A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules

Detalhes bibliográficos
Autor(a) principal: Paz, FAA
Data de Publicação: 2004
Outros Autores: Sousa, FL, Soares-Santos, PCR, Cavaleiro, AMV, Nogueira, HIS, Klinowski, J, Trindade, T
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10773/6037
Resumo: The structure of the title compound, tris(hydroxonium) 12- phosphato-tetracosa- 2-oxo-dodecaoxododecatungsten hexakis( benzo-15-crown-5)±methanol±water (1/1/1), (H3O)3- [PW12O40] 6C14H20O5 CH3OH H2O (where C14H20O5 is benzo-15-crown-5), has been determined at 180 K. [PW12O40]3ÿ anions are typical of -Keggin structures, and the [H3O (C14H20O5)2]+ sandwich-type moieties contain a large number of short O O close contacts, suggesting strong hydrogen bonding within them.
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spelling A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 moleculesThe structure of the title compound, tris(hydroxonium) 12- phosphato-tetracosa- 2-oxo-dodecaoxododecatungsten hexakis( benzo-15-crown-5)±methanol±water (1/1/1), (H3O)3- [PW12O40] 6C14H20O5 CH3OH H2O (where C14H20O5 is benzo-15-crown-5), has been determined at 180 K. [PW12O40]3ÿ anions are typical of -Keggin structures, and the [H3O (C14H20O5)2]+ sandwich-type moieties contain a large number of short O O close contacts, suggesting strong hydrogen bonding within them.International Union of Crystallography2012-02-08T15:06:29Z2004-01-01T00:00:00Z2004-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/6037eng1600-5368Paz, FAASousa, FLSoares-Santos, PCRCavaleiro, AMVNogueira, HISKlinowski, JTrindade, Tinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-22T11:06:37Zoai:ria.ua.pt:10773/6037Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:42:58.078888Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
title A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
spellingShingle A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
Paz, FAA
title_short A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
title_full A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
title_fullStr A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
title_full_unstemmed A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
title_sort A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
author Paz, FAA
author_facet Paz, FAA
Sousa, FL
Soares-Santos, PCR
Cavaleiro, AMV
Nogueira, HIS
Klinowski, J
Trindade, T
author_role author
author2 Sousa, FL
Soares-Santos, PCR
Cavaleiro, AMV
Nogueira, HIS
Klinowski, J
Trindade, T
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Paz, FAA
Sousa, FL
Soares-Santos, PCR
Cavaleiro, AMV
Nogueira, HIS
Klinowski, J
Trindade, T
description The structure of the title compound, tris(hydroxonium) 12- phosphato-tetracosa- 2-oxo-dodecaoxododecatungsten hexakis( benzo-15-crown-5)±methanol±water (1/1/1), (H3O)3- [PW12O40] 6C14H20O5 CH3OH H2O (where C14H20O5 is benzo-15-crown-5), has been determined at 180 K. [PW12O40]3ÿ anions are typical of -Keggin structures, and the [H3O (C14H20O5)2]+ sandwich-type moieties contain a large number of short O O close contacts, suggesting strong hydrogen bonding within them.
publishDate 2004
dc.date.none.fl_str_mv 2004-01-01T00:00:00Z
2004-01
2012-02-08T15:06:29Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10773/6037
url http://hdl.handle.net/10773/6037
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1600-5368
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv International Union of Crystallography
publisher.none.fl_str_mv International Union of Crystallography
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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