Chemical regeneration of bone char associated with a continuous system for defluoridation of water

Detalhes bibliográficos
Autor(a) principal: Elbert Müller Nigri
Data de Publicação: 2019
Outros Autores: André Luiz Alvarenga Santos, Amit Bhatnagar, Sônia Denise Ferreira Rocha
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFMG
Texto Completo: http://hdl.handle.net/1843/44396
Resumo: Sources of fluoride contaminated water are found around the world and their treatment is required before human consumption. This paper contributes to advances in the use of bone-char as an adsorbent for fluoride, associating steps of chemical regeneration and fluoride adsorption in continuous systems, thereby making feasible the multiple use of the adsorbent. Following the development of low cost treatment of water defluoridation in a fixed bed column, using bone-char, regeneration was carried out with NaOH (0.5 mol/L) solution in subsequent adsorption/desorption cycles. The continuous system was modeled applying Thomas, Yoon-Nelson, Adams-Bohart, Wolborska and Yan models, and the Yan model showed the best adjustment. The adsorption capacity of 6.28 mg/g was obtained from the breakthrough curve. Chemical regeneration of bone-char was feasible, and a reduction in adsorption capacity of 30% was observed only after five adsorption/desorption cycles.
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spelling 2022-08-19T17:20:00Z2022-08-19T17:20:00Z201936410.1590/0104-6632.20190364s2018025816784-383http://hdl.handle.net/1843/44396Sources of fluoride contaminated water are found around the world and their treatment is required before human consumption. This paper contributes to advances in the use of bone-char as an adsorbent for fluoride, associating steps of chemical regeneration and fluoride adsorption in continuous systems, thereby making feasible the multiple use of the adsorbent. Following the development of low cost treatment of water defluoridation in a fixed bed column, using bone-char, regeneration was carried out with NaOH (0.5 mol/L) solution in subsequent adsorption/desorption cycles. The continuous system was modeled applying Thomas, Yoon-Nelson, Adams-Bohart, Wolborska and Yan models, and the Yan model showed the best adjustment. The adsorption capacity of 6.28 mg/g was obtained from the breakthrough curve. Chemical regeneration of bone-char was feasible, and a reduction in adsorption capacity of 30% was observed only after five adsorption/desorption cycles.Fontes de água contaminada com flúor são encontradas em todo o mundo e seu tratamento é necessário antes do consumo humano. Este artigo contribui para avanços no uso do carvão de osso como adsorvente para flúor, associando etapas de regeneração química e adsorção de flúor em sistemas contínuos, viabilizando o uso múltiplo do adsorvente. Seguindo o desenvolvimento do tratamento de água de baixo custo defluoretação em coluna de leito fixo, utilizando-se osso-char, a regeneração foi realizada com NaOH (0,5 mol/L) solução em ciclos de adsorção/dessorção subsequentes. O sistema contínuo foi modelado aplicando Thomas, Os modelos Yoon-Nelson, Adams-Bohart, Wolborska e Yan, e o modelo Yan apresentaram o melhor ajuste. o a capacidade de adsorção de 6,28 mg/g foi obtida a partir da curva de ruptura. Regeneração química de osso-char foi viável, e uma redução na capacidade de adsorção de 30% foi observada somente após cinco ciclos.engUniversidade Federal de Minas GeraisUFMGBrasilENG - DEPARTAMENTO DE ENGENHARIA MINASBrazilian journal of chemical engineeringCarvão de OssoRegeneração QuímicaRemoção de FlúorModelagem de ColunasChemical regeneration of bone char associated with a continuous system for defluoridation of waterRegeneração química de carbonização óssea associada a um sistema contínuo de desfluoretação de águainfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://www.scielo.br/j/bjce/a/zzRTQ7qy7MTQJDNgxRZ6hxS/?format=pdf&lang=enElbert Müller NigriAndré Luiz Alvarenga SantosAmit BhatnagarSônia Denise Ferreira Rochaapplication/pdfinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGLICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/44396/1/License.txtfa505098d172de0bc8864fc1287ffe22MD51ORIGINAL2019_Chemical regeneration of bone char associated with a continuous system for defluoridation of water.pdf2019_Chemical regeneration of bone char associated with a continuous system for defluoridation of water.pdfapplication/pdf1551005https://repositorio.ufmg.br/bitstream/1843/44396/2/2019_Chemical%20regeneration%20of%20bone%20char%20associated%20with%20a%20continuous%20system%20for%20defluoridation%20of%20water.pdfecdfa38bf73170b243332a1321c2f0b4MD521843/443962022-08-19 14:20:00.245oai:repositorio.ufmg.br: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Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2022-08-19T17:20Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false
