A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules

Detalhes bibliográficos
Autor(a) principal: Almeida Paz, Filipe A.
Data de Publicação: 2004
Outros Autores: Sousa, Filipa L., Soares-Santos, Paula C. R., Cavaleiro, Ana M. V., Nogueira, Helena I. S., Klinowski, Jacek, Trindade, Tito
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10773/6037
Resumo: The structure of the title compound, tris(hydroxonium) 12- phosphato-tetracosa- 2-oxo-dodecaoxododecatungsten hexakis( benzo-15-crown-5)±methanol±water (1/1/1), (H3O)3- [PW12O40] 6C14H20O5 CH3OH H2O (where C14H20O5 is benzo-15-crown-5), has been determined at 180 K. [PW12O40]3ÿ anions are typical of -Keggin structures, and the [H3O (C14H20O5)2]+ sandwich-type moieties contain a large number of short O O close contacts, suggesting strong hydrogen bonding within them.
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spelling A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 moleculesThe structure of the title compound, tris(hydroxonium) 12- phosphato-tetracosa- 2-oxo-dodecaoxododecatungsten hexakis( benzo-15-crown-5)±methanol±water (1/1/1), (H3O)3- [PW12O40] 6C14H20O5 CH3OH H2O (where C14H20O5 is benzo-15-crown-5), has been determined at 180 K. [PW12O40]3ÿ anions are typical of -Keggin structures, and the [H3O (C14H20O5)2]+ sandwich-type moieties contain a large number of short O O close contacts, suggesting strong hydrogen bonding within them.International Union of Crystallography2012-02-08T15:06:29Z2004-01-01T00:00:00Z2004-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/6037eng1600-536810.1107/S1600536803024310Almeida Paz, Filipe A.Sousa, Filipa L.Soares-Santos, Paula C. R.Cavaleiro, Ana M. V.Nogueira, Helena I. S.Klinowski, JacekTrindade, Titoinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-06T03:35:14Zoai:ria.ua.pt:10773/6037Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-06T03:35:14Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
title A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
spellingShingle A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
Almeida Paz, Filipe A.
title_short A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
title_full A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
title_fullStr A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
title_full_unstemmed A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
title_sort A novel supramolecular organic-inorganic adduct containing alpha-Keggin-type [PW12O40](3-) anions and benzo-15-crown-5 molecules
author Almeida Paz, Filipe A.
author_facet Almeida Paz, Filipe A.
Sousa, Filipa L.
Soares-Santos, Paula C. R.
Cavaleiro, Ana M. V.
Nogueira, Helena I. S.
Klinowski, Jacek
Trindade, Tito
author_role author
author2 Sousa, Filipa L.
Soares-Santos, Paula C. R.
Cavaleiro, Ana M. V.
Nogueira, Helena I. S.
Klinowski, Jacek
Trindade, Tito
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Almeida Paz, Filipe A.
Sousa, Filipa L.
Soares-Santos, Paula C. R.
Cavaleiro, Ana M. V.
Nogueira, Helena I. S.
Klinowski, Jacek
Trindade, Tito
description The structure of the title compound, tris(hydroxonium) 12- phosphato-tetracosa- 2-oxo-dodecaoxododecatungsten hexakis( benzo-15-crown-5)±methanol±water (1/1/1), (H3O)3- [PW12O40] 6C14H20O5 CH3OH H2O (where C14H20O5 is benzo-15-crown-5), has been determined at 180 K. [PW12O40]3ÿ anions are typical of -Keggin structures, and the [H3O (C14H20O5)2]+ sandwich-type moieties contain a large number of short O O close contacts, suggesting strong hydrogen bonding within them.
publishDate 2004
dc.date.none.fl_str_mv 2004-01-01T00:00:00Z
2004-01
2012-02-08T15:06:29Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10773/6037
url http://hdl.handle.net/10773/6037
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1600-5368
10.1107/S1600536803024310
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv International Union of Crystallography
publisher.none.fl_str_mv International Union of Crystallography
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
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