A study on the microstructural parameters of Zn (1-x)LaxZrxO nanopowders by X-ray line broadening analysis
Autor(a) principal: | |
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Data de Publicação: | 2016 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392016000300548 |
Resumo: | In the present study, the pure and La-Zr co-doped ZnO nanoparticles were prepared by sol–gel technique using zinc acetate dehydrate (Zn(Ac)2·2H2O), lanthanum nitrate hexahydrate (La(NO3)3 ·6H2O) and zirconium chloride (ZrCl4) as precursor. The structure and morphology of the prepared nanoparticle samples were studied using X-ray diffraction and transmission electron microscopy measurements. X-ray diffraction results indicated that all the samples have crystalline wurtzite phase. TEM showed that powder was polycrystalline in nature with random distribution of the pure and La-Zr doped ZnO nanoparticles. We demonstrate strain-size evaluations for pure and doped ZnO nanoparticles from the x-ray line profile analysis. The microstructural effects of crystalline materials in terms of crystallite sizes and lattice strain on the peak broadening were investigated using Williamson-Hall (W-H) analysis and size- strain plot (SSP) method. The average crystallite size of Zn (1-x)LaxZrxO nanoparticles estimated from the W–H analysis and SSP method varied as the doping concentration increased. The incorporation of Zr4+ ion in the place of Zn2+ caused an increase in the size of nanocrystals as compared to undoped ZnO. The average particle sizes of co-doped ZnO nanoparticles estimated from the USDM model is in good agreement with the TEM results. |
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A study on the microstructural parameters of Zn (1-x)LaxZrxO nanopowders by X-ray line broadening analysisZnOX-ray diffractionTEMWilliamson-Hall analysisSSP modelIn the present study, the pure and La-Zr co-doped ZnO nanoparticles were prepared by sol–gel technique using zinc acetate dehydrate (Zn(Ac)2·2H2O), lanthanum nitrate hexahydrate (La(NO3)3 ·6H2O) and zirconium chloride (ZrCl4) as precursor. The structure and morphology of the prepared nanoparticle samples were studied using X-ray diffraction and transmission electron microscopy measurements. X-ray diffraction results indicated that all the samples have crystalline wurtzite phase. TEM showed that powder was polycrystalline in nature with random distribution of the pure and La-Zr doped ZnO nanoparticles. We demonstrate strain-size evaluations for pure and doped ZnO nanoparticles from the x-ray line profile analysis. The microstructural effects of crystalline materials in terms of crystallite sizes and lattice strain on the peak broadening were investigated using Williamson-Hall (W-H) analysis and size- strain plot (SSP) method. The average crystallite size of Zn (1-x)LaxZrxO nanoparticles estimated from the W–H analysis and SSP method varied as the doping concentration increased. The incorporation of Zr4+ ion in the place of Zn2+ caused an increase in the size of nanocrystals as compared to undoped ZnO. The average particle sizes of co-doped ZnO nanoparticles estimated from the USDM model is in good agreement with the TEM results.ABM, ABC, ABPol2016-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392016000300548Materials Research v.19 n.3 2016reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-MR-2016-0017info:eu-repo/semantics/openAccessChenari,Hossein MahmoudiMoafi,Hadi FallahRezaee,Omideng2016-05-19T00:00:00Zoai:scielo:S1516-14392016000300548Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2016-05-19T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
A study on the microstructural parameters of Zn (1-x)LaxZrxO nanopowders by X-ray line broadening analysis |
title |
A study on the microstructural parameters of Zn (1-x)LaxZrxO nanopowders by X-ray line broadening analysis |
spellingShingle |
A study on the microstructural parameters of Zn (1-x)LaxZrxO nanopowders by X-ray line broadening analysis Chenari,Hossein Mahmoudi ZnO X-ray diffraction TEM Williamson-Hall analysis SSP model |
title_short |
A study on the microstructural parameters of Zn (1-x)LaxZrxO nanopowders by X-ray line broadening analysis |
title_full |
A study on the microstructural parameters of Zn (1-x)LaxZrxO nanopowders by X-ray line broadening analysis |
title_fullStr |
A study on the microstructural parameters of Zn (1-x)LaxZrxO nanopowders by X-ray line broadening analysis |
title_full_unstemmed |
A study on the microstructural parameters of Zn (1-x)LaxZrxO nanopowders by X-ray line broadening analysis |
title_sort |
A study on the microstructural parameters of Zn (1-x)LaxZrxO nanopowders by X-ray line broadening analysis |
author |
Chenari,Hossein Mahmoudi |
author_facet |
Chenari,Hossein Mahmoudi Moafi,Hadi Fallah Rezaee,Omid |
author_role |
author |
author2 |
Moafi,Hadi Fallah Rezaee,Omid |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Chenari,Hossein Mahmoudi Moafi,Hadi Fallah Rezaee,Omid |
dc.subject.por.fl_str_mv |
ZnO X-ray diffraction TEM Williamson-Hall analysis SSP model |
topic |
ZnO X-ray diffraction TEM Williamson-Hall analysis SSP model |
description |
In the present study, the pure and La-Zr co-doped ZnO nanoparticles were prepared by sol–gel technique using zinc acetate dehydrate (Zn(Ac)2·2H2O), lanthanum nitrate hexahydrate (La(NO3)3 ·6H2O) and zirconium chloride (ZrCl4) as precursor. The structure and morphology of the prepared nanoparticle samples were studied using X-ray diffraction and transmission electron microscopy measurements. X-ray diffraction results indicated that all the samples have crystalline wurtzite phase. TEM showed that powder was polycrystalline in nature with random distribution of the pure and La-Zr doped ZnO nanoparticles. We demonstrate strain-size evaluations for pure and doped ZnO nanoparticles from the x-ray line profile analysis. The microstructural effects of crystalline materials in terms of crystallite sizes and lattice strain on the peak broadening were investigated using Williamson-Hall (W-H) analysis and size- strain plot (SSP) method. The average crystallite size of Zn (1-x)LaxZrxO nanoparticles estimated from the W–H analysis and SSP method varied as the doping concentration increased. The incorporation of Zr4+ ion in the place of Zn2+ caused an increase in the size of nanocrystals as compared to undoped ZnO. The average particle sizes of co-doped ZnO nanoparticles estimated from the USDM model is in good agreement with the TEM results. |
publishDate |
2016 |
dc.date.none.fl_str_mv |
2016-06-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392016000300548 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392016000300548 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/1980-5373-MR-2016-0017 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.19 n.3 2016 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212667875131392 |