Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion

Detalhes bibliográficos
Autor(a) principal: Martín-Ramos,Pablo
Data de Publicação: 2016
Outros Autores: Costa,Ana L., Silva,Manuela Ramos, Pereira,Laura C. J., Silva,Pedro S. Pereira da, Melo,J. Sergio Seixas de, Martín-Gil,Jesús
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Materials research (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392016000200328
Resumo: An uranyl complex [UO2(TFA)2(DMSO)3] (TFA=deprotonated trifluoroacetic acid; DMSO=dimethyl sulfoxide) has been successfully synthesized by reacting UO2(CH3COO)2·H2O with one equivalent of (CF3CO)2O and DMSO. The complex has been characterized by single-crystal X-ray diffraction, X-ray powder diffraction, elemental analysis, FT-IR spectroscopy, thermal analysis and absorption and emission spectroscopies. The spectroscopic properties of the material make it suitable for its application in the sensing and monitoring of uranyl in the PUREX process.
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spelling Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl IonDMSOsensingtrifluoroacetatePUREXuranylAn uranyl complex [UO2(TFA)2(DMSO)3] (TFA=deprotonated trifluoroacetic acid; DMSO=dimethyl sulfoxide) has been successfully synthesized by reacting UO2(CH3COO)2·H2O with one equivalent of (CF3CO)2O and DMSO. The complex has been characterized by single-crystal X-ray diffraction, X-ray powder diffraction, elemental analysis, FT-IR spectroscopy, thermal analysis and absorption and emission spectroscopies. The spectroscopic properties of the material make it suitable for its application in the sensing and monitoring of uranyl in the PUREX process.ABM, ABC, ABPol2016-04-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392016000200328Materials Research v.19 n.2 2016reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-MR-2015-0448info:eu-repo/semantics/openAccessMartín-Ramos,PabloCosta,Ana L.Silva,Manuela RamosPereira,Laura C. J.Silva,Pedro S. Pereira daMelo,J. Sergio Seixas deMartín-Gil,Jesúseng2016-04-01T00:00:00Zoai:scielo:S1516-14392016000200328Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2016-04-01T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false
dc.title.none.fl_str_mv Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
title Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
spellingShingle Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
Martín-Ramos,Pablo
DMSO
sensing
trifluoroacetate
PUREX
uranyl
title_short Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
title_full Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
title_fullStr Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
title_full_unstemmed Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
title_sort Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
author Martín-Ramos,Pablo
author_facet Martín-Ramos,Pablo
Costa,Ana L.
Silva,Manuela Ramos
Pereira,Laura C. J.
Silva,Pedro S. Pereira da
Melo,J. Sergio Seixas de
Martín-Gil,Jesús
author_role author
author2 Costa,Ana L.
Silva,Manuela Ramos
Pereira,Laura C. J.
Silva,Pedro S. Pereira da
Melo,J. Sergio Seixas de
Martín-Gil,Jesús
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Martín-Ramos,Pablo
Costa,Ana L.
Silva,Manuela Ramos
Pereira,Laura C. J.
Silva,Pedro S. Pereira da
Melo,J. Sergio Seixas de
Martín-Gil,Jesús
dc.subject.por.fl_str_mv DMSO
sensing
trifluoroacetate
PUREX
uranyl
topic DMSO
sensing
trifluoroacetate
PUREX
uranyl
description An uranyl complex [UO2(TFA)2(DMSO)3] (TFA=deprotonated trifluoroacetic acid; DMSO=dimethyl sulfoxide) has been successfully synthesized by reacting UO2(CH3COO)2·H2O with one equivalent of (CF3CO)2O and DMSO. The complex has been characterized by single-crystal X-ray diffraction, X-ray powder diffraction, elemental analysis, FT-IR spectroscopy, thermal analysis and absorption and emission spectroscopies. The spectroscopic properties of the material make it suitable for its application in the sensing and monitoring of uranyl in the PUREX process.
publishDate 2016
dc.date.none.fl_str_mv 2016-04-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392016000200328
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392016000200328
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/1980-5373-MR-2015-0448
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv ABM, ABC, ABPol
publisher.none.fl_str_mv ABM, ABC, ABPol
dc.source.none.fl_str_mv Materials Research v.19 n.2 2016
reponame:Materials research (São Carlos. Online)
instname:Universidade Federal de São Carlos (UFSCAR)
instacron:ABM ABC ABPOL
instname_str Universidade Federal de São Carlos (UFSCAR)
instacron_str ABM ABC ABPOL
institution ABM ABC ABPOL
reponame_str Materials research (São Carlos. Online)
collection Materials research (São Carlos. Online)
repository.name.fl_str_mv Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)
repository.mail.fl_str_mv dedz@power.ufscar.br
_version_ 1754212668007251968

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