Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion

Detalhes bibliográficos
Autor(a) principal: Martín-Ramos, Pablo
Data de Publicação: 2016
Outros Autores: Costa, Ana L., Silva, Manuela Ramos, Pereira, Laura C. J., Silva, Pedro S. Pereira da, Melo, J. Sérgio Seixas de, Martín-Gil, Jesús
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10316/108702
https://doi.org/10.1590/1980-5373-MR-2015-0448
Resumo: An uranyl complex [UO2(TFA)2(DMSO)3] (TFA=deprotonated trifluoroacetic acid; DMSO=dimethyl sulfoxide) has been successfully synthesized by reacting UO2(CH3COO)2·H2O with one equivalent of (CF3CO)2O and DMSO. The complex has been characterized by single-crystal X-ray diffraction, X-ray powder diffraction, elemental analysis, FT-IR spectroscopy, thermal analysis and absorption and emission spectroscopies. The spectroscopic properties of the material make it suitable for its application in the sensing and monitoring of uranyl in the PUREX process.
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spelling Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl IonDMSOsensingtrifluoroacetatePUREXuranylAn uranyl complex [UO2(TFA)2(DMSO)3] (TFA=deprotonated trifluoroacetic acid; DMSO=dimethyl sulfoxide) has been successfully synthesized by reacting UO2(CH3COO)2·H2O with one equivalent of (CF3CO)2O and DMSO. The complex has been characterized by single-crystal X-ray diffraction, X-ray powder diffraction, elemental analysis, FT-IR spectroscopy, thermal analysis and absorption and emission spectroscopies. The spectroscopic properties of the material make it suitable for its application in the sensing and monitoring of uranyl in the PUREX process.Universidade Federal de Sao Carlos2016info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/10316/108702http://hdl.handle.net/10316/108702https://doi.org/10.1590/1980-5373-MR-2015-0448eng1980-53731516-1439Martín-Ramos, PabloCosta, Ana L.Silva, Manuela RamosPereira, Laura C. J.Silva, Pedro S. Pereira daMelo, J. Sérgio Seixas deMartín-Gil, Jesúsinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-09-08T10:23:21Zoai:estudogeral.uc.pt:10316/108702Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T21:24:58.540911Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
title Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
spellingShingle Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
Martín-Ramos, Pablo
DMSO
sensing
trifluoroacetate
PUREX
uranyl
title_short Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
title_full Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
title_fullStr Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
title_full_unstemmed Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
title_sort Luminescent Properties of [UO2(TFA)2(DMSO)3], a Promising Material for Sensing and Monitoring the Uranyl Ion
author Martín-Ramos, Pablo
author_facet Martín-Ramos, Pablo
Costa, Ana L.
Silva, Manuela Ramos
Pereira, Laura C. J.
Silva, Pedro S. Pereira da
Melo, J. Sérgio Seixas de
Martín-Gil, Jesús
author_role author
author2 Costa, Ana L.
Silva, Manuela Ramos
Pereira, Laura C. J.
Silva, Pedro S. Pereira da
Melo, J. Sérgio Seixas de
Martín-Gil, Jesús
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Martín-Ramos, Pablo
Costa, Ana L.
Silva, Manuela Ramos
Pereira, Laura C. J.
Silva, Pedro S. Pereira da
Melo, J. Sérgio Seixas de
Martín-Gil, Jesús
dc.subject.por.fl_str_mv DMSO
sensing
trifluoroacetate
PUREX
uranyl
topic DMSO
sensing
trifluoroacetate
PUREX
uranyl
description An uranyl complex [UO2(TFA)2(DMSO)3] (TFA=deprotonated trifluoroacetic acid; DMSO=dimethyl sulfoxide) has been successfully synthesized by reacting UO2(CH3COO)2·H2O with one equivalent of (CF3CO)2O and DMSO. The complex has been characterized by single-crystal X-ray diffraction, X-ray powder diffraction, elemental analysis, FT-IR spectroscopy, thermal analysis and absorption and emission spectroscopies. The spectroscopic properties of the material make it suitable for its application in the sensing and monitoring of uranyl in the PUREX process.
publishDate 2016
dc.date.none.fl_str_mv 2016
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10316/108702
http://hdl.handle.net/10316/108702
https://doi.org/10.1590/1980-5373-MR-2015-0448
url http://hdl.handle.net/10316/108702
https://doi.org/10.1590/1980-5373-MR-2015-0448
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1980-5373
1516-1439
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Universidade Federal de Sao Carlos
publisher.none.fl_str_mv Universidade Federal de Sao Carlos
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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