dc.title.pt_BR.fl_str_mv Chemical regeneration of bone char associated with a continuous system for defluoridation of water
dc.title.alternative.pt_BR.fl_str_mv Regeneração química de carbonização óssea associada a um sistema contínuo de desfluoretação de água
title Chemical regeneration of bone char associated with a continuous system for defluoridation of water
spellingShingle Chemical regeneration of bone char associated with a continuous system for defluoridation of water
Elbert Müller Nigri
Carvão de Osso
Regeneração Química
Remoção de Flúor
Modelagem de Colunas
title_short Chemical regeneration of bone char associated with a continuous system for defluoridation of water
title_full Chemical regeneration of bone char associated with a continuous system for defluoridation of water
title_fullStr Chemical regeneration of bone char associated with a continuous system for defluoridation of water
title_full_unstemmed Chemical regeneration of bone char associated with a continuous system for defluoridation of water
title_sort Chemical regeneration of bone char associated with a continuous system for defluoridation of water
author Elbert Müller Nigri
author_facet Elbert Müller Nigri
André Luiz Alvarenga Santos
Amit Bhatnagar
Sônia Denise Ferreira Rocha
author_role author
author2 André Luiz Alvarenga Santos
Amit Bhatnagar
Sônia Denise Ferreira Rocha
author2_role author
author
author
dc.contributor.author.fl_str_mv Elbert Müller Nigri
André Luiz Alvarenga Santos
Amit Bhatnagar
Sônia Denise Ferreira Rocha
dc.subject.other.pt_BR.fl_str_mv Carvão de Osso
Regeneração Química
Remoção de Flúor
Modelagem de Colunas
topic Carvão de Osso
Regeneração Química
Remoção de Flúor
Modelagem de Colunas
description Sources of fluoride contaminated water are found around the world and their treatment is required before human consumption. This paper contributes to advances in the use of bone-char as an adsorbent for fluoride, associating steps of chemical regeneration and fluoride adsorption in continuous systems, thereby making feasible the multiple use of the adsorbent. Following the development of low cost treatment of water defluoridation in a fixed bed column, using bone-char, regeneration was carried out with NaOH (0.5 mol/L) solution in subsequent adsorption/desorption cycles. The continuous system was modeled applying Thomas, Yoon-Nelson, Adams-Bohart, Wolborska and Yan models, and the Yan model showed the best adjustment. The adsorption capacity of 6.28 mg/g was obtained from the breakthrough curve. Chemical regeneration of bone-char was feasible, and a reduction in adsorption capacity of 30% was observed only after five adsorption/desorption cycles.
publishDate 2019
dc.date.issued.fl_str_mv 2019
dc.date.accessioned.fl_str_mv 2022-08-19T17:20:00Z
dc.date.available.fl_str_mv 2022-08-19T17:20:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
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dc.identifier.uri.fl_str_mv http://hdl.handle.net/1843/44396
dc.identifier.doi.pt_BR.fl_str_mv 10.1590/0104-6632.20190364s20180258
dc.identifier.issn.pt_BR.fl_str_mv 16784-383
identifier_str_mv 10.1590/0104-6632.20190364s20180258
16784-383
url http://hdl.handle.net/1843/44396
dc.language.iso.fl_str_mv eng
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dc.relation.ispartof.pt_BR.fl_str_mv Brazilian journal of chemical engineering
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dc.publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.publisher.initials.fl_str_mv UFMG
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv ENG - DEPARTAMENTO DE ENGENHARIA MINAS
publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFMG
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