Vapor-Liquid Equilibria for Pentane + Dodecane and Heptane + Dodecane at Low Pressures
Autor(a) principal: | |
---|---|
Data de Publicação: | 2002 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/44877 |
Resumo: | A Fischer recirculating still has been used to measure isobaric vapor-liquid equilibrium data for pentane + dodecane and heptane + dodecane at 70 and 100 kPa and 40, 70, and 100 kPa, respectively. The concentrations of the vapor and liquid mixtures have been determined with the aid of an oscillating tube densimeter. The excess volume behavior has also been found on the basis of density-composition calibration curves. Vapor pressure data of the pure components as function of the temperature have also been measured and indicated the reliability of the experimental procedure. Thermodynamic consistency tests of the vapor-liquid data have been checked using a maximum likelihood data reduction and the UNIQUAC model |
id |
UFRN_4509c7eb835c01f60c3db16251277b70 |
---|---|
oai_identifier_str |
oai:https://repositorio.ufrn.br:123456789/44877 |
network_acronym_str |
UFRN |
network_name_str |
Repositório Institucional da UFRN |
repository_id_str |
|
spelling |
Chiavone Filho, OsvaldoOliveira, Humberto Neves Maia deLopes, Francisco W. BezerraDantas Neto, Afonso Avelino2021-11-10T19:58:04Z2021-11-10T19:58:04Z2002-10-25CHIAVONE-FILHO, Osvaldo; OLIVEIRA, Humberto Neves Maia de ; DANTAS NETO, Afonso Avelino ; LOPES, F. W. B.. Vapor−Liquid Equilibria for Pentane + Dodecane and Heptane + Dodecane at Low Pressures. Journal of Chemical and Engineering Data, USA, v. 47, p. 1384-1387, 2002. Disponível em: https://pubs.acs.org/doi/10.1021/je020037u. Acesso em: 15 jun. 2021. https://doi.org/10.1021/je020037u.0021-95681520-5134https://repositorio.ufrn.br/handle/123456789/4487710.1021/je020037uACS PublicationsAttribution-NonCommercial-NoDerivs 3.0 Brazilhttp://creativecommons.org/licenses/by-nc-nd/3.0/br/info:eu-repo/semantics/openAccessVapor liquid equilibriumLiquidsEquilibriumVapor pressureMathematical methodsVapor-Liquid Equilibria for Pentane + Dodecane and Heptane + Dodecane at Low Pressuresinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleA Fischer recirculating still has been used to measure isobaric vapor-liquid equilibrium data for pentane + dodecane and heptane + dodecane at 70 and 100 kPa and 40, 70, and 100 kPa, respectively. The concentrations of the vapor and liquid mixtures have been determined with the aid of an oscillating tube densimeter. The excess volume behavior has also been found on the basis of density-composition calibration curves. Vapor pressure data of the pure components as function of the temperature have also been measured and indicated the reliability of the experimental procedure. Thermodynamic consistency tests of the vapor-liquid data have been checked using a maximum likelihood data reduction and the UNIQUAC modelengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALVapor−LiquidEquilibriaPentane_ChiavoneFilho_2002.pdfVapor−LiquidEquilibriaPentane_ChiavoneFilho_2002.pdfapplication/pdf44780https://repositorio.ufrn.br/bitstream/123456789/44877/1/Vapor%e2%88%92LiquidEquilibriaPentane_ChiavoneFilho_2002.pdf349a335233332e9f826d93593e9c2610MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8811https://repositorio.ufrn.br/bitstream/123456789/44877/2/license_rdfe39d27027a6cc9cb039ad269a5db8e34MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/44877/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53123456789/448772021-11-10 16:58:05.561oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-11-10T19:58:05Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pt_BR.fl_str_mv |
Vapor-Liquid Equilibria for Pentane + Dodecane and Heptane + Dodecane at Low Pressures |
title |
Vapor-Liquid Equilibria for Pentane + Dodecane and Heptane + Dodecane at Low Pressures |
spellingShingle |
Vapor-Liquid Equilibria for Pentane + Dodecane and Heptane + Dodecane at Low Pressures Chiavone Filho, Osvaldo Vapor liquid equilibrium Liquids Equilibrium Vapor pressure Mathematical methods |
title_short |
Vapor-Liquid Equilibria for Pentane + Dodecane and Heptane + Dodecane at Low Pressures |
title_full |
Vapor-Liquid Equilibria for Pentane + Dodecane and Heptane + Dodecane at Low Pressures |
title_fullStr |
