Evaluation of Corrosion Behavior of Copper in Chloride Media Using Electrochemical Impedance Spectroscopy (EIS)
Autor(a) principal: | |
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Data de Publicação: | 2005 |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042005000200007 |
Resumo: | The corrosion behavior of pure copper rotating cylinder electrode (RCE) exposed to 3% NaCl or artificial seawater prepared as Vätäänen nine salt solution (VNSS) has been studied using electrochemical impedance spectroscopy (EIS) and polarization techniques. EIS experiments for copper RCE were carried out at different rotation rate from 0 rpm to 1600 rpm. Polarization resistance (Rp) values were obtained from both EIS and polarization experiments. Excellent agreement between impedance and polarization data is observed. RCE experiments demonstrated that Ecorr and corrosion rate for copper depend linearly on rotation speed r0.7. The results obtained showed that EIS is a powerful electrochemical method to follow the change of corrosion mechanisms. |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Evaluation of Corrosion Behavior of Copper in Chloride Media Using Electrochemical Impedance Spectroscopy (EIS)copperrotating cylinder electrodeseawaterimpedanceThe corrosion behavior of pure copper rotating cylinder electrode (RCE) exposed to 3% NaCl or artificial seawater prepared as Vätäänen nine salt solution (VNSS) has been studied using electrochemical impedance spectroscopy (EIS) and polarization techniques. EIS experiments for copper RCE were carried out at different rotation rate from 0 rpm to 1600 rpm. Polarization resistance (Rp) values were obtained from both EIS and polarization experiments. Excellent agreement between impedance and polarization data is observed. RCE experiments demonstrated that Ecorr and corrosion rate for copper depend linearly on rotation speed r0.7. The results obtained showed that EIS is a powerful electrochemical method to follow the change of corrosion mechanisms.Sociedade Portuguesa de Electroquímica2005-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042005000200007Portugaliae Electrochimica Acta v.23 n.2 2005reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAPenghttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042005000200007Nagiub,A.M.info:eu-repo/semantics/openAccess2024-02-06T17:06:46Zoai:scielo:S0872-19042005000200007Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:19:59.324437Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Evaluation of Corrosion Behavior of Copper in Chloride Media Using Electrochemical Impedance Spectroscopy (EIS) |
title |
Evaluation of Corrosion Behavior of Copper in Chloride Media Using Electrochemical Impedance Spectroscopy (EIS) |
spellingShingle |
Evaluation of Corrosion Behavior of Copper in Chloride Media Using Electrochemical Impedance Spectroscopy (EIS) Nagiub,A.M. copper rotating cylinder electrode seawater impedance |
title_short |
Evaluation of Corrosion Behavior of Copper in Chloride Media Using Electrochemical Impedance Spectroscopy (EIS) |
title_full |
Evaluation of Corrosion Behavior of Copper in Chloride Media Using Electrochemical Impedance Spectroscopy (EIS) |
title_fullStr |
Evaluation of Corrosion Behavior of Copper in Chloride Media Using Electrochemical Impedance Spectroscopy (EIS) |
title_full_unstemmed |
Evaluation of Corrosion Behavior of Copper in Chloride Media Using Electrochemical Impedance Spectroscopy (EIS) |
title_sort |
Evaluation of Corrosion Behavior of Copper in Chloride Media Using Electrochemical Impedance Spectroscopy (EIS) |
author |
Nagiub,A.M. |
author_facet |
Nagiub,A.M. |
author_role |
author |
dc.contributor.author.fl_str_mv |
Nagiub,A.M. |
dc.subject.por.fl_str_mv |
copper rotating cylinder electrode seawater impedance |
topic |
copper rotating cylinder electrode seawater impedance |
description |
The corrosion behavior of pure copper rotating cylinder electrode (RCE) exposed to 3% NaCl or artificial seawater prepared as Vätäänen nine salt solution (VNSS) has been studied using electrochemical impedance spectroscopy (EIS) and polarization techniques. EIS experiments for copper RCE were carried out at different rotation rate from 0 rpm to 1600 rpm. Polarization resistance (Rp) values were obtained from both EIS and polarization experiments. Excellent agreement between impedance and polarization data is observed. RCE experiments demonstrated that Ecorr and corrosion rate for copper depend linearly on rotation speed r0.7. The results obtained showed that EIS is a powerful electrochemical method to follow the change of corrosion mechanisms. |
publishDate |
2005 |
dc.date.none.fl_str_mv |
2005-01-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042005000200007 |
url |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042005000200007 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042005000200007 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
dc.source.none.fl_str_mv |
Portugaliae Electrochimica Acta v.23 n.2 2005 reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
|
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1799137289382658048 |