Probing the effect of amino acid-based ionic liquids on the CO2 (sI) and THF (sII) hydrate formation

Detalhes bibliográficos
Autor(a) principal: Soromenho, Mário R. C.
Data de Publicação: 2024
Outros Autores: Keba, Anastasiia, Esperança, José M. S. S., Tariq, Mohammad
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/168995
Resumo: Funding Information: The authors would like to thank Fundação para a Ciência e Tecnologia, FCT/MCTES (Portugal), for financial support through project PTDC/EQU-EQU/32050/2017. This work was partially supported by the Associate Laboratory for Green Chemistry—LAQV, which is financed by national funds from FCT/MCTES (UIDB/50006/2020 and UIDP/50006/2020 and LA/P/0008/2020). Publisher Copyright: © 2023 The Author(s)
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spelling Probing the effect of amino acid-based ionic liquids on the CO2 (sI) and THF (sII) hydrate formationAcetyl glycineCO hydratesIonic liquidsNucleation temperaturePhase behaviourElectronic, Optical and Magnetic MaterialsAtomic and Molecular Physics, and OpticsCondensed Matter PhysicsSpectroscopyPhysical and Theoretical ChemistryMaterials ChemistryFunding Information: The authors would like to thank Fundação para a Ciência e Tecnologia, FCT/MCTES (Portugal), for financial support through project PTDC/EQU-EQU/32050/2017. This work was partially supported by the Associate Laboratory for Green Chemistry—LAQV, which is financed by national funds from FCT/MCTES (UIDB/50006/2020 and UIDP/50006/2020 and LA/P/0008/2020). Publisher Copyright: © 2023 The Author(s)In the present work, four acetyl glycinate-based ionic liquids (ILs) with distinct cations, namely 1-alkyl-3-methylimidazolium acetyl glycinate [C2mim][AcGly], ammonium acetyl glycinate [NH4][AcGly], N-(2-hydroxyethyl)-N,N,N-trimethyl ammonium N-acetylglycinate [N111(2OH)][AcGly] ≈ [Ch][AcGly], and N-Butyl-N,N-dimethyl-N-(2-hydroxyethyl) ammonium N-acetylglycinate [N411(2OH)][AcGly] ≈ [C4Ch][AcGly], were synthesized and tested for their effect on the formation of CO2 hydrates at elevated pressures and tetrahydrofuran (THF) hydrate formation at atmospheric pressure. The phase behaviour of the CO2 hydrates, sI type, was studied in the presence of the selected ILs using the isochoric pressure search method. The ILs shifted the phase boundary towards lower temperatures indicating a thermodynamic inhibition characteristic. The constant cooling method was used to determine the onset nucleation temperature of CO2 hydrates in the presence and absence of additives. The isothermal method was used to determine the induction time of CO2 hydrates in the presence of additives. The pressure drops in both experiments indicate the hydrate growth in the absence/presence of additives. Later, the THF hydrate crystal growth experiments at atmospheric pressure were carried out to understand the effect of additives on the sII-type hydrate growth. The crystal morphology also points out the mode of action of the tested additives on hydrate formation and growth. The extensive testing using the same additives at identical concentrations revealed the importance of the method and conditions, which become crucial in the absence of a standard screening procedure for kinetic hydrate additives.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNSoromenho, Mário R. C.Keba, AnastasiiaEsperança, José M. S. S.Tariq, Mohammad2024-06-24T22:29:42Z2024-01-152024-01-15T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article10application/pdfhttp://hdl.handle.net/10362/168995eng0167-7322PURE: 92109401https://doi.org/10.1016/j.molliq.2023.123744info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-09-09T01:38:45Zoai:run.unl.pt:10362/168995Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-09-09T01:38:45Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Probing the effect of amino acid-based ionic liquids on the CO2 (sI) and THF (sII) hydrate formation
title Probing the effect of amino acid-based ionic liquids on the CO2 (sI) and THF (sII) hydrate formation
spellingShingle Probing the effect of amino acid-based ionic liquids on the CO2 (sI) and THF (sII) hydrate formation
Soromenho, Mário R. C.
Acetyl glycine
CO hydrates
Ionic liquids
Nucleation temperature
Phase behaviour
Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry
Materials Chemistry
title_short Probing the effect of amino acid-based ionic liquids on the CO2 (sI) and THF (sII) hydrate formation
title_full Probing the effect of amino acid-based ionic liquids on the CO2 (sI) and THF (sII) hydrate formation
title_fullStr Probing the effect of amino acid-based ionic liquids on the CO2 (sI) and THF (sII) hydrate formation
title_full_unstemmed Probing the effect of amino acid-based ionic liquids on the CO2 (sI) and THF (sII) hydrate formation
title_sort Probing the effect of amino acid-based ionic liquids on the CO2 (sI) and THF (sII) hydrate formation
author Soromenho, Mário R. C.
author_facet Soromenho, Mário R. C.
Keba, Anastasiia
Esperança, José M. S. S.
Tariq, Mohammad
author_role author
author2 Keba, Anastasiia
Esperança, José M. S. S.
Tariq, Mohammad
author2_role author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Soromenho, Mário R. C.
Keba, Anastasiia
Esperança, José M. S. S.
Tariq, Mohammad
dc.subject.por.fl_str_mv Acetyl glycine
CO hydrates
Ionic liquids
Nucleation temperature
Phase behaviour
Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry
Materials Chemistry
topic Acetyl glycine
CO hydrates
Ionic liquids
Nucleation temperature
Phase behaviour
Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry
Materials Chemistry
description Funding Information: The authors would like to thank Fundação para a Ciência e Tecnologia, FCT/MCTES (Portugal), for financial support through project PTDC/EQU-EQU/32050/2017. This work was partially supported by the Associate Laboratory for Green Chemistry—LAQV, which is financed by national funds from FCT/MCTES (UIDB/50006/2020 and UIDP/50006/2020 and LA/P/0008/2020). Publisher Copyright: © 2023 The Author(s)
publishDate 2024
dc.date.none.fl_str_mv 2024-06-24T22:29:42Z
2024-01-15
2024-01-15T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/168995
url http://hdl.handle.net/10362/168995
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0167-7322
PURE: 92109401
https://doi.org/10.1016/j.molliq.2023.123744
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 10
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
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