Bismuth-catalyzed allylic oxidation using t-butyl hydroperoxide

Detalhes bibliográficos
Autor(a) principal: Salvador, Jorge A. R.
Data de Publicação: 2005
Outros Autores: Silvestre, Samuel M.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10316/5755
https://doi.org/10.1016/j.tetlet.2005.02.080
Resumo: Bismuth(III) salts are efficient catalysts for the selective allylic oxidation using tert-butyl hydroperoxide. BiCl3 is especially effective and can be easily recovered and reused as BiOCl. Using BiCl3/K-10 as catalyst, an increase in the reaction rate was observed.
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spelling Bismuth-catalyzed allylic oxidation using t-butyl hydroperoxideAllylic oxidationUnsaturated compoundsBismutht-Butyl hydroperoxideBismuth(III) salts are efficient catalysts for the selective allylic oxidation using tert-butyl hydroperoxide. BiCl3 is especially effective and can be easily recovered and reused as BiOCl. Using BiCl3/K-10 as catalyst, an increase in the reaction rate was observed.http://www.sciencedirect.com/science/article/B6THS-4FM3WXK-3/1/d89629a08a7ed175593fb6938b963a342005info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleaplication/PDFhttp://hdl.handle.net/10316/5755http://hdl.handle.net/10316/5755https://doi.org/10.1016/j.tetlet.2005.02.080engTetrahedron Letters. 46:15 (2005) 2581-2584Salvador, Jorge A. R.Silvestre, Samuel M.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2021-10-28T11:20:41Zoai:estudogeral.uc.pt:10316/5755Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:47:23.778583Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Bismuth-catalyzed allylic oxidation using t-butyl hydroperoxide
title Bismuth-catalyzed allylic oxidation using t-butyl hydroperoxide
spellingShingle Bismuth-catalyzed allylic oxidation using t-butyl hydroperoxide
Salvador, Jorge A. R.
Allylic oxidation
Unsaturated compounds
Bismuth
t-Butyl hydroperoxide
title_short Bismuth-catalyzed allylic oxidation using t-butyl hydroperoxide
title_full Bismuth-catalyzed allylic oxidation using t-butyl hydroperoxide
title_fullStr Bismuth-catalyzed allylic oxidation using t-butyl hydroperoxide
title_full_unstemmed Bismuth-catalyzed allylic oxidation using t-butyl hydroperoxide
title_sort Bismuth-catalyzed allylic oxidation using t-butyl hydroperoxide
author Salvador, Jorge A. R.
author_facet Salvador, Jorge A. R.
Silvestre, Samuel M.
author_role author
author2 Silvestre, Samuel M.
author2_role author
dc.contributor.author.fl_str_mv Salvador, Jorge A. R.
Silvestre, Samuel M.
dc.subject.por.fl_str_mv Allylic oxidation
Unsaturated compounds
Bismuth
t-Butyl hydroperoxide
topic Allylic oxidation
Unsaturated compounds
Bismuth
t-Butyl hydroperoxide
description Bismuth(III) salts are efficient catalysts for the selective allylic oxidation using tert-butyl hydroperoxide. BiCl3 is especially effective and can be easily recovered and reused as BiOCl. Using BiCl3/K-10 as catalyst, an increase in the reaction rate was observed.
publishDate 2005
dc.date.none.fl_str_mv 2005
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10316/5755
http://hdl.handle.net/10316/5755
https://doi.org/10.1016/j.tetlet.2005.02.080
url http://hdl.handle.net/10316/5755
https://doi.org/10.1016/j.tetlet.2005.02.080
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Tetrahedron Letters. 46:15 (2005) 2581-2584
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv aplication/PDF
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
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