Portland clinker production with carbonatite waste and tire-derived fuel: crystallochemistry of minor and trace elements
Autor(a) principal: | |
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Data de Publicação: | 2014 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Cerâmica (São Paulo. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132014000400014 |
Resumo: | This paper presents results on the composition of Portland clinkers produced with non-conventional raw-materials and fuels, focusing on the distribution of selected trace elements. Clinkers produced with three different fuel compositions were sampled in an industrial plant, where all other parameters were kept unchanged. The fuels have chemical fingerprints, which are sulfur for petroleum coke and zinc for TDF (tire-derived fuel). Presence of carbonatite in the raw materials is indicated by high amounts of strontium and phosphorous. Electron microprobe data was used to determine occupation of structural site of both C3S and C2S, and the distribution of trace elements among clinker phases. Phosphorous occurs in similar proportions in C3S and C2S; while considering its modal abundance, C3S is its main reservoir in the clinker. Sulfur is preferentially partitioned toward C2S compared to C3S. Strontium substitutes for Ca2+ mainly in C2S and in non-silicatic phases, compared to C3S. |
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Cerâmica (São Paulo. Online) |
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Portland clinker production with carbonatite waste and tire-derived fuel: crystallochemistry of minor and trace elementstire-derived fuelcarbonatiteclinkercrystallochemistryThis paper presents results on the composition of Portland clinkers produced with non-conventional raw-materials and fuels, focusing on the distribution of selected trace elements. Clinkers produced with three different fuel compositions were sampled in an industrial plant, where all other parameters were kept unchanged. The fuels have chemical fingerprints, which are sulfur for petroleum coke and zinc for TDF (tire-derived fuel). Presence of carbonatite in the raw materials is indicated by high amounts of strontium and phosphorous. Electron microprobe data was used to determine occupation of structural site of both C3S and C2S, and the distribution of trace elements among clinker phases. Phosphorous occurs in similar proportions in C3S and C2S; while considering its modal abundance, C3S is its main reservoir in the clinker. Sulfur is preferentially partitioned toward C2S compared to C3S. Strontium substitutes for Ca2+ mainly in C2S and in non-silicatic phases, compared to C3S.Associação Brasileira de Cerâmica2014-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132014000400014Cerâmica v.60 n.356 2014reponame:Cerâmica (São Paulo. Online)instname:Universidade de São Paulo (USP)instacron:USP10.1590/S0366-69132014000400014info:eu-repo/semantics/openAccessAndrade,F. R. D.Pecchio,M.Santos,J. M. C.Kihara,Y.eng2015-01-26T00:00:00Zoai:scielo:S0366-69132014000400014Revistahttps://www.scielo.br/j/ce/PUBhttps://old.scielo.br/oai/scielo-oai.phpceram.abc@gmail.com||ceram.abc@gmail.com1678-45530366-6913opendoar:2015-01-26T00:00Cerâmica (São Paulo. Online) - Universidade de São Paulo (USP)false |
dc.title.none.fl_str_mv |
Portland clinker production with carbonatite waste and tire-derived fuel: crystallochemistry of minor and trace elements |
title |
Portland clinker production with carbonatite waste and tire-derived fuel: crystallochemistry of minor and trace elements |
spellingShingle |
Portland clinker production with carbonatite waste and tire-derived fuel: crystallochemistry of minor and trace elements Andrade,F. R. D. tire-derived fuel carbonatite clinker crystallochemistry |
title_short |
Portland clinker production with carbonatite waste and tire-derived fuel: crystallochemistry of minor and trace elements |
title_full |
Portland clinker production with carbonatite waste and tire-derived fuel: crystallochemistry of minor and trace elements |
title_fullStr |
Portland clinker production with carbonatite waste and tire-derived fuel: crystallochemistry of minor and trace elements |
title_full_unstemmed |
Portland clinker production with carbonatite waste and tire-derived fuel: crystallochemistry of minor and trace elements |
title_sort |
Portland clinker production with carbonatite waste and tire-derived fuel: crystallochemistry of minor and trace elements |
author |
Andrade,F. R. D. |
author_facet |
Andrade,F. R. D. Pecchio,M. Santos,J. M. C. Kihara,Y. |
author_role |
author |
author2 |
Pecchio,M. Santos,J. M. C. Kihara,Y. |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Andrade,F. R. D. Pecchio,M. Santos,J. M. C. Kihara,Y. |
dc.subject.por.fl_str_mv |
tire-derived fuel carbonatite clinker crystallochemistry |
topic |
tire-derived fuel carbonatite clinker crystallochemistry |
description |
This paper presents results on the composition of Portland clinkers produced with non-conventional raw-materials and fuels, focusing on the distribution of selected trace elements. Clinkers produced with three different fuel compositions were sampled in an industrial plant, where all other parameters were kept unchanged. The fuels have chemical fingerprints, which are sulfur for petroleum coke and zinc for TDF (tire-derived fuel). Presence of carbonatite in the raw materials is indicated by high amounts of strontium and phosphorous. Electron microprobe data was used to determine occupation of structural site of both C3S and C2S, and the distribution of trace elements among clinker phases. Phosphorous occurs in similar proportions in C3S and C2S; while considering its modal abundance, C3S is its main reservoir in the clinker. Sulfur is preferentially partitioned toward C2S compared to C3S. Strontium substitutes for Ca2+ mainly in C2S and in non-silicatic phases, compared to C3S. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-12-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132014000400014 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132014000400014 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0366-69132014000400014 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Associação Brasileira de Cerâmica |
publisher.none.fl_str_mv |
Associação Brasileira de Cerâmica |
dc.source.none.fl_str_mv |
Cerâmica v.60 n.356 2014 reponame:Cerâmica (São Paulo. Online) instname:Universidade de São Paulo (USP) instacron:USP |
instname_str |
Universidade de São Paulo (USP) |
instacron_str |
USP |
institution |
USP |
reponame_str |
Cerâmica (São Paulo. Online) |
collection |
Cerâmica (São Paulo. Online) |
repository.name.fl_str_mv |
Cerâmica (São Paulo. Online) - Universidade de São Paulo (USP) |
repository.mail.fl_str_mv |
ceram.abc@gmail.com||ceram.abc@gmail.com |
_version_ |
1748936783037464576 |