Allylic and benzylic oxidation reactions with sodium chlorite

Detalhes bibliográficos
Autor(a) principal: Silvestre, Samuel M.
Data de Publicação: 2007
Outros Autores: Salvador, Jorge A. R.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10316/5861
https://doi.org/10.1016/j.tet.2007.01.012
Resumo: Various allylic and benzylic substrates were selectively oxidized to the corresponding enones in good yields using sodium chlorite, either in combination with tert-butyl hydroperoxide in stoichiometric conditions, or associated with N-hydroxyphthalimide as catalyst. These oxidation reactions were effectively and economically performed under mild, transition-metal free conditions and therefore the dual challenge of cost effectiveness and benign nature of the processes was met with.
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spelling Allylic and benzylic oxidation reactions with sodium chloriteSodium chloriteAllylic oxidationBenzylic oxidationTransition-metal freeVarious allylic and benzylic substrates were selectively oxidized to the corresponding enones in good yields using sodium chlorite, either in combination with tert-butyl hydroperoxide in stoichiometric conditions, or associated with N-hydroxyphthalimide as catalyst. These oxidation reactions were effectively and economically performed under mild, transition-metal free conditions and therefore the dual challenge of cost effectiveness and benign nature of the processes was met with.http://www.sciencedirect.com/science/article/B6THR-4MT5JX3-5/1/64e51e9b1aae448b3f47f8c2efad85af2007info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleaplication/PDFhttp://hdl.handle.net/10316/5861http://hdl.handle.net/10316/5861https://doi.org/10.1016/j.tet.2007.01.012engTetrahedron. 63:11 (2007) 2439-2445Silvestre, Samuel M.Salvador, Jorge A. R.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2021-10-28T11:13:47Zoai:estudogeral.uc.pt:10316/5861Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:47:24.367529Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Allylic and benzylic oxidation reactions with sodium chlorite
title Allylic and benzylic oxidation reactions with sodium chlorite
spellingShingle Allylic and benzylic oxidation reactions with sodium chlorite
Silvestre, Samuel M.
Sodium chlorite
Allylic oxidation
Benzylic oxidation
Transition-metal free
title_short Allylic and benzylic oxidation reactions with sodium chlorite
title_full Allylic and benzylic oxidation reactions with sodium chlorite
title_fullStr Allylic and benzylic oxidation reactions with sodium chlorite
title_full_unstemmed Allylic and benzylic oxidation reactions with sodium chlorite
title_sort Allylic and benzylic oxidation reactions with sodium chlorite
author Silvestre, Samuel M.
author_facet Silvestre, Samuel M.
Salvador, Jorge A. R.
author_role author
author2 Salvador, Jorge A. R.
author2_role author
dc.contributor.author.fl_str_mv Silvestre, Samuel M.
Salvador, Jorge A. R.
dc.subject.por.fl_str_mv Sodium chlorite
Allylic oxidation
Benzylic oxidation
Transition-metal free
topic Sodium chlorite
Allylic oxidation
Benzylic oxidation
Transition-metal free
description Various allylic and benzylic substrates were selectively oxidized to the corresponding enones in good yields using sodium chlorite, either in combination with tert-butyl hydroperoxide in stoichiometric conditions, or associated with N-hydroxyphthalimide as catalyst. These oxidation reactions were effectively and economically performed under mild, transition-metal free conditions and therefore the dual challenge of cost effectiveness and benign nature of the processes was met with.
publishDate 2007
dc.date.none.fl_str_mv 2007
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10316/5861
http://hdl.handle.net/10316/5861
https://doi.org/10.1016/j.tet.2007.01.012
url http://hdl.handle.net/10316/5861
https://doi.org/10.1016/j.tet.2007.01.012
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Tetrahedron. 63:11 (2007) 2439-2445
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv aplication/PDF
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
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