The Electrocatalysis of Multi-walled Carbon Nanotubes (MWCNTs) for Oxygen Reduction Reaction (ORR) in Room Temperature Ionic Liquids (RTILs)
Autor(a) principal: | |
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Data de Publicação: | 2009 |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000200009 |
Resumo: | Oxygen reduction reaction (ORR) was investigated on a multi-walled carbon nanotubes (MWCNTs)-modified edge plane pyrolytic graphite (EPPG) electrode using cyclic voltammetry (CV) in three kinds of room temperature ionic liquids (RTILs), i.e., 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIBF4), 1-n-propyl-3-methylimida-zolium tetrafluoroborate (PMIBF4), and 1-n-butyl-3-methylimidazolium tetrafluoro-borate (BMIBF4). The results demonstrated that, after being modified by MWCNTs on the EPPG electrode, both the reduction peak current of oxygen and the oxidation peak current of superoxide anion were all dramatically increased, and the values of standard rate constant, κs, corresponding to ORR, were greatly enhanced. Under the same condition, in PMIBF4, MWCNTs-modified EPPG electrode exhibited the most satisfied electrocatalysis for ORR, in which standard rate constant, κs, was improved from 2.9 × 10-3 cm s-1 on a EPPG electrode, to 10.4 × 10-3 cm s-1. While in EMIBF4 and BMIBF4, after being modified by MWCNTs, the value of κs was increased from 4.3 × 10-3 to 8.3 × 10-3 and 2.3 × 10-3 to 4.2 × 10-3 cm s-1, respectively. For the catalysis of MWCNTs-modified EPPG electrode towards ORR, the enhanced surface area of electrode and the increased amount of defect sites on electrode were thought to be the main reasons for our obtained results. |
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The Electrocatalysis of Multi-walled Carbon Nanotubes (MWCNTs) for Oxygen Reduction Reaction (ORR) in Room Temperature Ionic Liquids (RTILs)multi-walled carbon nanotubes (MWCNTs)room temperature ionic liquids (RTILs)oxygen reduction reaction (ORR)graphite electrodeOxygen reduction reaction (ORR) was investigated on a multi-walled carbon nanotubes (MWCNTs)-modified edge plane pyrolytic graphite (EPPG) electrode using cyclic voltammetry (CV) in three kinds of room temperature ionic liquids (RTILs), i.e., 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIBF4), 1-n-propyl-3-methylimida-zolium tetrafluoroborate (PMIBF4), and 1-n-butyl-3-methylimidazolium tetrafluoro-borate (BMIBF4). The results demonstrated that, after being modified by MWCNTs on the EPPG electrode, both the reduction peak current of oxygen and the oxidation peak current of superoxide anion were all dramatically increased, and the values of standard rate constant, κs, corresponding to ORR, were greatly enhanced. Under the same condition, in PMIBF4, MWCNTs-modified EPPG electrode exhibited the most satisfied electrocatalysis for ORR, in which standard rate constant, κs, was improved from 2.9 × 10-3 cm s-1 on a EPPG electrode, to 10.4 × 10-3 cm s-1. While in EMIBF4 and BMIBF4, after being modified by MWCNTs, the value of κs was increased from 4.3 × 10-3 to 8.3 × 10-3 and 2.3 × 10-3 to 4.2 × 10-3 cm s-1, respectively. For the catalysis of MWCNTs-modified EPPG electrode towards ORR, the enhanced surface area of electrode and the increased amount of defect sites on electrode were thought to be the main reasons for our obtained results.Sociedade Portuguesa de Electroquímica2009-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000200009Portugaliae Electrochimica Acta v.27 n.2 2009reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAPenghttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000200009Ding,Keqianginfo:eu-repo/semantics/openAccess2024-02-06T17:06:58Zoai:scielo:S0872-19042009000200009Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:20:05.748654Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
