CHEMICAL REGENERATION OF BONE CHAR ASSOCIATED WITH A CONTINUOUS SYSTEM FOR DEFLUORIDATION OF WATER

Detalhes bibliográficos
Autor(a) principal: Nigri,Elbert M.
Data de Publicação: 2019
Outros Autores: Santos,André L. A., Bhatnagar,Amit, Rocha,Sônia D. F.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Brazilian Journal of Chemical Engineering
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322019000401631
Resumo: Abstract Sources of fluoride contaminated water are found around the world and their treatment is required before human consumption. This paper contributes to advances in the use of bone-char as an adsorbent for fluoride, associating steps of chemical regeneration and fluoride adsorption in continuous systems, thereby making feasible the multiple use of the adsorbent. Following the development of low cost treatment of water defluoridation in a fixed bed column, using bone-char, regeneration was carried out with NaOH (0.5 mol/L) solution in subsequent adsorption/desorption cycles. The continuous system was modeled applying Thomas, Yoon-Nelson, Adams-Bohart, Wolborska and Yan models, and the Yan model showed the best adjustment. The adsorption capacity of 6.28 mg/g was obtained from the breakthrough curve. Chemical regeneration of bone-char was feasible, and a reduction in adsorption capacity of 30% was observed only after five adsorption/desorption cycles.
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spelling CHEMICAL REGENERATION OF BONE CHAR ASSOCIATED WITH A CONTINUOUS SYSTEM FOR DEFLUORIDATION OF WATERBone-charChemical regenerationFluoride removalColumn modelingAdsorption/desorption’s cyclesAbstract Sources of fluoride contaminated water are found around the world and their treatment is required before human consumption. This paper contributes to advances in the use of bone-char as an adsorbent for fluoride, associating steps of chemical regeneration and fluoride adsorption in continuous systems, thereby making feasible the multiple use of the adsorbent. Following the development of low cost treatment of water defluoridation in a fixed bed column, using bone-char, regeneration was carried out with NaOH (0.5 mol/L) solution in subsequent adsorption/desorption cycles. The continuous system was modeled applying Thomas, Yoon-Nelson, Adams-Bohart, Wolborska and Yan models, and the Yan model showed the best adjustment. The adsorption capacity of 6.28 mg/g was obtained from the breakthrough curve. Chemical regeneration of bone-char was feasible, and a reduction in adsorption capacity of 30% was observed only after five adsorption/desorption cycles.Brazilian Society of Chemical Engineering2019-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322019000401631Brazilian Journal of Chemical Engineering v.36 n.4 2019reponame:Brazilian Journal of Chemical Engineeringinstname:Associação Brasileira de Engenharia Química (ABEQ)instacron:ABEQ10.1590/0104-6632.20190364s20180258info:eu-repo/semantics/openAccessNigri,Elbert M.Santos,André L. A.Bhatnagar,AmitRocha,Sônia D. F.eng2020-01-08T00:00:00Zoai:scielo:S0104-66322019000401631Revistahttps://www.scielo.br/j/bjce/https://old.scielo.br/oai/scielo-oai.phprgiudici@usp.br||rgiudici@usp.br1678-43830104-6632opendoar:2020-01-08T00:00Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)false
dc.title.none.fl_str_mv CHEMICAL REGENERATION OF BONE CHAR ASSOCIATED WITH A CONTINUOUS SYSTEM FOR DEFLUORIDATION OF WATER
title CHEMICAL REGENERATION OF BONE CHAR ASSOCIATED WITH A CONTINUOUS SYSTEM FOR DEFLUORIDATION OF WATER
spellingShingle CHEMICAL REGENERATION OF BONE CHAR ASSOCIATED WITH A CONTINUOUS SYSTEM FOR DEFLUORIDATION OF WATER
Nigri,Elbert M.
Bone-char
Chemical regeneration
Fluoride removal
Column modeling
Adsorption/desorption’s cycles
title_short CHEMICAL REGENERATION OF BONE CHAR ASSOCIATED WITH A CONTINUOUS SYSTEM FOR DEFLUORIDATION OF WATER
title_full CHEMICAL REGENERATION OF BONE CHAR ASSOCIATED WITH A CONTINUOUS SYSTEM FOR DEFLUORIDATION OF WATER
title_fullStr CHEMICAL REGENERATION OF BONE CHAR ASSOCIATED WITH A CONTINUOUS SYSTEM FOR DEFLUORIDATION OF WATER
title_full_unstemmed CHEMICAL REGENERATION OF BONE CHAR ASSOCIATED WITH A CONTINUOUS SYSTEM FOR DEFLUORIDATION OF WATER
title_sort CHEMICAL REGENERATION OF BONE CHAR ASSOCIATED WITH A CONTINUOUS SYSTEM FOR DEFLUORIDATION OF WATER
author Nigri,Elbert M.
author_facet Nigri,Elbert M.
Santos,André L. A.
Bhatnagar,Amit
Rocha,Sônia D. F.
author_role author
author2 Santos,André L. A.
Bhatnagar,Amit
Rocha,Sônia D. F.
author2_role author
author
author
dc.contributor.author.fl_str_mv Nigri,Elbert M.
Santos,André L. A.
Bhatnagar,Amit
Rocha,Sônia D. F.
dc.subject.por.fl_str_mv Bone-char
Chemical regeneration
Fluoride removal
Column modeling
Adsorption/desorption’s cycles
topic Bone-char
Chemical regeneration
Fluoride removal
Column modeling
Adsorption/desorption’s cycles
description Abstract Sources of fluoride contaminated water are found around the world and their treatment is required before human consumption. This paper contributes to advances in the use of bone-char as an adsorbent for fluoride, associating steps of chemical regeneration and fluoride adsorption in continuous systems, thereby making feasible the multiple use of the adsorbent. Following the development of low cost treatment of water defluoridation in a fixed bed column, using bone-char, regeneration was carried out with NaOH (0.5 mol/L) solution in subsequent adsorption/desorption cycles. The continuous system was modeled applying Thomas, Yoon-Nelson, Adams-Bohart, Wolborska and Yan models, and the Yan model showed the best adjustment. The adsorption capacity of 6.28 mg/g was obtained from the breakthrough curve. Chemical regeneration of bone-char was feasible, and a reduction in adsorption capacity of 30% was observed only after five adsorption/desorption cycles.
publishDate 2019
dc.date.none.fl_str_mv 2019-12-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322019000401631
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322019000401631
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/0104-6632.20190364s20180258
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Brazilian Society of Chemical Engineering
publisher.none.fl_str_mv Brazilian Society of Chemical Engineering
dc.source.none.fl_str_mv Brazilian Journal of Chemical Engineering v.36 n.4 2019
reponame:Brazilian Journal of Chemical Engineering
instname:Associação Brasileira de Engenharia Química (ABEQ)
instacron:ABEQ
instname_str Associação Brasileira de Engenharia Química (ABEQ)
instacron_str ABEQ
institution ABEQ
reponame_str Brazilian Journal of Chemical Engineering
collection Brazilian Journal of Chemical Engineering
repository.name.fl_str_mv Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)
repository.mail.fl_str_mv rgiudici@usp.br||rgiudici@usp.br
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