Structure and nanomechanical characterization of synthetic calcium-silicate-hydrate with poly-methacrylic acid
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Revista IBRACON de Estruturas e Materiais |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952020000500202 |
Resumo: | ABSTRACT: The principal phase of hardened Portland cement pastes is calcium silicate hydrate (C-S-H), which influences the physical and mechanical properties of construction materials. In this work, calcium silicate hydrate (C-S-H) was synthesized, with the addition of poly-methacrylic acid with sodium (PMA), for the development of C-S-H/ polymer nanocomposites. Among the polymers available, PMA is indicated in the literature as one of those viable for producing C-S-H/polymer complexes. However, no consensus exists regarding the type of interaction this produces. The resulting compounds were characterized by XRD, FT-IR, TGA, carbon content (CHN), TEM, SEM and elastic modulus and hardness were measured by instrumented indentation. A significant change was verified in the nanomechanical properties of C-S-H with PMA, resulting in reduction in the elastic modulus and hardness. The set of results presented do not confirm the intercalation of PMA in the interlayer space of C-S-H, but presented evidence of the potential for intercalation, since changes in the microstructure clearly occurred. |
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Structure and nanomechanical characterization of synthetic calcium-silicate-hydrate with poly-methacrylic acidcalcium silicate hydratepoly-methacrylic acidnanocompositesnanoindentationABSTRACT: The principal phase of hardened Portland cement pastes is calcium silicate hydrate (C-S-H), which influences the physical and mechanical properties of construction materials. In this work, calcium silicate hydrate (C-S-H) was synthesized, with the addition of poly-methacrylic acid with sodium (PMA), for the development of C-S-H/ polymer nanocomposites. Among the polymers available, PMA is indicated in the literature as one of those viable for producing C-S-H/polymer complexes. However, no consensus exists regarding the type of interaction this produces. The resulting compounds were characterized by XRD, FT-IR, TGA, carbon content (CHN), TEM, SEM and elastic modulus and hardness were measured by instrumented indentation. A significant change was verified in the nanomechanical properties of C-S-H with PMA, resulting in reduction in the elastic modulus and hardness. The set of results presented do not confirm the intercalation of PMA in the interlayer space of C-S-H, but presented evidence of the potential for intercalation, since changes in the microstructure clearly occurred.IBRACON - Instituto Brasileiro do Concreto2020-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952020000500202Revista IBRACON de Estruturas e Materiais v.13 n.5 2020reponame:Revista IBRACON de Estruturas e Materiaisinstname:Instituto Brasileiro do Concreto (IBRACON)instacron:IBRACON10.1590/s1983-41952020000500009info:eu-repo/semantics/openAccessPelisser,FernandoGleize,Philippe Jean PaulMikowski,Alexandreeng2020-09-17T00:00:00Zoai:scielo:S1983-41952020000500202Revistahttp://www.revistas.ibracon.org.br/index.php/riemhttps://old.scielo.br/oai/scielo-oai.phpeditores.riem@gmail.com||arlene@ibracon.org.br1983-41951983-4195opendoar:2020-09-17T00:00Revista IBRACON de Estruturas e Materiais - Instituto Brasileiro do Concreto (IBRACON)false |
dc.title.none.fl_str_mv |
Structure and nanomechanical characterization of synthetic calcium-silicate-hydrate with poly-methacrylic acid |
title |
Structure and nanomechanical characterization of synthetic calcium-silicate-hydrate with poly-methacrylic acid |
spellingShingle |
Structure and nanomechanical characterization of synthetic calcium-silicate-hydrate with poly-methacrylic acid Pelisser,Fernando calcium silicate hydrate poly-methacrylic acid nanocomposites nanoindentation |
title_short |
Structure and nanomechanical characterization of synthetic calcium-silicate-hydrate with poly-methacrylic acid |
title_full |
Structure and nanomechanical characterization of synthetic calcium-silicate-hydrate with poly-methacrylic acid |
title_fullStr |
Structure and nanomechanical characterization of synthetic calcium-silicate-hydrate with poly-methacrylic acid |
title_full_unstemmed |
Structure and nanomechanical characterization of synthetic calcium-silicate-hydrate with poly-methacrylic acid |
title_sort |
Structure and nanomechanical characterization of synthetic calcium-silicate-hydrate with poly-methacrylic acid |
author |
Pelisser,Fernando |
author_facet |
Pelisser,Fernando Gleize,Philippe Jean Paul Mikowski,Alexandre |
author_role |
author |
author2 |
Gleize,Philippe Jean Paul Mikowski,Alexandre |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Pelisser,Fernando Gleize,Philippe Jean Paul Mikowski,Alexandre |
dc.subject.por.fl_str_mv |
calcium silicate hydrate poly-methacrylic acid nanocomposites nanoindentation |
topic |
calcium silicate hydrate poly-methacrylic acid nanocomposites nanoindentation |
description |
ABSTRACT: The principal phase of hardened Portland cement pastes is calcium silicate hydrate (C-S-H), which influences the physical and mechanical properties of construction materials. In this work, calcium silicate hydrate (C-S-H) was synthesized, with the addition of poly-methacrylic acid with sodium (PMA), for the development of C-S-H/ polymer nanocomposites. Among the polymers available, PMA is indicated in the literature as one of those viable for producing C-S-H/polymer complexes. However, no consensus exists regarding the type of interaction this produces. The resulting compounds were characterized by XRD, FT-IR, TGA, carbon content (CHN), TEM, SEM and elastic modulus and hardness were measured by instrumented indentation. A significant change was verified in the nanomechanical properties of C-S-H with PMA, resulting in reduction in the elastic modulus and hardness. The set of results presented do not confirm the intercalation of PMA in the interlayer space of C-S-H, but presented evidence of the potential for intercalation, since changes in the microstructure clearly occurred. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952020000500202 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952020000500202 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/s1983-41952020000500009 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
IBRACON - Instituto Brasileiro do Concreto |
publisher.none.fl_str_mv |
IBRACON - Instituto Brasileiro do Concreto |
dc.source.none.fl_str_mv |
Revista IBRACON de Estruturas e Materiais v.13 n.5 2020 reponame:Revista IBRACON de Estruturas e Materiais instname:Instituto Brasileiro do Concreto (IBRACON) instacron:IBRACON |
instname_str |
Instituto Brasileiro do Concreto (IBRACON) |
instacron_str |
IBRACON |
institution |
IBRACON |
reponame_str |
Revista IBRACON de Estruturas e Materiais |
collection |
Revista IBRACON de Estruturas e Materiais |
repository.name.fl_str_mv |
Revista IBRACON de Estruturas e Materiais - Instituto Brasileiro do Concreto (IBRACON) |
repository.mail.fl_str_mv |
editores.riem@gmail.com||arlene@ibracon.org.br |
_version_ |
1754193606124503040 |