Desorption of toluene from modified clays using supercritical carbon dioxide
Autor(a) principal: | |
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Data de Publicação: | 2004 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Brazilian Journal of Chemical Engineering |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322004000400013 |
Resumo: | The main objective of this work is to study the regeneration capacity of modified clays using supercritical fluid. These modified clays are used as organic compound adsorvents. The experimental step was done using a packed column with the clay contaminated by toluene. The results obtained showed the influence of the density of the supercritical CO2 and of the organic modifier in the desorption process. These data were modeled with first- and second-order models. Better results were obtained using the second-order model. This study makes possible the scale-up of the desorption process for regeneration of solid matrices using supercritical fluids. |
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Brazilian Journal of Chemical Engineering |
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Desorption of toluene from modified clays using supercritical carbon dioxideSupercritical fluiddesorption processorganic compound adsorventsThe main objective of this work is to study the regeneration capacity of modified clays using supercritical fluid. These modified clays are used as organic compound adsorvents. The experimental step was done using a packed column with the clay contaminated by toluene. The results obtained showed the influence of the density of the supercritical CO2 and of the organic modifier in the desorption process. These data were modeled with first- and second-order models. Better results were obtained using the second-order model. This study makes possible the scale-up of the desorption process for regeneration of solid matrices using supercritical fluids.Brazilian Society of Chemical Engineering2004-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322004000400013Brazilian Journal of Chemical Engineering v.21 n.4 2004reponame:Brazilian Journal of Chemical Engineeringinstname:Associação Brasileira de Engenharia Química (ABEQ)instacron:ABEQ10.1590/S0104-66322004000400013info:eu-repo/semantics/openAccessCarneiro,D. G. P.Mendes,M. F.Coelho,G. L. V.eng2004-10-01T00:00:00Zoai:scielo:S0104-66322004000400013Revistahttps://www.scielo.br/j/bjce/https://old.scielo.br/oai/scielo-oai.phprgiudici@usp.br||rgiudici@usp.br1678-43830104-6632opendoar:2004-10-01T00:00Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)false |
dc.title.none.fl_str_mv |
Desorption of toluene from modified clays using supercritical carbon dioxide |
title |
Desorption of toluene from modified clays using supercritical carbon dioxide |
spellingShingle |
Desorption of toluene from modified clays using supercritical carbon dioxide Carneiro,D. G. P. Supercritical fluid desorption process organic compound adsorvents |
title_short |
Desorption of toluene from modified clays using supercritical carbon dioxide |
title_full |
Desorption of toluene from modified clays using supercritical carbon dioxide |
title_fullStr |
Desorption of toluene from modified clays using supercritical carbon dioxide |
title_full_unstemmed |
Desorption of toluene from modified clays using supercritical carbon dioxide |
title_sort |
Desorption of toluene from modified clays using supercritical carbon dioxide |
author |
Carneiro,D. G. P. |
author_facet |
Carneiro,D. G. P. Mendes,M. F. Coelho,G. L. V. |
author_role |
author |
author2 |
Mendes,M. F. Coelho,G. L. V. |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Carneiro,D. G. P. Mendes,M. F. Coelho,G. L. V. |
dc.subject.por.fl_str_mv |
Supercritical fluid desorption process organic compound adsorvents |
topic |
Supercritical fluid desorption process organic compound adsorvents |
description |
The main objective of this work is to study the regeneration capacity of modified clays using supercritical fluid. These modified clays are used as organic compound adsorvents. The experimental step was done using a packed column with the clay contaminated by toluene. The results obtained showed the influence of the density of the supercritical CO2 and of the organic modifier in the desorption process. These data were modeled with first- and second-order models. Better results were obtained using the second-order model. This study makes possible the scale-up of the desorption process for regeneration of solid matrices using supercritical fluids. |
publishDate |
2004 |
dc.date.none.fl_str_mv |
2004-12-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322004000400013 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322004000400013 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0104-66322004000400013 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Brazilian Society of Chemical Engineering |
publisher.none.fl_str_mv |
Brazilian Society of Chemical Engineering |
dc.source.none.fl_str_mv |
Brazilian Journal of Chemical Engineering v.21 n.4 2004 reponame:Brazilian Journal of Chemical Engineering instname:Associação Brasileira de Engenharia Química (ABEQ) instacron:ABEQ |
instname_str |
Associação Brasileira de Engenharia Química (ABEQ) |
instacron_str |
ABEQ |
institution |
ABEQ |
reponame_str |
Brazilian Journal of Chemical Engineering |
collection |
Brazilian Journal of Chemical Engineering |
repository.name.fl_str_mv |
Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ) |
repository.mail.fl_str_mv |
rgiudici@usp.br||rgiudici@usp.br |
_version_ |
1754213171841728512 |