O método potenciométrico na determinação do H+ trocável em solos
Autor(a) principal: | |
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Data de Publicação: | 1960 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Anais da Escola Superior de Agricultura Luiz de Queiroz |
Texto Completo: | https://www.revistas.usp.br/aesalq/article/view/43177 |
Resumo: | For the determination of exchangeable hydrogen ion in soils, the authors of the presente work made the extraction with normal calcium acetate solution that may have an initial pH between 7 and 8 without altering the amount of hydrogen ion extracted. The extraction was made by shaking 5,0 grams of air dry soil with 100 ml of normal calcium acetate solution, the pH of wich was ascertained to 7,0, 7,5 and 8,0 with acetic acid, in 250 mil conical flasks for 30 minutes in a Wagner shaker (30-40 rpm). The contents of the flasks were then, filtered. A 50 ml aliquot of each of the leachate was titrated with a 0,020 N NaOH solution and the volumes consumed sodium hydroxide were ploted against pH. The titration curves thus obtained showed to be straight lines between pH 8 and 9 and parallel to the curve obtained by the titration of the blank. Two ways of locating the end point of the titration showed to be possible: the use of a pHmeter or titrimeter or the use of phenolphtalein as indicator. When using a pH meter or a titrimeter, the end point may rest in any point between pH 8 and 9, and the volume of sodium hydroxide consumed is found by comparison with a similar curve obtained by the titration of the blank. When using phenolphtalein the calcium acetate solution must have a pH below 8. |
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Anais da Escola Superior de Agricultura Luiz de Queiroz |
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O método potenciométrico na determinação do H+ trocável em solosFor the determination of exchangeable hydrogen ion in soils, the authors of the presente work made the extraction with normal calcium acetate solution that may have an initial pH between 7 and 8 without altering the amount of hydrogen ion extracted. The extraction was made by shaking 5,0 grams of air dry soil with 100 ml of normal calcium acetate solution, the pH of wich was ascertained to 7,0, 7,5 and 8,0 with acetic acid, in 250 mil conical flasks for 30 minutes in a Wagner shaker (30-40 rpm). The contents of the flasks were then, filtered. A 50 ml aliquot of each of the leachate was titrated with a 0,020 N NaOH solution and the volumes consumed sodium hydroxide were ploted against pH. The titration curves thus obtained showed to be straight lines between pH 8 and 9 and parallel to the curve obtained by the titration of the blank. Two ways of locating the end point of the titration showed to be possible: the use of a pHmeter or titrimeter or the use of phenolphtalein as indicator. When using a pH meter or a titrimeter, the end point may rest in any point between pH 8 and 9, and the volume of sodium hydroxide consumed is found by comparison with a similar curve obtained by the titration of the blank. When using phenolphtalein the calcium acetate solution must have a pH below 8.Universidade de São Paulo. Escola Superior de Agricultura Luiz de Queiroz1960-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://www.revistas.usp.br/aesalq/article/view/4317710.1590/S0071-12761960000100018Anais da Escola Superior de Agricultura Luiz de Queiroz; v. 17 (1960); 207-2162316-89350071-1276reponame:Anais da Escola Superior de Agricultura Luiz de Queirozinstname:Escola Superior de Agricultura Luiz de Queiroz (ESALQ-USP)instacron:USPporhttps://www.revistas.usp.br/aesalq/article/view/43177/46802Bergamin Filho, H.Catani, R. A.Petrin Junior, H.info:eu-repo/semantics/openAccess2012-09-18T13:31:22Zoai:revistas.usp.br:article/43177Revistahttps://www.revistas.usp.br/aesalq/about/contactPUBhttps://www.revistas.usp.br/aesalq/oaiscientia@esalq.usp.br0071-12760071-1276opendoar:2012-09-18T13:31:22Anais da Escola Superior de Agricultura Luiz de Queiroz - Escola Superior de Agricultura Luiz de Queiroz (ESALQ-USP)false |
dc.title.none.fl_str_mv |
O método potenciométrico na determinação do H+ trocável em solos |
title |
O método potenciométrico na determinação do H+ trocável em solos |
spellingShingle |
O método potenciométrico na determinação do H+ trocável em solos Bergamin Filho, H. |
title_short |
O método potenciométrico na determinação do H+ trocável em solos |
title_full |
O método potenciométrico na determinação do H+ trocável em solos |
title_fullStr |
O método potenciométrico na determinação do H+ trocável em solos |
title_full_unstemmed |
O método potenciométrico na determinação do H+ trocável em solos |
title_sort |
O método potenciométrico na determinação do H+ trocável em solos |
author |
Bergamin Filho, H. |
author_facet |
Bergamin Filho, H. Catani, R. A. Petrin Junior, H. |
author_role |
author |
author2 |
Catani, R. A. Petrin Junior, H. |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Bergamin Filho, H. Catani, R. A. Petrin Junior, H. |
description |
For the determination of exchangeable hydrogen ion in soils, the authors of the presente work made the extraction with normal calcium acetate solution that may have an initial pH between 7 and 8 without altering the amount of hydrogen ion extracted. The extraction was made by shaking 5,0 grams of air dry soil with 100 ml of normal calcium acetate solution, the pH of wich was ascertained to 7,0, 7,5 and 8,0 with acetic acid, in 250 mil conical flasks for 30 minutes in a Wagner shaker (30-40 rpm). The contents of the flasks were then, filtered. A 50 ml aliquot of each of the leachate was titrated with a 0,020 N NaOH solution and the volumes consumed sodium hydroxide were ploted against pH. The titration curves thus obtained showed to be straight lines between pH 8 and 9 and parallel to the curve obtained by the titration of the blank. Two ways of locating the end point of the titration showed to be possible: the use of a pHmeter or titrimeter or the use of phenolphtalein as indicator. When using a pH meter or a titrimeter, the end point may rest in any point between pH 8 and 9, and the volume of sodium hydroxide consumed is found by comparison with a similar curve obtained by the titration of the blank. When using phenolphtalein the calcium acetate solution must have a pH below 8. |
publishDate |
1960 |
dc.date.none.fl_str_mv |
1960-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://www.revistas.usp.br/aesalq/article/view/43177 10.1590/S0071-12761960000100018 |
url |
https://www.revistas.usp.br/aesalq/article/view/43177 |
identifier_str_mv |
10.1590/S0071-12761960000100018 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
https://www.revistas.usp.br/aesalq/article/view/43177/46802 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade de São Paulo. Escola Superior de Agricultura Luiz de Queiroz |
publisher.none.fl_str_mv |
Universidade de São Paulo. Escola Superior de Agricultura Luiz de Queiroz |
dc.source.none.fl_str_mv |
Anais da Escola Superior de Agricultura Luiz de Queiroz; v. 17 (1960); 207-216 2316-8935 0071-1276 reponame:Anais da Escola Superior de Agricultura Luiz de Queiroz instname:Escola Superior de Agricultura Luiz de Queiroz (ESALQ-USP) instacron:USP |
instname_str |
Escola Superior de Agricultura Luiz de Queiroz (ESALQ-USP) |
instacron_str |
USP |
institution |
USP |
reponame_str |
Anais da Escola Superior de Agricultura Luiz de Queiroz |
collection |
Anais da Escola Superior de Agricultura Luiz de Queiroz |
repository.name.fl_str_mv |
Anais da Escola Superior de Agricultura Luiz de Queiroz - Escola Superior de Agricultura Luiz de Queiroz (ESALQ-USP) |
repository.mail.fl_str_mv |
scientia@esalq.usp.br |
_version_ |
1797050007762763776 |