The Electrocatalysis of Multi-walled Carbon Nanotubes (MWCNTs) for Oxygen Reduction Reaction (ORR) in Room Temperature Ionic Liquids (RTILs) |
title |
The Electrocatalysis of Multi-walled Carbon Nanotubes (MWCNTs) for Oxygen Reduction Reaction (ORR) in Room Temperature Ionic Liquids (RTILs) |
spellingShingle |
The Electrocatalysis of Multi-walled Carbon Nanotubes (MWCNTs) for Oxygen Reduction Reaction (ORR) in Room Temperature Ionic Liquids (RTILs) Ding,Keqiang multi-walled carbon nanotubes (MWCNTs) room temperature ionic liquids (RTILs) oxygen reduction reaction (ORR) graphite electrode |
title_short |
The Electrocatalysis of Multi-walled Carbon Nanotubes (MWCNTs) for Oxygen Reduction Reaction (ORR) in Room Temperature Ionic Liquids (RTILs) |
title_full |
The Electrocatalysis of Multi-walled Carbon Nanotubes (MWCNTs) for Oxygen Reduction Reaction (ORR) in Room Temperature Ionic Liquids (RTILs) |
title_fullStr |
The Electrocatalysis of Multi-walled Carbon Nanotubes (MWCNTs) for Oxygen Reduction Reaction (ORR) in Room Temperature Ionic Liquids (RTILs) |
title_full_unstemmed |
The Electrocatalysis of Multi-walled Carbon Nanotubes (MWCNTs) for Oxygen Reduction Reaction (ORR) in Room Temperature Ionic Liquids (RTILs) |
title_sort |
The Electrocatalysis of Multi-walled Carbon Nanotubes (MWCNTs) for Oxygen Reduction Reaction (ORR) in Room Temperature Ionic Liquids (RTILs) |
author |
Ding,Keqiang |
author_facet |
Ding,Keqiang |
author_role |
author |
dc.contributor.author.fl_str_mv |
Ding,Keqiang |
dc.subject.por.fl_str_mv |
multi-walled carbon nanotubes (MWCNTs) room temperature ionic liquids (RTILs) oxygen reduction reaction (ORR) graphite electrode |
topic |
multi-walled carbon nanotubes (MWCNTs) room temperature ionic liquids (RTILs) oxygen reduction reaction (ORR) graphite electrode |
description |
Oxygen reduction reaction (ORR) was investigated on a multi-walled carbon nanotubes (MWCNTs)-modified edge plane pyrolytic graphite (EPPG) electrode using cyclic voltammetry (CV) in three kinds of room temperature ionic liquids (RTILs), i.e., 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIBF4), 1-n-propyl-3-methylimida-zolium tetrafluoroborate (PMIBF4), and 1-n-butyl-3-methylimidazolium tetrafluoro-borate (BMIBF4). The results demonstrated that, after being modified by MWCNTs on the EPPG electrode, both the reduction peak current of oxygen and the oxidation peak current of superoxide anion were all dramatically increased, and the values of standard rate constant, κs, corresponding to ORR, were greatly enhanced. Under the same condition, in PMIBF4, MWCNTs-modified EPPG electrode exhibited the most satisfied electrocatalysis for ORR, in which standard rate constant, κs, was improved from 2.9 × 10-3 cm s-1 on a EPPG electrode, to 10.4 × 10-3 cm s-1. While in EMIBF4 and BMIBF4, after being modified by MWCNTs, the value of κs was increased from 4.3 × 10-3 to 8.3 × 10-3 and 2.3 × 10-3 to 4.2 × 10-3 cm s-1, respectively. For the catalysis of MWCNTs-modified EPPG electrode towards ORR, the enhanced surface area of electrode and the increased amount of defect sites on electrode were thought to be the main reasons for our obtained results. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-01-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000200009 |
url |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000200009 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000200009 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
dc.source.none.fl_str_mv |
Portugaliae Electrochimica Acta v.27 n.2 2009 reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799137289931063296 |