Bioremediation of Textile Industrial Effluents Using Nutraceutical Industrial Spent

Detalhes bibliográficos
Autor(a) principal: Taqui, Syed Noeman
Data de Publicação: 2022
Outros Autores: Syed, Usman Taqui, Syed, Raihan Taqui, Alqahtani, Mohammed Saeed, Abbas, Mohamed, Syed, Akheel Ahmed
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/151027
Resumo: Funding Information: The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University (KKU) for funding this research through the Research Group Program under the Grant Number: R.G.P.2/248/43. Publisher Copyright: © 2022 by the authors. Licensee MDPI, Basel, Switzerland.
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spelling Bioremediation of Textile Industrial Effluents Using Nutraceutical Industrial SpentLaboratory-Scale Demonstration of Circular Economybioremediationcircular economycompositesNutraceutical Industrial SpentSMEtextile industrial effluentChemical Engineering(all)Materials Science(all)SDG 8 - Decent Work and Economic GrowthSDG 9 - Industry, Innovation, and InfrastructureSDG 12 - Responsible Consumption and ProductionFunding Information: The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University (KKU) for funding this research through the Research Group Program under the Grant Number: R.G.P.2/248/43. Publisher Copyright: © 2022 by the authors. Licensee MDPI, Basel, Switzerland.This research reports the first-ever study on abundantly available, environmentally friendly, low-cost and ready-for-use Nutraceutical Industrial Cumin Seed Spent (NICUS) as an innovative adsorbent for bioremediation of a bisazo Acid Red 119 (AR119) dye, a probable mutagen from textile industrial effluents (TIEs). The experiment at the laboratory scale is designed to suit the concepts of sustainability and valorisation under the domain of circular economy. The experimental qe value obtained was 96.00 mg g−1 . The optimised conditions of parameters are as follows: pH of 2; adsorption time, 210 min; adsorbent dosage, 0.300 g L−1; particle size, 175 µM; initial dye concentration, 950 mg L−1; orbital shaking, 165 rpm and temperature, 50◦C, producing an impressive value of 748 mg of dye adsorbing on 1 g of dry NICUS. The adsorption capacity of NICUS obtained from the quadratic model developed for process optimisation gave values of 748 mg g−1 . As a prelude to commercialisation, five variables that affect the adsorption process were experimentally studied. For the feasibility and efficiency of the process, a two-level fractional factorial experimental design (FFED) was applied to identify variables that influence the adsorption capacity of NICUS. The identified variables were applied to scale experiments by three orders. Nine isotherm models were used to analyse the adsorption equilibrium data. The Vieth–Sladek adsorption isotherm model was found to be the best fit. The pseudo-second-order reaction was the appropriate mechanism for the overall rate of the adsorption process. Mechanistic studies related to mass transfer phenomena were more likely to be dominant over the diffusion process. Techniques such as SEM, FTIR and CHN analysis were used to characterise NICUS. The dye-adsorbed NICUS obtained as “sludge” was used as a reinforcing material for the fabrication of composites using plastic waste. The physicomechanical and chemical properties of thermoplastic and thermoset composite using dye-adsorbed NICUS were evaluated and compared with NICUS composites. Prospects of integrating Small and Medium Enterprises (SMEs) into the circular economy of Nutraceutical Industrial Spent (NIS) are discussed.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNTaqui, Syed NoemanSyed, Usman TaquiSyed, Raihan TaquiAlqahtani, Mohammed SaeedAbbas, MohamedSyed, Akheel Ahmed2023-03-21T22:28:25Z2022-05-152022-05-15T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article25application/pdfhttp://hdl.handle.net/10362/151027eng2079-4991PURE: 56521487https://doi.org/10.3390/nano12101684info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:33:28Zoai:run.unl.pt:10362/151027Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:54:25.751760Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Bioremediation of Textile Industrial Effluents Using Nutraceutical Industrial Spent
Laboratory-Scale Demonstration of Circular Economy
title Bioremediation of Textile Industrial Effluents Using Nutraceutical Industrial Spent
spellingShingle Bioremediation of Textile Industrial Effluents Using Nutraceutical Industrial Spent
Taqui, Syed Noeman
bioremediation
circular economy
composites
Nutraceutical Industrial Spent
SME
textile industrial effluent
Chemical Engineering(all)
Materials Science(all)
SDG 8 - Decent Work and Economic Growth
SDG 9 - Industry, Innovation, and Infrastructure
SDG 12 - Responsible Consumption and Production
title_short Bioremediation of Textile Industrial Effluents Using Nutraceutical Industrial Spent
title_full Bioremediation of Textile Industrial Effluents Using Nutraceutical Industrial Spent
title_fullStr Bioremediation of Textile Industrial Effluents Using Nutraceutical Industrial Spent
title_full_unstemmed Bioremediation of Textile Industrial Effluents Using Nutraceutical Industrial Spent
title_sort Bioremediation of Textile Industrial Effluents Using Nutraceutical Industrial Spent
author Taqui, Syed Noeman
author_facet Taqui, Syed Noeman
Syed, Usman Taqui
Syed, Raihan Taqui
Alqahtani, Mohammed Saeed
Abbas, Mohamed
Syed, Akheel Ahmed
author_role author
author2 Syed, Usman Taqui
Syed, Raihan Taqui
Alqahtani, Mohammed Saeed
Abbas, Mohamed
Syed, Akheel Ahmed
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Taqui, Syed Noeman
Syed, Usman Taqui
Syed, Raihan Taqui
Alqahtani, Mohammed Saeed
Abbas, Mohamed
Syed, Akheel Ahmed
dc.subject.por.fl_str_mv bioremediation
circular economy
composites
Nutraceutical Industrial Spent
SME
textile industrial effluent
Chemical Engineering(all)
Materials Science(all)
SDG 8 - Decent Work and Economic Growth
SDG 9 - Industry, Innovation, and Infrastructure
SDG 12 - Responsible Consumption and Production
topic bioremediation
circular economy
composites
Nutraceutical Industrial Spent
SME
textile industrial effluent
Chemical Engineering(all)
Materials Science(all)
SDG 8 - Decent Work and Economic Growth
SDG 9 - Industry, Innovation, and Infrastructure
SDG 12 - Responsible Consumption and Production
description Funding Information: The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University (KKU) for funding this research through the Research Group Program under the Grant Number: R.G.P.2/248/43. Publisher Copyright: © 2022 by the authors. Licensee MDPI, Basel, Switzerland.
publishDate 2022
dc.date.none.fl_str_mv 2022-05-15
2022-05-15T00:00:00Z
2023-03-21T22:28:25Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/151027
url http://hdl.handle.net/10362/151027
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2079-4991
PURE: 56521487
https://doi.org/10.3390/nano12101684
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 25
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instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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