Structure and nanomechanical characterization of synthetic calcium-silicate-hydrate with poly-methacrylic acid

• Autor(a) principal: Pelisser,Fernando
• Data de Publicação: 2020
• Outros Autores: Gleize,Philippe Jean Paul, Mikowski,Alexandre
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Revista IBRACON de Estruturas e Materiais
• Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952020000500202
• topic: calcium silicate hydrate; poly-methacrylic acid; nanocomposites; nanoindentation

ABSTRACT: The principal phase of hardened Portland cement pastes is calcium silicate hydrate (C-S-H), which influences the physical and mechanical properties of construction materials. In this work, calcium silicate hydrate (C-S-H) was synthesized, with the addition of poly-methacrylic acid with sodium (PMA), for the development of C-S-H/ polymer nanocomposites. Among the polymers available, PMA is indicated in the literature as one of those viable for producing C-S-H/polymer complexes. However, no consensus exists regarding the type of interaction this produces. The resulting compounds were characterized by XRD, FT-IR, TGA, carbon content (CHN), TEM, SEM and elastic modulus and hardness were measured by instrumented indentation. A significant change was verified in the nanomechanical properties of C-S-H with PMA, resulting in reduction in the elastic modulus and hardness. The set of results presented do not confirm the intercalation of PMA in the interlayer space of C-S-H, but presented evidence of the potential for intercalation, since changes in the microstructure clearly occurred.