Effects of Aging on Chlorinated Plasma Polymers

Detalhes bibliográficos
Autor(a) principal: Turri,Rafael Gustavo
Data de Publicação: 2017
Outros Autores: Amorim,Milena Kowalczuk Manosso, Hadich,Tayan Vieira, Fernandes,Isabela Cristina, Fernandes,Gabriel Ferreira, Rossi,Diego, Rangel,Elidiane Cipriano, Durrant,Steven Frederick
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Materials research (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000400862
Resumo: Thin films deposited from propanol-chloroform-argon mixtures by plasma enhanced chemical vapor deposition at different partial pressures of chloroform in the feed, CCl, were characterized after two years of aging and their characteristics compared with their as-deposited properties. Film thickness decreased and surface roughness increased with aging. Surface contact angles also increased with aging for the chlorinated films. For the film deposited with 40% chloroform in the feed the contact angle increased about 14°. Transmission infrared and Energy dispersive X-ray spectroscopy revealed that the films gain carbonyl and hydroxyl groups and lose chlorine and hydrogen on aging. Chlorination appears to make the films more durable. Delamination was observed for the unchlorinated films.
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spelling Effects of Aging on Chlorinated Plasma Polymersthin filmsa-C:H:O:ClIRSstabilitycontact angleThin films deposited from propanol-chloroform-argon mixtures by plasma enhanced chemical vapor deposition at different partial pressures of chloroform in the feed, CCl, were characterized after two years of aging and their characteristics compared with their as-deposited properties. Film thickness decreased and surface roughness increased with aging. Surface contact angles also increased with aging for the chlorinated films. For the film deposited with 40% chloroform in the feed the contact angle increased about 14°. Transmission infrared and Energy dispersive X-ray spectroscopy revealed that the films gain carbonyl and hydroxyl groups and lose chlorine and hydrogen on aging. Chlorination appears to make the films more durable. Delamination was observed for the unchlorinated films.ABM, ABC, ABPol2017-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000400862Materials Research v.20 n.4 2017reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2016-0667info:eu-repo/semantics/openAccessTurri,Rafael GustavoAmorim,Milena Kowalczuk ManossoHadich,Tayan VieiraFernandes,Isabela CristinaFernandes,Gabriel FerreiraRossi,DiegoRangel,Elidiane CiprianoDurrant,Steven Frederickeng2017-09-05T00:00:00Zoai:scielo:S1516-14392017000400862Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2017-09-05T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false
dc.title.none.fl_str_mv Effects of Aging on Chlorinated Plasma Polymers
title Effects of Aging on Chlorinated Plasma Polymers
spellingShingle Effects of Aging on Chlorinated Plasma Polymers
Turri,Rafael Gustavo
thin films
a-C:H:O:Cl
IRS
stability
contact angle
title_short Effects of Aging on Chlorinated Plasma Polymers
title_full Effects of Aging on Chlorinated Plasma Polymers
title_fullStr Effects of Aging on Chlorinated Plasma Polymers
title_full_unstemmed Effects of Aging on Chlorinated Plasma Polymers
title_sort Effects of Aging on Chlorinated Plasma Polymers
author Turri,Rafael Gustavo
author_facet Turri,Rafael Gustavo
Amorim,Milena Kowalczuk Manosso
Hadich,Tayan Vieira
Fernandes,Isabela Cristina
Fernandes,Gabriel Ferreira
Rossi,Diego
Rangel,Elidiane Cipriano
Durrant,Steven Frederick
author_role author
author2 Amorim,Milena Kowalczuk Manosso
Hadich,Tayan Vieira
Fernandes,Isabela Cristina
Fernandes,Gabriel Ferreira
Rossi,Diego
Rangel,Elidiane Cipriano
Durrant,Steven Frederick
author2_role author
author
author
author
author
author
author
dc.contributor.author.fl_str_mv Turri,Rafael Gustavo
Amorim,Milena Kowalczuk Manosso
Hadich,Tayan Vieira
Fernandes,Isabela Cristina
Fernandes,Gabriel Ferreira
Rossi,Diego
Rangel,Elidiane Cipriano
Durrant,Steven Frederick
dc.subject.por.fl_str_mv thin films
a-C:H:O:Cl
IRS
stability
contact angle
topic thin films
a-C:H:O:Cl
IRS
stability
contact angle
description Thin films deposited from propanol-chloroform-argon mixtures by plasma enhanced chemical vapor deposition at different partial pressures of chloroform in the feed, CCl, were characterized after two years of aging and their characteristics compared with their as-deposited properties. Film thickness decreased and surface roughness increased with aging. Surface contact angles also increased with aging for the chlorinated films. For the film deposited with 40% chloroform in the feed the contact angle increased about 14°. Transmission infrared and Energy dispersive X-ray spectroscopy revealed that the films gain carbonyl and hydroxyl groups and lose chlorine and hydrogen on aging. Chlorination appears to make the films more durable. Delamination was observed for the unchlorinated films.
publishDate 2017
dc.date.none.fl_str_mv 2017-08-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000400862
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000400862
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/1980-5373-mr-2016-0667
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv ABM, ABC, ABPol
publisher.none.fl_str_mv ABM, ABC, ABPol
dc.source.none.fl_str_mv Materials Research v.20 n.4 2017
reponame:Materials research (São Carlos. Online)
instname:Universidade Federal de São Carlos (UFSCAR)
instacron:ABM ABC ABPOL
instname_str Universidade Federal de São Carlos (UFSCAR)
instacron_str ABM ABC ABPOL
institution ABM ABC ABPOL
reponame_str Materials research (São Carlos. Online)
collection Materials research (São Carlos. Online)
repository.name.fl_str_mv Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)
repository.mail.fl_str_mv dedz@power.ufscar.br
_version_ 1754212670699995136

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