around 3.4 g/cm3, which represented about 61% of the theoretical density of ZnO. After obtaining the ceramic samples, the degradation of Rhodamine B dye by photocatalysis was evaluated in six cycles of degradation. After the cycles, changes in the surface of the samples were verified, possibly due to leaching during photocatalysis since they presented mean grain sizes of 0.61 μm before and 0.36 μm after the photocatalysis. The ceramic ZnO samples were able to satisfactorily degrade Rhodamine B for several cycles, resulting in successful reuse of photocatalysts and increased facility of removing the photocatalysts from the medium after degradation compared to powders in suspensions.
id USP-29_399fd49fe0c34c75c4f0fbdeda9e58cb
oai_identifier_str oai:scielo:S0366-69132019000500047
network_acronym_str USP-29
network_name_str Cerâmica (São Paulo. Online)
repository_id_str
spelling Photodegradation of Rhodamine B catalyzed by ZnO pelletsslip castingsemiconductorsphotocatalysisRhodamine BZnOAbstract This paper describes the development of ZnO semiconductors applied as photocatalysts for the degradation of water contaminants, with the shape of ceramic pellets thick enough to maintain their structures, prepared by slip casting and sintering. The samples presented porosities around 40% and densities around 3.4 g/cm3, which represented about 61% of the theoretical density of ZnO. After obtaining the ceramic samples, the degradation of Rhodamine B dye by photocatalysis was evaluated in six cycles of degradation. After the cycles, changes in the surface of the samples were verified, possibly due to leaching during photocatalysis since they presented mean grain sizes of 0.61 μm before and 0.36 μm after the photocatalysis. The ceramic ZnO samples were able to satisfactorily degrade Rhodamine B for several cycles, resulting in successful reuse of photocatalysts and increased facility of removing the photocatalysts from the medium after degradation compared to powders in suspensions.Associação Brasileira de Cerâmica2019-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132019000500047Cerâmica v.65 suppl.1 2019reponame:Cerâmica (São Paulo. Online)instname:Universidade de São Paulo (USP)instacron:USP10.1590/0366-6913201965s12609info:eu-repo/semantics/openAccessRuellas,T. M. O.Domingos,G. H. S.Peçanha,L. O. O.Maestrelli,S. C.Giraldi,T. R.eng2019-03-18T00:00:00Zoai:scielo:S0366-69132019000500047Revistahttps://www.scielo.br/j/ce/PUBhttps://old.scielo.br/oai/scielo-oai.phpceram.abc@gmail.com||ceram.abc@gmail.com1678-45530366-6913opendoar:2019-03-18T00:00Cerâmica (São Paulo. Online) - Universidade de São Paulo (USP)false
dc.title.none.fl_str_mv Photodegradation of Rhodamine B catalyzed by ZnO pellets
title Photodegradation of Rhodamine B catalyzed by ZnO pellets
spellingShingle Photodegradation of Rhodamine B catalyzed by ZnO pellets
Ruellas,T. M. O.
slip casting
semiconductors
photocatalysis
Rhodamine B
ZnO
title_short Photodegradation of Rhodamine B catalyzed by ZnO pellets
title_full Photodegradation of Rhodamine B catalyzed by ZnO pellets
title_fullStr Photodegradation of Rhodamine B catalyzed by ZnO pellets
title_full_unstemmed Photodegradation of Rhodamine B catalyzed by ZnO pellets
title_sort Photodegradation of Rhodamine B catalyzed by ZnO pellets
author Ruellas,T. M. O.
author_facet Ruellas,T. M. O.
Domingos,G. H. S.
Peçanha,L. O. O.
Maestrelli,S. C.
Giraldi,T. R.
author_role author
author2 Domingos,G. H. S.
Peçanha,L. O. O.
Maestrelli,S. C.
Giraldi,T. R.
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Ruellas,T. M. O.
Domingos,G. H. S.
Peçanha,L. O. O.
Maestrelli,S. C.
Giraldi,T. R.
dc.subject.por.fl_str_mv slip casting
semiconductors
photocatalysis
Rhodamine B
ZnO
topic slip casting
semiconductors
photocatalysis
Rhodamine B
ZnO
description Abstract This paper describes the development of ZnO semiconductors applied as photocatalysts for the degradation of water contaminants, with the shape of ceramic pellets thick enough to maintain their structures, prepared by slip casting and sintering. The samples presented porosities around 40% and densities around 3.4 g/cm3, which represented about 61% of the theoretical density of ZnO. After obtaining the ceramic samples, the degradation of Rhodamine B dye by photocatalysis was evaluated in six cycles of degradation. After the cycles, changes in the surface of the samples were verified, possibly due to leaching during photocatalysis since they presented mean grain sizes of 0.61 μm before and 0.36 μm after the photocatalysis. The ceramic ZnO samples were able to satisfactorily degrade Rhodamine B for several cycles, resulting in successful reuse of photocatalysts and increased facility of removing the photocatalysts from the medium after degradation compared to powders in suspensions.
publishDate 2019
dc.date.none.fl_str_mv 2019-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132019000500047
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132019000500047
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/0366-6913201965s12609
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Associação Brasileira de Cerâmica
publisher.none.fl_str_mv Associação Brasileira de Cerâmica
dc.source.none.fl_str_mv Cerâmica v.65 suppl.1 2019
reponame:Cerâmica (São Paulo. Online)
instname:Universidade de São Paulo (USP)
instacron:USP
instname_str Universidade de São Paulo (USP)
instacron_str USP
institution USP
reponame_str Cerâmica (São Paulo. Online)
collection Cerâmica (São Paulo. Online)
repository.name.fl_str_mv Cerâmica (São Paulo. Online) - Universidade de São Paulo (USP)
repository.mail.fl_str_mv ceram.abc@gmail.com||ceram.abc@gmail.com
_version_ 1748936784629202944