Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation

Detalhes bibliográficos
Autor(a) principal: Martins, Luisa
Data de Publicação: 2016
Outros Autores: Ribeiro, A. P. C., Carabineiro, S. A. C., Figueiredo, J. L., Pombeiro, Armando
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.21/6276
Resumo: The highly efficient eco-friendly synthesis of ketones (yields over 99%) from secondary alcohols is achieved by combination of [FeCl2{eta(3)-HC(pz)(3)}] (pz = pyrazol-1-yl) supported on functionalized multi-walled carbon nanotubes and microwave irradiation, in a solvent-free medium. The carbon homoscorpionate iron(II) complex is the first one of this class to be used as catalyst for the oxidation of alcohols.
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spelling Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidationCyclohexane oxidationHydrogen-peroxideAerobic oxidationComplexesXPSRadicalsFEThe highly efficient eco-friendly synthesis of ketones (yields over 99%) from secondary alcohols is achieved by combination of [FeCl2{eta(3)-HC(pz)(3)}] (pz = pyrazol-1-yl) supported on functionalized multi-walled carbon nanotubes and microwave irradiation, in a solvent-free medium. The carbon homoscorpionate iron(II) complex is the first one of this class to be used as catalyst for the oxidation of alcohols.Royal Soc ChemistryRCIPLMartins, LuisaRibeiro, A. P. C.Carabineiro, S. A. C.Figueiredo, J. L.Pombeiro, Armando2016-06-30T15:24:00Z20162016-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.21/6276engMARTINS, Luisa Margarida Dias Ribeiro de Sousa; [et al.] - Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation. Dalton Transactions. ISSN 1477-9226. Vol. 45, N.º 16, (2016), pp. 6816-68191477-922610.1039/c6dt00514dmetadata only accessinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-08-03T09:50:53Zoai:repositorio.ipl.pt:10400.21/6276Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:15:26.287433Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation
title Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation
spellingShingle Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation
Martins, Luisa
Cyclohexane oxidation
Hydrogen-peroxide
Aerobic oxidation
Complexes
XPS
Radicals
FE
title_short Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation
title_full Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation
title_fullStr Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation
title_full_unstemmed Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation
title_sort Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation
author Martins, Luisa
author_facet Martins, Luisa
Ribeiro, A. P. C.
Carabineiro, S. A. C.
Figueiredo, J. L.
Pombeiro, Armando
author_role author
author2 Ribeiro, A. P. C.
Carabineiro, S. A. C.
Figueiredo, J. L.
Pombeiro, Armando
author2_role author
author
author
author
dc.contributor.none.fl_str_mv RCIPL
dc.contributor.author.fl_str_mv Martins, Luisa
Ribeiro, A. P. C.
Carabineiro, S. A. C.
Figueiredo, J. L.
Pombeiro, Armando
dc.subject.por.fl_str_mv Cyclohexane oxidation
Hydrogen-peroxide
Aerobic oxidation
Complexes
XPS
Radicals
FE
topic Cyclohexane oxidation
Hydrogen-peroxide
Aerobic oxidation
Complexes
XPS
Radicals
FE
description The highly efficient eco-friendly synthesis of ketones (yields over 99%) from secondary alcohols is achieved by combination of [FeCl2{eta(3)-HC(pz)(3)}] (pz = pyrazol-1-yl) supported on functionalized multi-walled carbon nanotubes and microwave irradiation, in a solvent-free medium. The carbon homoscorpionate iron(II) complex is the first one of this class to be used as catalyst for the oxidation of alcohols.
publishDate 2016
dc.date.none.fl_str_mv 2016-06-30T15:24:00Z
2016
2016-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.21/6276
url http://hdl.handle.net/10400.21/6276
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv MARTINS, Luisa Margarida Dias Ribeiro de Sousa; [et al.] - Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation. Dalton Transactions. ISSN 1477-9226. Vol. 45, N.º 16, (2016), pp. 6816-6819
1477-9226
10.1039/c6dt00514d
dc.rights.driver.fl_str_mv metadata only access
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rights_invalid_str_mv metadata only access
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Royal Soc Chemistry
publisher.none.fl_str_mv Royal Soc Chemistry
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
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reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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