COMPARATIVE STUDY FOR ADSORPTION OF HYDROGEN-METHANE MIXTURES ON ACTIVATED CARBON AND 5A MOLECULAR SIEVE

Detalhes bibliográficos
Autor(a) principal: Mohammad,Abbas Khalaf
Data de Publicação: 2018
Outros Autores: Sabeeh,Nawras Shareef
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Brazilian Journal of Chemical Engineering
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322018000200795
Resumo: Abstract Equilibrium adsorption isotherms were obtained experimentally by a static method for a binary component hydrogen-methane mixture on activated carbon and 5A molecular sieve adsorbents. The temperature range 303-333 K and pressure range 0 - 4 MPa were examined. Methods for predicting gas-mixture equilibrium adsorption data from the pure-component isotherms were evaluated. Extended Langmuir model correlated the adsorption of binary mixtures fairly well. In all cases mutual interference was found, that is, the amount of a given gas adsorbed at a given partial pressure was always less in the mixture than it would have been if the other gaseous component had not been present. It was found that the amount adsorbed of gases per unit bulk volume for 5A molecular sieve was higher than for activated carbon. Furthermore, 5A molecular sieve showed better adsorption characteristics than activated carbon in mass transfer properties, affinity, selectivity and heat of adsorption.
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spelling COMPARATIVE STUDY FOR ADSORPTION OF HYDROGEN-METHANE MIXTURES ON ACTIVATED CARBON AND 5A MOLECULAR SIEVEHydrogenMethaneAdsorptionEquilibriumMixtureAbstract Equilibrium adsorption isotherms were obtained experimentally by a static method for a binary component hydrogen-methane mixture on activated carbon and 5A molecular sieve adsorbents. The temperature range 303-333 K and pressure range 0 - 4 MPa were examined. Methods for predicting gas-mixture equilibrium adsorption data from the pure-component isotherms were evaluated. Extended Langmuir model correlated the adsorption of binary mixtures fairly well. In all cases mutual interference was found, that is, the amount of a given gas adsorbed at a given partial pressure was always less in the mixture than it would have been if the other gaseous component had not been present. It was found that the amount adsorbed of gases per unit bulk volume for 5A molecular sieve was higher than for activated carbon. Furthermore, 5A molecular sieve showed better adsorption characteristics than activated carbon in mass transfer properties, affinity, selectivity and heat of adsorption.Brazilian Society of Chemical Engineering2018-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322018000200795Brazilian Journal of Chemical Engineering v.35 n.2 2018reponame:Brazilian Journal of Chemical Engineeringinstname:Associação Brasileira de Engenharia Química (ABEQ)instacron:ABEQ10.1590/0104-6632.20180352s20160469info:eu-repo/semantics/openAccessMohammad,Abbas KhalafSabeeh,Nawras Shareefeng2018-09-17T00:00:00Zoai:scielo:S0104-66322018000200795Revistahttps://www.scielo.br/j/bjce/https://old.scielo.br/oai/scielo-oai.phprgiudici@usp.br||rgiudici@usp.br1678-43830104-6632opendoar:2018-09-17T00:00Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)false
dc.title.none.fl_str_mv COMPARATIVE STUDY FOR ADSORPTION OF HYDROGEN-METHANE MIXTURES ON ACTIVATED CARBON AND 5A MOLECULAR SIEVE
title COMPARATIVE STUDY FOR ADSORPTION OF HYDROGEN-METHANE MIXTURES ON ACTIVATED CARBON AND 5A MOLECULAR SIEVE
spellingShingle COMPARATIVE STUDY FOR ADSORPTION OF HYDROGEN-METHANE MIXTURES ON ACTIVATED CARBON AND 5A MOLECULAR SIEVE
Mohammad,Abbas Khalaf
Hydrogen
Methane
Adsorption
Equilibrium
Mixture
title_short COMPARATIVE STUDY FOR ADSORPTION OF HYDROGEN-METHANE MIXTURES ON ACTIVATED CARBON AND 5A MOLECULAR SIEVE
title_full COMPARATIVE STUDY FOR ADSORPTION OF HYDROGEN-METHANE MIXTURES ON ACTIVATED CARBON AND 5A MOLECULAR SIEVE
title_fullStr COMPARATIVE STUDY FOR ADSORPTION OF HYDROGEN-METHANE MIXTURES ON ACTIVATED CARBON AND 5A MOLECULAR SIEVE
title_full_unstemmed COMPARATIVE STUDY FOR ADSORPTION OF HYDROGEN-METHANE MIXTURES ON ACTIVATED CARBON AND 5A MOLECULAR SIEVE
title_sort COMPARATIVE STUDY FOR ADSORPTION OF HYDROGEN-METHANE MIXTURES ON ACTIVATED CARBON AND 5A MOLECULAR SIEVE
author Mohammad,Abbas Khalaf
author_facet Mohammad,Abbas Khalaf
Sabeeh,Nawras Shareef
author_role author
author2 Sabeeh,Nawras Shareef
author2_role author
dc.contributor.author.fl_str_mv Mohammad,Abbas Khalaf
Sabeeh,Nawras Shareef
dc.subject.por.fl_str_mv Hydrogen
Methane
Adsorption
Equilibrium
Mixture
topic Hydrogen
Methane
Adsorption
Equilibrium
Mixture
description Abstract Equilibrium adsorption isotherms were obtained experimentally by a static method for a binary component hydrogen-methane mixture on activated carbon and 5A molecular sieve adsorbents. The temperature range 303-333 K and pressure range 0 - 4 MPa were examined. Methods for predicting gas-mixture equilibrium adsorption data from the pure-component isotherms were evaluated. Extended Langmuir model correlated the adsorption of binary mixtures fairly well. In all cases mutual interference was found, that is, the amount of a given gas adsorbed at a given partial pressure was always less in the mixture than it would have been if the other gaseous component had not been present. It was found that the amount adsorbed of gases per unit bulk volume for 5A molecular sieve was higher than for activated carbon. Furthermore, 5A molecular sieve showed better adsorption characteristics than activated carbon in mass transfer properties, affinity, selectivity and heat of adsorption.
publishDate 2018
dc.date.none.fl_str_mv 2018-06-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322018000200795
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322018000200795
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/0104-6632.20180352s20160469
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Brazilian Society of Chemical Engineering
publisher.none.fl_str_mv Brazilian Society of Chemical Engineering
dc.source.none.fl_str_mv Brazilian Journal of Chemical Engineering v.35 n.2 2018
reponame:Brazilian Journal of Chemical Engineering
instname:Associação Brasileira de Engenharia Química (ABEQ)
instacron:ABEQ
instname_str Associação Brasileira de Engenharia Química (ABEQ)
instacron_str ABEQ
institution ABEQ
reponame_str Brazilian Journal of Chemical Engineering
collection Brazilian Journal of Chemical Engineering
repository.name.fl_str_mv Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)
repository.mail.fl_str_mv rgiudici@usp.br||rgiudici@usp.br
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