Vapor pressure and thermophysical properties of eugenol and (+)-carvone

Detalhes bibliográficos
Autor(a) principal: Vilas-Boas, Sérgio M.
Data de Publicação: 2018
Outros Autores: Pokorný, Václav, Štejfa, Vojtech, Ferreira, Olga, Pinho, Simão, Růžička, Květoslav, Fulem, Michal
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10198/20116
Resumo: In this work, vapor pressures, liquid-phase heat capacities, and phase behavior of two monoterpenoids, (þ)-carvone and eugenol were studied. The vapor pressure experiments were performed using a static method over an environmentally relevant range of temperatures, from 258 K to 308 K. Liquid-phase heat capacities were measured by Tian-Calvet calorimetry between 265 K and 355 K. The phase behavior was investigated by heat-flux differential scanning calorimetry from 183 K. Experimental data were supplemented by ideal-gas thermodynamic properties obtained by combining quantum chemical and statistical thermodynamic calculations. Vapor pressures and heat capacities obtained in this work along with selected literature values were treated simultaneously by multi-property correlation in order to obtain a consistent description of thermodynamically linked properties. To our knowledge, liquid-phase heat capacities and phase behavior of eugenol are reported for the first time in this work.
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spelling Vapor pressure and thermophysical properties of eugenol and (+)-carvoneHeat capacityPolymorphic behaviorTerpenoidsVapor pressureIn this work, vapor pressures, liquid-phase heat capacities, and phase behavior of two monoterpenoids, (þ)-carvone and eugenol were studied. The vapor pressure experiments were performed using a static method over an environmentally relevant range of temperatures, from 258 K to 308 K. Liquid-phase heat capacities were measured by Tian-Calvet calorimetry between 265 K and 355 K. The phase behavior was investigated by heat-flux differential scanning calorimetry from 183 K. Experimental data were supplemented by ideal-gas thermodynamic properties obtained by combining quantum chemical and statistical thermodynamic calculations. Vapor pressures and heat capacities obtained in this work along with selected literature values were treated simultaneously by multi-property correlation in order to obtain a consistent description of thermodynamically linked properties. To our knowledge, liquid-phase heat capacities and phase behavior of eugenol are reported for the first time in this work.The authors M.F., K.R., V. S., and V.P. acknowledge financial support from the Czech Science Foundation (GACR no. 17-03875S) and specific university research (MSMT No. 20-SVV/2018). The authors S.M.V., O.F., and S.P.P. acknowledge financial support from the project POCI-01-0145-FEDER-006984 e Associate Laboratory LSRE-LCM (UID/EQU/50020/2019) funded by national funds through FCT/MCTES (PIDDAC). S.M.V. also acknowledges FCT for his PhD grant (SFRH/BD/138149/2018).Biblioteca Digital do IPBVilas-Boas, Sérgio M.Pokorný, VáclavŠtejfa, VojtechFerreira, OlgaPinho, SimãoRůžička, KvětoslavFulem, Michal2018-01-19T10:00:00Z20192019-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10198/20116engVilas-Boas, Sérgio M.; Pokorný, Václav; Štejfa, Vojtěch; Ferreira, Olga; Pinho, Simão P.; Růžička, K.; Fulem, Michal (2019). Vapor pressure and thermophysical properties of eugenol and (+)-carvone. Fluid Phase Equilibria. ISSN 0378-3812. 499, p. 1-100378-381210.1016/j.fluid.2019.112248info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-12-20T01:18:04Zoai:bibliotecadigital.ipb.pt:10198/20116Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T23:10:55.105508Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Vapor pressure and thermophysical properties of eugenol and (+)-carvone
title Vapor pressure and thermophysical properties of eugenol and (+)-carvone
spellingShingle Vapor pressure and thermophysical properties of eugenol and (+)-carvone
Vilas-Boas, Sérgio M.
Heat capacity
Polymorphic behavior
Terpenoids
Vapor pressure
title_short Vapor pressure and thermophysical properties of eugenol and (+)-carvone
title_full Vapor pressure and thermophysical properties of eugenol and (+)-carvone
title_fullStr Vapor pressure and thermophysical properties of eugenol and (+)-carvone
title_full_unstemmed Vapor pressure and thermophysical properties of eugenol and (+)-carvone
title_sort Vapor pressure and thermophysical properties of eugenol and (+)-carvone
author Vilas-Boas, Sérgio M.
author_facet Vilas-Boas, Sérgio M.
Pokorný, Václav
Štejfa, Vojtech
Ferreira, Olga
Pinho, Simão
Růžička, Květoslav
Fulem, Michal
author_role author
author2 Pokorný, Václav
Štejfa, Vojtech
Ferreira, Olga
Pinho, Simão
Růžička, Květoslav
Fulem, Michal
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Biblioteca Digital do IPB
dc.contributor.author.fl_str_mv Vilas-Boas, Sérgio M.
Pokorný, Václav
Štejfa, Vojtech
Ferreira, Olga
Pinho, Simão
Růžička, Květoslav
Fulem, Michal
dc.subject.por.fl_str_mv Heat capacity
Polymorphic behavior
Terpenoids
Vapor pressure
topic Heat capacity
Polymorphic behavior
Terpenoids
Vapor pressure
description In this work, vapor pressures, liquid-phase heat capacities, and phase behavior of two monoterpenoids, (þ)-carvone and eugenol were studied. The vapor pressure experiments were performed using a static method over an environmentally relevant range of temperatures, from 258 K to 308 K. Liquid-phase heat capacities were measured by Tian-Calvet calorimetry between 265 K and 355 K. The phase behavior was investigated by heat-flux differential scanning calorimetry from 183 K. Experimental data were supplemented by ideal-gas thermodynamic properties obtained by combining quantum chemical and statistical thermodynamic calculations. Vapor pressures and heat capacities obtained in this work along with selected literature values were treated simultaneously by multi-property correlation in order to obtain a consistent description of thermodynamically linked properties. To our knowledge, liquid-phase heat capacities and phase behavior of eugenol are reported for the first time in this work.
publishDate 2018
dc.date.none.fl_str_mv 2018-01-19T10:00:00Z
2019
2019-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10198/20116
url http://hdl.handle.net/10198/20116
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Vilas-Boas, Sérgio M.; Pokorný, Václav; Štejfa, Vojtěch; Ferreira, Olga; Pinho, Simão P.; Růžička, K.; Fulem, Michal (2019). Vapor pressure and thermophysical properties of eugenol and (+)-carvone. Fluid Phase Equilibria. ISSN 0378-3812. 499, p. 1-10
0378-3812
10.1016/j.fluid.2019.112248
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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