Bacterial cellulose and emulsified AESO biocomposites as an ecological alternative to leather
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/1822/62524 |
Resumo: | This research investigated the development of bio-based composites comprising bacterial cellulose (BC), as obtained by static culture, and acrylated epoxidized soybean oil (AESO) as an alternative to leather. AESO was first emulsified; polyethylene glycol (PEG), polydimethylsiloxane (PDMS) and perfluorocarbon-based polymers were also added to the AESO emulsion, with the mixtures being diffused into the BC 3D nanofibrillar matrix by an exhaustion process. Scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) spectroscopy analysis demonstrated that the tested polymers penetrated well and uniformly into the bulk of the BC matrix. The obtained composites were hydrophobic and thermally stable up to 200 °C. Regarding their mechanical properties, the addition of different polymers lead to a decrease in the tensile strength and an increase in the elongation at break, overall presenting satisfactory performance as a potential alternative to leather. |
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Bacterial cellulose and emulsified AESO biocomposites as an ecological alternative to leatherBacterial celluloseAcrylated epoxidized soybean oilBiocompositeEmulsionExhaustionAlternative leatherEngenharia e Tecnologia::Engenharia dos MateriaisEngenharia e Tecnologia::Biotecnologia IndustrialScience & TechnologyThis research investigated the development of bio-based composites comprising bacterial cellulose (BC), as obtained by static culture, and acrylated epoxidized soybean oil (AESO) as an alternative to leather. AESO was first emulsified; polyethylene glycol (PEG), polydimethylsiloxane (PDMS) and perfluorocarbon-based polymers were also added to the AESO emulsion, with the mixtures being diffused into the BC 3D nanofibrillar matrix by an exhaustion process. Scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) spectroscopy analysis demonstrated that the tested polymers penetrated well and uniformly into the bulk of the BC matrix. The obtained composites were hydrophobic and thermally stable up to 200 °C. Regarding their mechanical properties, the addition of different polymers lead to a decrease in the tensile strength and an increase in the elongation at break, overall presenting satisfactory performance as a potential alternative to leather.FEDER funding on the Programa Operacional Regional do Norte (NORTE2020) within the scope of the project NORTE-01-0247-FEDER-003435 (‘BUILD–Bacterial cellulose Leather’) and Bio-TecNorte operation NORTE-01-0145-FEDER-000004, FEDER funding on the Programa Operacional Factores de Competitividade–COMPETE within the scope of the project POCI-01-0145-FEDER-007136 and POCI-01- 0145-FEDER-006684, national funds through FCT–Foundation for Science and Technology within the scope of the project UID/CTM/00264/2019 and UID/BIO/04469/2013info:eu-repo/semantics/publishedVersionMDPIUniversidade do MinhoFernandes, MartaSouto, António PedroGama, F. M.Dourado, Fernando2019-11-292019-11-29T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/62524engFernandes, Marta; Souto, António Pedro; Gama, F. M.; Dourado, Fernando, Bacterial cellulose and emulsified AESO biocomposites as an ecological alternative to leather. Nanomaterials, 9(12), 1710, 20192079-49912079-499110.3390/nano9121710https://www.mdpi.com/2079-4991/9/12/1710info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:07:12Zoai:repositorium.sdum.uminho.pt:1822/62524Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T18:58:04.857491Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Bacterial cellulose and emulsified AESO biocomposites as an ecological alternative to leather |
title |
Bacterial cellulose and emulsified AESO biocomposites as an ecological alternative to leather |
spellingShingle |
Bacterial cellulose and emulsified AESO biocomposites as an ecological alternative to leather Fernandes, Marta Bacterial cellulose Acrylated epoxidized soybean oil Biocomposite Emulsion Exhaustion Alternative leather Engenharia e Tecnologia::Engenharia dos Materiais Engenharia e Tecnologia::Biotecnologia Industrial Science & Technology |
title_short |
Bacterial cellulose and emulsified AESO biocomposites as an ecological alternative to leather |
title_full |
Bacterial cellulose and emulsified AESO biocomposites as an ecological alternative to leather |
title_fullStr |
Bacterial cellulose and emulsified AESO biocomposites as an ecological alternative to leather |
title_full_unstemmed |
Bacterial cellulose and emulsified AESO biocomposites as an ecological alternative to leather |
title_sort |
Bacterial cellulose and emulsified AESO biocomposites as an ecological alternative to leather |
author |
Fernandes, Marta |
author_facet |
Fernandes, Marta Souto, António Pedro Gama, F. M. Dourado, Fernando |
author_role |
author |
author2 |
Souto, António Pedro Gama, F. M. Dourado, Fernando |
author2_role |
author author author |
dc.contributor.none.fl_str_mv |
Universidade do Minho |
dc.contributor.author.fl_str_mv |
Fernandes, Marta Souto, António Pedro Gama, F. M. Dourado, Fernando |
dc.subject.por.fl_str_mv |
Bacterial cellulose Acrylated epoxidized soybean oil Biocomposite Emulsion Exhaustion Alternative leather Engenharia e Tecnologia::Engenharia dos Materiais Engenharia e Tecnologia::Biotecnologia Industrial Science & Technology |
topic |
Bacterial cellulose Acrylated epoxidized soybean oil Biocomposite Emulsion Exhaustion Alternative leather Engenharia e Tecnologia::Engenharia dos Materiais Engenharia e Tecnologia::Biotecnologia Industrial Science & Technology |
description |
This research investigated the development of bio-based composites comprising bacterial cellulose (BC), as obtained by static culture, and acrylated epoxidized soybean oil (AESO) as an alternative to leather. AESO was first emulsified; polyethylene glycol (PEG), polydimethylsiloxane (PDMS) and perfluorocarbon-based polymers were also added to the AESO emulsion, with the mixtures being diffused into the BC 3D nanofibrillar matrix by an exhaustion process. Scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) spectroscopy analysis demonstrated that the tested polymers penetrated well and uniformly into the bulk of the BC matrix. The obtained composites were hydrophobic and thermally stable up to 200 °C. Regarding their mechanical properties, the addition of different polymers lead to a decrease in the tensile strength and an increase in the elongation at break, overall presenting satisfactory performance as a potential alternative to leather. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019-11-29 2019-11-29T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1822/62524 |
url |
http://hdl.handle.net/1822/62524 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Fernandes, Marta; Souto, António Pedro; Gama, F. M.; Dourado, Fernando, Bacterial cellulose and emulsified AESO biocomposites as an ecological alternative to leather. Nanomaterials, 9(12), 1710, 2019 2079-4991 2079-4991 10.3390/nano9121710 https://www.mdpi.com/2079-4991/9/12/1710 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
MDPI |
publisher.none.fl_str_mv |
MDPI |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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