Vapor-Liquid Equilibria for Pentane + Dodecane and Heptane + Dodecane at Low Pressures |
title_full_unstemmed |
Vapor-Liquid Equilibria for Pentane + Dodecane and Heptane + Dodecane at Low Pressures |
title_sort |
Vapor-Liquid Equilibria for Pentane + Dodecane and Heptane + Dodecane at Low Pressures |
author |
Chiavone Filho, Osvaldo |
author_facet |
Chiavone Filho, Osvaldo Oliveira, Humberto Neves Maia de Lopes, Francisco W. Bezerra Dantas Neto, Afonso Avelino |
author_role |
author |
author2 |
Oliveira, Humberto Neves Maia de Lopes, Francisco W. Bezerra Dantas Neto, Afonso Avelino |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Chiavone Filho, Osvaldo Oliveira, Humberto Neves Maia de Lopes, Francisco W. Bezerra Dantas Neto, Afonso Avelino |
dc.subject.por.fl_str_mv |
Vapor liquid equilibrium Liquids Equilibrium Vapor pressure Mathematical methods |
topic |
Vapor liquid equilibrium Liquids Equilibrium Vapor pressure Mathematical methods |
description |
A Fischer recirculating still has been used to measure isobaric vapor-liquid equilibrium data for pentane + dodecane and heptane + dodecane at 70 and 100 kPa and 40, 70, and 100 kPa, respectively. The concentrations of the vapor and liquid mixtures have been determined with the aid of an oscillating tube densimeter. The excess volume behavior has also been found on the basis of density-composition calibration curves. Vapor pressure data of the pure components as function of the temperature have also been measured and indicated the reliability of the experimental procedure. Thermodynamic consistency tests of the vapor-liquid data have been checked using a maximum likelihood data reduction and the UNIQUAC model |
publishDate |
2002 |
dc.date.issued.fl_str_mv |
2002-10-25 |
dc.date.accessioned.fl_str_mv |
2021-11-10T19:58:04Z |
dc.date.available.fl_str_mv |
2021-11-10T19:58:04Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
CHIAVONE-FILHO, Osvaldo; OLIVEIRA, Humberto Neves Maia de ; DANTAS NETO, Afonso Avelino ; LOPES, F. W. B.. Vapor−Liquid Equilibria for Pentane + Dodecane and Heptane + Dodecane at Low Pressures. Journal of Chemical and Engineering Data, USA, v. 47, p. 1384-1387, 2002. Disponível em: https://pubs.acs.org/doi/10.1021/je020037u. Acesso em: 15 jun. 2021. https://doi.org/10.1021/je020037u. |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/44877 |
dc.identifier.issn.none.fl_str_mv |
0021-9568 1520-5134 |
dc.identifier.doi.none.fl_str_mv |
10.1021/je020037u |
identifier_str_mv |
CHIAVONE-FILHO, Osvaldo; OLIVEIRA, Humberto Neves Maia de ; DANTAS NETO, Afonso Avelino ; LOPES, F. W. B.. Vapor−Liquid Equilibria for Pentane + Dodecane and Heptane + Dodecane at Low Pressures. Journal of Chemical and Engineering Data, USA, v. 47, p. 1384-1387, 2002. Disponível em: https://pubs.acs.org/doi/10.1021/je020037u. Acesso em: 15 jun. 2021. https://doi.org/10.1021/je020037u. 0021-9568 1520-5134 10.1021/je020037u |
url |
https://repositorio.ufrn.br/handle/123456789/44877 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
Attribution-NonCommercial-NoDerivs 3.0 Brazil http://creativecommons.org/licenses/by-nc-nd/3.0/br/ info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
Attribution-NonCommercial-NoDerivs 3.0 Brazil http://creativecommons.org/licenses/by-nc-nd/3.0/br/ |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
ACS Publications |
publisher.none.fl_str_mv |
ACS Publications |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFRN instname:Universidade Federal do Rio Grande do Norte (UFRN) instacron:UFRN |
instname_str |
Universidade Federal do Rio Grande do Norte (UFRN) |
instacron_str |
UFRN |
institution |
UFRN |
reponame_str |
Repositório Institucional da UFRN |
collection |
Repositório Institucional da UFRN |
bitstream.url.fl_str_mv |
https://repositorio.ufrn.br/bitstream/123456789/44877/1/Vapor%e2%88%92LiquidEquilibriaPentane_ChiavoneFilho_2002.pdf https://repositorio.ufrn.br/bitstream/123456789/44877/2/license_rdf https://repositorio.ufrn.br/bitstream/123456789/44877/3/license.txt |
bitstream.checksum.fl_str_mv |
349a335233332e9f826d93593e9c2610 e39d27027a6cc9cb039ad269a5db8e34 e9597aa2854d128fd968be5edc8a28d9 |
bitstream.checksumAlgorithm.fl_str_mv |
MD5 MD5 MD5 |
repository.name.fl_str_mv |
Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN) |
repository.mail.fl_str_mv |
|
_version_ |
1814833004096258048 |