Corrosion Behavior of Spark Plasma Sintered Alumina and Al2O3-SiC-CNT Hybrid Nanocomposite
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000500204 |
Resumo: | Abstract The use of ceramic-based materials has become more common in many applications because of their unique characteristics and properties. Design of alumina hybrid nanocomposites achieved by incorporating two nanoreinforcements, with different morphologies and/or attributes, such as CNTs and SiC, is a new approach that has been adopted to enhance the properties of alumina. The microstructural, mechanical, electrical, and thermal properties of Al2O3-SiC-CNT hybrid nanocomposites were investigated and reported in the literature. However, the corrosion behavior was not considered. The present paper reports the electrochemical corrosion behavior of pure Al2O3 and Al2O3-5SiC-2CNT hybrid nanocomposite in acidic (2.34M HCl) and alkaline (6.5M NaOH) environments at room temperature. Ball milling (BM) and spark plasma sintering (SPS) were used for preparation of samples. The microstructure of sintered samples was investigated through field emission scanning electron microscopy (FE-SEM). Potentiodynamic polarization (PDP) technique was used to investigate the corrosion behavior. The corrosion rate of the Al2O3-5SiC-2CNT nanocomposite increased 96 and 178% in HCl and NaOH solution, respectively, compared to alumina. Possible corrosion mechanisms and factors effecting corrosion were discussed. |
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Corrosion Behavior of Spark Plasma Sintered Alumina and Al2O3-SiC-CNT Hybrid NanocompositeAluminahybrid ceramic nanocompositesspark plasma sinteringelectrochemical corrosionAbstract The use of ceramic-based materials has become more common in many applications because of their unique characteristics and properties. Design of alumina hybrid nanocomposites achieved by incorporating two nanoreinforcements, with different morphologies and/or attributes, such as CNTs and SiC, is a new approach that has been adopted to enhance the properties of alumina. The microstructural, mechanical, electrical, and thermal properties of Al2O3-SiC-CNT hybrid nanocomposites were investigated and reported in the literature. However, the corrosion behavior was not considered. The present paper reports the electrochemical corrosion behavior of pure Al2O3 and Al2O3-5SiC-2CNT hybrid nanocomposite in acidic (2.34M HCl) and alkaline (6.5M NaOH) environments at room temperature. Ball milling (BM) and spark plasma sintering (SPS) were used for preparation of samples. The microstructure of sintered samples was investigated through field emission scanning electron microscopy (FE-SEM). Potentiodynamic polarization (PDP) technique was used to investigate the corrosion behavior. The corrosion rate of the Al2O3-5SiC-2CNT nanocomposite increased 96 and 178% in HCl and NaOH solution, respectively, compared to alumina. Possible corrosion mechanisms and factors effecting corrosion were discussed.ABM, ABC, ABPol2020-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000500204Materials Research v.23 n.5 2020reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2019-0496info:eu-repo/semantics/openAccessAl-Ashwan,Z.H.Hayat,U.Toor,I.H.Hassan,Syed FidaSaheb,N.eng2020-10-09T00:00:00Zoai:scielo:S1516-14392020000500204Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2020-10-09T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Corrosion Behavior of Spark Plasma Sintered Alumina and Al2O3-SiC-CNT Hybrid Nanocomposite |
title |
Corrosion Behavior of Spark Plasma Sintered Alumina and Al2O3-SiC-CNT Hybrid Nanocomposite |
spellingShingle |
Corrosion Behavior of Spark Plasma Sintered Alumina and Al2O3-SiC-CNT Hybrid Nanocomposite Al-Ashwan,Z.H. Alumina hybrid ceramic nanocomposites spark plasma sintering electrochemical corrosion |
title_short |
Corrosion Behavior of Spark Plasma Sintered Alumina and Al2O3-SiC-CNT Hybrid Nanocomposite |
title_full |
Corrosion Behavior of Spark Plasma Sintered Alumina and Al2O3-SiC-CNT Hybrid Nanocomposite |
title_fullStr |
Corrosion Behavior of Spark Plasma Sintered Alumina and Al2O3-SiC-CNT Hybrid Nanocomposite |
title_full_unstemmed |
Corrosion Behavior of Spark Plasma Sintered Alumina and Al2O3-SiC-CNT Hybrid Nanocomposite |
title_sort |
Corrosion Behavior of Spark Plasma Sintered Alumina and Al2O3-SiC-CNT Hybrid Nanocomposite |
author |
Al-Ashwan,Z.H. |
author_facet |
Al-Ashwan,Z.H. Hayat,U. Toor,I.H. Hassan,Syed Fida Saheb,N. |
author_role |
author |
author2 |
Hayat,U. Toor,I.H. Hassan,Syed Fida Saheb,N. |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Al-Ashwan,Z.H. Hayat,U. Toor,I.H. Hassan,Syed Fida Saheb,N. |
dc.subject.por.fl_str_mv |
Alumina hybrid ceramic nanocomposites spark plasma sintering electrochemical corrosion |
topic |
Alumina hybrid ceramic nanocomposites spark plasma sintering electrochemical corrosion |
description |
Abstract The use of ceramic-based materials has become more common in many applications because of their unique characteristics and properties. Design of alumina hybrid nanocomposites achieved by incorporating two nanoreinforcements, with different morphologies and/or attributes, such as CNTs and SiC, is a new approach that has been adopted to enhance the properties of alumina. The microstructural, mechanical, electrical, and thermal properties of Al2O3-SiC-CNT hybrid nanocomposites were investigated and reported in the literature. However, the corrosion behavior was not considered. The present paper reports the electrochemical corrosion behavior of pure Al2O3 and Al2O3-5SiC-2CNT hybrid nanocomposite in acidic (2.34M HCl) and alkaline (6.5M NaOH) environments at room temperature. Ball milling (BM) and spark plasma sintering (SPS) were used for preparation of samples. The microstructure of sintered samples was investigated through field emission scanning electron microscopy (FE-SEM). Potentiodynamic polarization (PDP) technique was used to investigate the corrosion behavior. The corrosion rate of the Al2O3-5SiC-2CNT nanocomposite increased 96 and 178% in HCl and NaOH solution, respectively, compared to alumina. Possible corrosion mechanisms and factors effecting corrosion were discussed. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000500204 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000500204 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/1980-5373-mr-2019-0496 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.23 n.5 2020 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212677760057344 |