Phytochemistry of Trattinnickia burserifolia, T. rhoifolia, and Dacryodes hopkinsii: Chemosystematic implications

• Autor(a) principal: Lima, Maria da Paz
• Data de Publicação: 2004
• Outros Autores: Campos Braga, Patrícia Aparecida de, Macedo, Mario Lopes, Silva, Maria Fátima das Graças Fernandes da, Ferreira, Antonio Gilberto, Fernandes, João Batista, Vieira, Paulo Cezar
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Institucional do INPA
• Texto Completo: https://repositorio.inpa.gov.br/handle/1/16391
• topic: 3 Epi Alpha Amyrin; 3 Epi Beta Amyrin; 3 Oxotirucall 8,24 Dien 21 Oic; 3alpha Hydroxytirucall 7,24 Dien 21 Oic; 3alpha Hydroxytirucall 8,24 Dien 21 Oic; 3alpha,16beta Dihydroxyolean 12 Ene; 3alpha,16beta Dihydroxyurs 12 Ene; 3alpha,20 Dihydroxydammar 24 Ene; 3beta Phenylacetoxyurs 12 Ene 3beta Phenylacetoxyolean 12 Ene; 3beta,16beta,11alpha Trihydroxyurs 12 Ene; Acid; Alpha Amyrenone; Alpha Amyrin; Beta Amyrenone; Beta Amyrin; Dammarane Derivative; Dammarenediol; Lupenone; Lupeol; Monoterpene Phenylacetoxy 4 Mentha 1(7),5 Diene; Plant Extract; Sitosterol; Stigmasterol; Terpene; Tirucallol; Triterpene Derivative; Unclassified Drug; Carbon Nuclear Magnetic Resonance; Chemical Analysis; Chemotaxonomy; Controlled Study; Dacryodes Hopkinsii; Isolation Procedure; Nonhuman; Phytochemistry; Plant; Trattinnickia Burserifolia; Trattinnickia Rhoifolia

Trattinnickia burserifolia has yielded the known ursanes, α-amyrenone, α-amyrin, 3-epi-α-amyrin, 3α,16β- dihydroxyurs-12-ene, the oleananes β-amyrenone, β-amyrin, 3-epi-β-amyrin, 3α,16β-dihydroxyolean-12-ene, the tirucallane acids 3α-hydroxytirucall-8,24-dien-21-oic, 3α-hydroxytirucall-7,24- dien-21-oic and 3-oxotirucall-8,24-dien-21-oic, the dammaranes dammarenediol-II and 3α,20(S)-dihydroxydammar-24-ene. Besides it was isolated the new monoterpene 2(S*)-phenylacetoxy-4(R*)-p-mentha-1(7),5-diene and, the new triterpenes 3β-phenylacetoxyurs-12-ene, 3β-phenylacetoxyolean-12- ene and 3β,16β,11α-trihydroxyurs-12-ene. The triterpenes from T. burserifolia, T. rhoifolia and Dacryodes were analyzed in mixture. Their 13C NMR spectra showed that the major triterpenes were in T. burserifolia α-amyrin and β-amyrin; in T. rhoifolia α-amyrin, β-amyrin, 3-epi-α-amyrin, 3-epi-β-amyrin, and lupenone; in T. rhoifolia α-amyrin, β-amyrin, 3-epi-α-amyrin, 3-epi-β-amyrin, 3α-hydroxytirucall-8,24-dien-21-oic acid and 3α-hydroxytirucall-7,24-dien-21-oic acid; in D. hopkinsii α-amyrin, β-amyrin, lupeol, tirucallol, sitosterol and stigmasterol. Aspects of chemosystematic of the tribe Protieae are discussed.