Measurement and correlation of isobaric vapor-liquid equilibrium for the binary system of cyclopentane and tetrahydrofuran

Detalhes bibliográficos
Autor(a) principal: Li,Yumei
Data de Publicação: 2014
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Brazilian Journal of Chemical Engineering
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322014000300022
Resumo: Isobaric vapor-liquid equilibrium (VLE) data for the cyclopentane and tetrahydrofuran (THF) system were measured at 101.3 kPa by using an equilibrium still. Thermodynamic consistency of the experimental data was confirmed by means of the Herington method. The experimental data were correlated and calculated by the Margules, Van Laar and Wilson activity-coefficient models, respectively. The Wilson and Van Laar activity-coefficient models are better than the Margules activity-coefficient model based on the average absolute deviations of temperature and the vapor-phase composition. For the Wilson and Van Laar activity-coefficient models the average absolute deviations between the experimental and the calculated values were 0.24 K and 0.23 K for the boiling point, and 0.0040 for vapor-phase composition, respectively. These agree well with the experimental data. Therefore, it was shown that the Wilson and Van Laar activity-coefficient models satisfactorily correlate the experimental results of the cyclopentane and tetrahydrofuran system.
id ABEQ-1_db2e7416821009b8690fa20bad63ceac
oai_identifier_str oai:scielo:S0104-66322014000300022
network_acronym_str ABEQ-1
network_name_str Brazilian Journal of Chemical Engineering
repository_id_str
spelling Measurement and correlation of isobaric vapor-liquid equilibrium for the binary system of cyclopentane and tetrahydrofuranCyclopentaneTetrahydrofuranVapor-liquid equilibriumIsobaric vapor-liquid equilibrium (VLE) data for the cyclopentane and tetrahydrofuran (THF) system were measured at 101.3 kPa by using an equilibrium still. Thermodynamic consistency of the experimental data was confirmed by means of the Herington method. The experimental data were correlated and calculated by the Margules, Van Laar and Wilson activity-coefficient models, respectively. The Wilson and Van Laar activity-coefficient models are better than the Margules activity-coefficient model based on the average absolute deviations of temperature and the vapor-phase composition. For the Wilson and Van Laar activity-coefficient models the average absolute deviations between the experimental and the calculated values were 0.24 K and 0.23 K for the boiling point, and 0.0040 for vapor-phase composition, respectively. These agree well with the experimental data. Therefore, it was shown that the Wilson and Van Laar activity-coefficient models satisfactorily correlate the experimental results of the cyclopentane and tetrahydrofuran system.Brazilian Society of Chemical Engineering2014-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322014000300022Brazilian Journal of Chemical Engineering v.31 n.3 2014reponame:Brazilian Journal of Chemical Engineeringinstname:Associação Brasileira de Engenharia Química (ABEQ)instacron:ABEQ10.1590/0104-6632.20140313s00002623info:eu-repo/semantics/openAccessLi,Yumeieng2014-09-17T00:00:00Zoai:scielo:S0104-66322014000300022Revistahttps://www.scielo.br/j/bjce/https://old.scielo.br/oai/scielo-oai.phprgiudici@usp.br||rgiudici@usp.br1678-43830104-6632opendoar:2014-09-17T00:00Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)false
dc.title.none.fl_str_mv Measurement and correlation of isobaric vapor-liquid equilibrium for the binary system of cyclopentane and tetrahydrofuran
title Measurement and correlation of isobaric vapor-liquid equilibrium for the binary system of cyclopentane and tetrahydrofuran
spellingShingle Measurement and correlation of isobaric vapor-liquid equilibrium for the binary system of cyclopentane and tetrahydrofuran
Li,Yumei
Cyclopentane
Tetrahydrofuran
Vapor-liquid equilibrium
title_short Measurement and correlation of isobaric vapor-liquid equilibrium for the binary system of cyclopentane and tetrahydrofuran
title_full Measurement and correlation of isobaric vapor-liquid equilibrium for the binary system of cyclopentane and tetrahydrofuran
title_fullStr Measurement and correlation of isobaric vapor-liquid equilibrium for the binary system of cyclopentane and tetrahydrofuran
title_full_unstemmed Measurement and correlation of isobaric vapor-liquid equilibrium for the binary system of cyclopentane and tetrahydrofuran
title_sort Measurement and correlation of isobaric vapor-liquid equilibrium for the binary system of cyclopentane and tetrahydrofuran
author Li,Yumei
author_facet Li,Yumei
author_role author
dc.contributor.author.fl_str_mv Li,Yumei
dc.subject.por.fl_str_mv Cyclopentane
Tetrahydrofuran
Vapor-liquid equilibrium
topic Cyclopentane
Tetrahydrofuran
Vapor-liquid equilibrium
description Isobaric vapor-liquid equilibrium (VLE) data for the cyclopentane and tetrahydrofuran (THF) system were measured at 101.3 kPa by using an equilibrium still. Thermodynamic consistency of the experimental data was confirmed by means of the Herington method. The experimental data were correlated and calculated by the Margules, Van Laar and Wilson activity-coefficient models, respectively. The Wilson and Van Laar activity-coefficient models are better than the Margules activity-coefficient model based on the average absolute deviations of temperature and the vapor-phase composition. For the Wilson and Van Laar activity-coefficient models the average absolute deviations between the experimental and the calculated values were 0.24 K and 0.23 K for the boiling point, and 0.0040 for vapor-phase composition, respectively. These agree well with the experimental data. Therefore, it was shown that the Wilson and Van Laar activity-coefficient models satisfactorily correlate the experimental results of the cyclopentane and tetrahydrofuran system.
publishDate 2014
dc.date.none.fl_str_mv 2014-09-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322014000300022
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322014000300022
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/0104-6632.20140313s00002623
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Brazilian Society of Chemical Engineering
publisher.none.fl_str_mv Brazilian Society of Chemical Engineering
dc.source.none.fl_str_mv Brazilian Journal of Chemical Engineering v.31 n.3 2014
reponame:Brazilian Journal of Chemical Engineering
instname:Associação Brasileira de Engenharia Química (ABEQ)
instacron:ABEQ
instname_str Associação Brasileira de Engenharia Química (ABEQ)
instacron_str ABEQ
institution ABEQ
reponame_str Brazilian Journal of Chemical Engineering
collection Brazilian Journal of Chemical Engineering
repository.name.fl_str_mv Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)
repository.mail.fl_str_mv rgiudici@usp.br||rgiudici@usp.br
_version_ 1754213174600531968

Registros relacionados