Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst

Detalhes bibliográficos
Autor(a) principal: Ribeiro, A. P. C.
Data de Publicação: 2017
Outros Autores: Martins, Luisa, Pombeiro, Armando
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.21/7623
Resumo: The highly efficient eco-friendly synthesis of methanol (44% yield, TONs up to 2.3 x 10(3)) directly from carbon dioxide is achieved by using H-2 and the iron(II) scorpionate catalyst [FeCl2{kappa(3)- HC(pz)(3)}] (pz = pyrazol-1-yl) in a solvent- or amine-free mild new protocol.
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spelling Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalystRuthenium pincer complexesComputational designCyclohexane oxidationMechanistic insightsCO2 hydrogenationMetal catalystsBicarbonatesFormamidesReductionPeroxideThe highly efficient eco-friendly synthesis of methanol (44% yield, TONs up to 2.3 x 10(3)) directly from carbon dioxide is achieved by using H-2 and the iron(II) scorpionate catalyst [FeCl2{kappa(3)- HC(pz)(3)}] (pz = pyrazol-1-yl) in a solvent- or amine-free mild new protocol.Royal Society of ChemistryRCIPLRibeiro, A. P. C.Martins, LuisaPombeiro, Armando2017-11-29T14:17:19Z2017-10-212017-10-21T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.21/7623engRIBEIRO, A. P. C.; MARTINS, L. M. D. R. S.; POMBEIRO, A. J. L. – Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst. Green Chemistry. ISSN 1463-9262. Vol. 19, N.º 20 (2017), pp. 4811-48151463-926210.1039/c7gc01993ametadata only accessinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-08-03T09:53:55Zoai:repositorio.ipl.pt:10400.21/7623Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:16:31.543117Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst
title Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst
spellingShingle Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst
Ribeiro, A. P. C.
Ruthenium pincer complexes
Computational design
Cyclohexane oxidation
Mechanistic insights
CO2 hydrogenation
Metal catalysts
Bicarbonates
Formamides
Reduction
Peroxide
title_short Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst
title_full Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst
title_fullStr Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst
title_full_unstemmed Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst
title_sort Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst
author Ribeiro, A. P. C.
author_facet Ribeiro, A. P. C.
Martins, Luisa
Pombeiro, Armando
author_role author
author2 Martins, Luisa
Pombeiro, Armando
author2_role author
author
dc.contributor.none.fl_str_mv RCIPL
dc.contributor.author.fl_str_mv Ribeiro, A. P. C.
Martins, Luisa
Pombeiro, Armando
dc.subject.por.fl_str_mv Ruthenium pincer complexes
Computational design
Cyclohexane oxidation
Mechanistic insights
CO2 hydrogenation
Metal catalysts
Bicarbonates
Formamides
Reduction
Peroxide
topic Ruthenium pincer complexes
Computational design
Cyclohexane oxidation
Mechanistic insights
CO2 hydrogenation
Metal catalysts
Bicarbonates
Formamides
Reduction
Peroxide
description The highly efficient eco-friendly synthesis of methanol (44% yield, TONs up to 2.3 x 10(3)) directly from carbon dioxide is achieved by using H-2 and the iron(II) scorpionate catalyst [FeCl2{kappa(3)- HC(pz)(3)}] (pz = pyrazol-1-yl) in a solvent- or amine-free mild new protocol.
publishDate 2017
dc.date.none.fl_str_mv 2017-11-29T14:17:19Z
2017-10-21
2017-10-21T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.21/7623
url http://hdl.handle.net/10400.21/7623
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv RIBEIRO, A. P. C.; MARTINS, L. M. D. R. S.; POMBEIRO, A. J. L. – Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst. Green Chemistry. ISSN 1463-9262. Vol. 19, N.º 20 (2017), pp. 4811-4815
1463-9262
10.1039/c7gc01993a
dc.rights.driver.fl_str_mv metadata only access
info:eu-repo/semantics/openAccess
rights_invalid_str_mv metadata only access
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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