Functionalization of fluorinated ionic liquids: A combined experimental-theoretical study

Detalhes bibliográficos
Autor(a) principal: Ferreira, Margarida L.
Data de Publicação: 2020
Outros Autores: Araújo, João M. M., Vega, Lourdes F., Llovell, Fèlix, Pereiro, Ana B.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/107732
Resumo: FCT/MCTES (Portugal), through: grant SFRH/BD/130965/2017 (M.LF.); Investigador FCT 2014 (IF/00190/2014 to A.B.P. and IF/00210/2014 to J.M.M.A.); projects PTDC/EQU-EQU/29737/2017, PTDC/QEQ-FTT/3289/2014 and IF/00210/2014/CP1244/CT0003. Associate Laboratory for Green Chemistry-LAQV, financed by national funds from FCT/MCTES (UID/QUI/50006/2019). projects 2018-LC-01 and 2019-URL-IR1rQ-011, from Obra Social "la Caixa" and by Khalifa University through project RCII-2018-0024.
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spelling Functionalization of fluorinated ionic liquids: A combined experimental-theoretical studyFluorosurfactantsHydroxyl groupSelf-aggregationSoft-SAFTThermophysical and thermodynamic propertiesElectronic, Optical and Magnetic MaterialsAtomic and Molecular Physics, and OpticsCondensed Matter PhysicsSpectroscopyPhysical and Theoretical ChemistryMaterials ChemistryFCT/MCTES (Portugal), through: grant SFRH/BD/130965/2017 (M.LF.); Investigador FCT 2014 (IF/00190/2014 to A.B.P. and IF/00210/2014 to J.M.M.A.); projects PTDC/EQU-EQU/29737/2017, PTDC/QEQ-FTT/3289/2014 and IF/00210/2014/CP1244/CT0003. Associate Laboratory for Green Chemistry-LAQV, financed by national funds from FCT/MCTES (UID/QUI/50006/2019). projects 2018-LC-01 and 2019-URL-IR1rQ-011, from Obra Social "la Caixa" and by Khalifa University through project RCII-2018-0024.We present new experimental and modelling data concerning imidazolium based-FILs synthesized with a hydroxyl group in the end of the cationic hydrogenated side chain and compared them with the analogous non-functionalized FILs in order to verify their suitability in the biomedical field. The thermophysical and thermodynamic properties of the neat compounds and the self-aggregation behaviour of FILs in aqueous solutions were measured and compared with theoretical results from the soft-SAFT equation of state, in good agreement with each other. Results showed that the presence of the hydroxyl group increases the density and viscosity of pure compounds and aqueous mixtures, whereas the thermal stability, melting, free volume, ionicity and self-aggregation behaviour decrease. These properties are improved with respect to the conventional perfluorosurfactants for the desired application, due to the full miscibility in water and the promising improved biocompatibility.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNFerreira, Margarida L.Araújo, João M. M.Vega, Lourdes F.Llovell, FèlixPereiro, Ana B.2022-03-23T01:31:16Z2020-03-152020-03-15T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10362/107732eng0167-7322PURE: 16874928https://doi.org/10.1016/j.molliq.2020.112489info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T04:52:22Zoai:run.unl.pt:10362/107732Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:41:02.534397Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Functionalization of fluorinated ionic liquids: A combined experimental-theoretical study
title Functionalization of fluorinated ionic liquids: A combined experimental-theoretical study
spellingShingle Functionalization of fluorinated ionic liquids: A combined experimental-theoretical study
Ferreira, Margarida L.
Fluorosurfactants
Hydroxyl group
Self-aggregation
Soft-SAFT
Thermophysical and thermodynamic properties
Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry
Materials Chemistry
title_short Functionalization of fluorinated ionic liquids: A combined experimental-theoretical study
title_full Functionalization of fluorinated ionic liquids: A combined experimental-theoretical study
title_fullStr Functionalization of fluorinated ionic liquids: A combined experimental-theoretical study
title_full_unstemmed Functionalization of fluorinated ionic liquids: A combined experimental-theoretical study
title_sort Functionalization of fluorinated ionic liquids: A combined experimental-theoretical study
author Ferreira, Margarida L.
author_facet Ferreira, Margarida L.
Araújo, João M. M.
Vega, Lourdes F.
Llovell, Fèlix
Pereiro, Ana B.
author_role author
author2 Araújo, João M. M.
Vega, Lourdes F.
Llovell, Fèlix
Pereiro, Ana B.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Ferreira, Margarida L.
Araújo, João M. M.
Vega, Lourdes F.
Llovell, Fèlix
Pereiro, Ana B.
dc.subject.por.fl_str_mv Fluorosurfactants
Hydroxyl group
Self-aggregation
Soft-SAFT
Thermophysical and thermodynamic properties
Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry
Materials Chemistry
topic Fluorosurfactants
Hydroxyl group
Self-aggregation
Soft-SAFT
Thermophysical and thermodynamic properties
Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry
Materials Chemistry
description FCT/MCTES (Portugal), through: grant SFRH/BD/130965/2017 (M.LF.); Investigador FCT 2014 (IF/00190/2014 to A.B.P. and IF/00210/2014 to J.M.M.A.); projects PTDC/EQU-EQU/29737/2017, PTDC/QEQ-FTT/3289/2014 and IF/00210/2014/CP1244/CT0003. Associate Laboratory for Green Chemistry-LAQV, financed by national funds from FCT/MCTES (UID/QUI/50006/2019). projects 2018-LC-01 and 2019-URL-IR1rQ-011, from Obra Social "la Caixa" and by Khalifa University through project RCII-2018-0024.
publishDate 2020
dc.date.none.fl_str_mv 2020-03-15
2020-03-15T00:00:00Z
2022-03-23T01:31:16Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/107732
url http://hdl.handle.net/10362/107732
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0167-7322
PURE: 16874928
https://doi.org/10.1016/j.molliq.2020.112489
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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