Thermal behaviour of titanium in host matrix clay

Detalhes bibliográficos
Autor(a) principal: Volzone,Cristina
Data de Publicação: 2009
Outros Autores: Cesio,Ana María
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Materials research (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392009000200013
Resumo: Titanium in hosted by a clay matrix has important applications in a variety of catalysts. However, there is insufficient information about of textural and structural characteristics of the titanium in matrix clay at room temperature and after thermal treatment. In this study, titanium in host matrix clay was obtained by treating montmorillonite clay minerals with different OH-Ti solutions. The titanium-solutions containing partially hydrolyzed titanium were obtained using a TiCl4 solution with and without the addition of glycerol. The amount of Ti added to the solid was 20 mmol Ti per gram of clay. Thermal treatments were carried out at 500 and 1,000 °C in an air atmosphere. The solids were characterized by X ray diffraction, thermal analyses, infrared spectroscopy, N2 adsorption-desorption isotherms. The products presented different structural and textural characteristics and, after calcination at 1,000 °C, anatase and rutile in different proportions were present in the samples.
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spelling Thermal behaviour of titanium in host matrix claytitaniumclaythermal treatmentmontmorilloniteTitanium in hosted by a clay matrix has important applications in a variety of catalysts. However, there is insufficient information about of textural and structural characteristics of the titanium in matrix clay at room temperature and after thermal treatment. In this study, titanium in host matrix clay was obtained by treating montmorillonite clay minerals with different OH-Ti solutions. The titanium-solutions containing partially hydrolyzed titanium were obtained using a TiCl4 solution with and without the addition of glycerol. The amount of Ti added to the solid was 20 mmol Ti per gram of clay. Thermal treatments were carried out at 500 and 1,000 °C in an air atmosphere. The solids were characterized by X ray diffraction, thermal analyses, infrared spectroscopy, N2 adsorption-desorption isotherms. The products presented different structural and textural characteristics and, after calcination at 1,000 °C, anatase and rutile in different proportions were present in the samples.ABM, ABC, ABPol2009-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392009000200013Materials Research v.12 n.2 2009reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/S1516-14392009000200013info:eu-repo/semantics/openAccessVolzone,CristinaCesio,Ana Maríaeng2009-07-24T00:00:00Zoai:scielo:S1516-14392009000200013Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2009-07-24T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false
dc.title.none.fl_str_mv Thermal behaviour of titanium in host matrix clay
title Thermal behaviour of titanium in host matrix clay
spellingShingle Thermal behaviour of titanium in host matrix clay
Volzone,Cristina
titanium
clay
thermal treatment
montmorillonite
title_short Thermal behaviour of titanium in host matrix clay
title_full Thermal behaviour of titanium in host matrix clay
title_fullStr Thermal behaviour of titanium in host matrix clay
title_full_unstemmed Thermal behaviour of titanium in host matrix clay
title_sort Thermal behaviour of titanium in host matrix clay
author Volzone,Cristina
author_facet Volzone,Cristina
Cesio,Ana María
author_role author
author2 Cesio,Ana María
author2_role author
dc.contributor.author.fl_str_mv Volzone,Cristina
Cesio,Ana María
dc.subject.por.fl_str_mv titanium
clay
thermal treatment
montmorillonite
topic titanium
clay
thermal treatment
montmorillonite
description Titanium in hosted by a clay matrix has important applications in a variety of catalysts. However, there is insufficient information about of textural and structural characteristics of the titanium in matrix clay at room temperature and after thermal treatment. In this study, titanium in host matrix clay was obtained by treating montmorillonite clay minerals with different OH-Ti solutions. The titanium-solutions containing partially hydrolyzed titanium were obtained using a TiCl4 solution with and without the addition of glycerol. The amount of Ti added to the solid was 20 mmol Ti per gram of clay. Thermal treatments were carried out at 500 and 1,000 °C in an air atmosphere. The solids were characterized by X ray diffraction, thermal analyses, infrared spectroscopy, N2 adsorption-desorption isotherms. The products presented different structural and textural characteristics and, after calcination at 1,000 °C, anatase and rutile in different proportions were present in the samples.
publishDate 2009
dc.date.none.fl_str_mv 2009-06-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392009000200013
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392009000200013
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S1516-14392009000200013
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv ABM, ABC, ABPol
publisher.none.fl_str_mv ABM, ABC, ABPol
dc.source.none.fl_str_mv Materials Research v.12 n.2 2009
reponame:Materials research (São Carlos. Online)
instname:Universidade Federal de São Carlos (UFSCAR)
instacron:ABM ABC ABPOL
instname_str Universidade Federal de São Carlos (UFSCAR)
instacron_str ABM ABC ABPOL
institution ABM ABC ABPOL
reponame_str Materials research (São Carlos. Online)
collection Materials research (São Carlos. Online)
repository.name.fl_str_mv Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)
repository.mail.fl_str_mv dedz@power.ufscar.br
_version_ 1754212659271565312

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