Structural properties of lithium borate glasses doped with rare earth ions

• Autor(a) principal: Thomazini,D.
• Data de Publicação: 2001
• Outros Autores: Lanciotti Jr.,F., Sombra,A. S. B.
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Cerâmica (São Paulo. Online)
• Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0366-69132001000200005
• topic: rare-earth; LBO; niobium; up-conversion; laser

This paper presents the study on lithium triborate glass (LBO) in the system (1-x)|3B2O3.Li2O| (x)Nb2O5 yPr3+ zYb3+ wNd3+ with 0 £ x £ 20 mol% (y, z and w in mol%). The samples were studied by Raman spectroscopy, infrared absorption and differential thermal analysis. Pr3+-doped LBO and Pr3+/Yb3+-doped LBO samples show an increase of the glass transition and crystallization temperatures and a decrease of the fusion temperature associated with the increase of the praseodymium concentration in the LBO matrix. For the Nd3+-doped LBO and Pr3+/Yb3+-doped (LBO+Nb2O5) samples, a decrease of the glass transition temperature of the samples was observed. The increase of the rare earth doping leads to an increase of the difference between the glass transition and the crystallization temperatures. From infrared analysis it was possible to identify all the modes associated to the B-O structure. The NbO6 octahedra was also identified by IR spectroscopy for samples with x=5, 10, 15 and 20 mol% and y=0.05, z=1.1 mol%. Raman spectroscopy shows the presence of boroxol rings, tetrahedral and triangular coordination for boron. For samples containing niobium, the Raman spectra show the vibrational mode associated with the Nb-O bond in the niobium octahedra (NbO6).