Systematic development of vanadium catalysts for sustainable epoxidation of small alkenes and allylic alcohols

Detalhes bibliográficos
Autor(a) principal: Ferraz-Caetano, José
Data de Publicação: 2023
Outros Autores: Teixeira, Filipe, Cordeiro, Maria Natália Dias Soeiro
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: https://hdl.handle.net/1822/87063
Resumo: The catalytic epoxidation of small alkenes and allylic alcohols includes a wide range of valuable chemical applications, with many works describing vanadium complexes as suitable catalysts towards sustainable process chemistry. But, given the complexity of these mechanisms, it is not always easy to sort out efficient examples for streamlining sustainable processes and tuning product optimization. In this review, we provide an update on major works of tunable vanadium-catalyzed epoxidations, with a focus on sustainable optimization routes. After presenting the current mechanistic view on vanadium catalysts for small alkenes and allylic alcohols’ epoxidation, we argue the key challenges in green process development by highlighting the value of updated kinetic and mechanistic studies, along with essential computational studies.
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spelling Systematic development of vanadium catalysts for sustainable epoxidation of small alkenes and allylic alcoholsAlkene epoxidationAllylic alcohol epoxidationVanadium catalystsSustainable chemistryThe catalytic epoxidation of small alkenes and allylic alcohols includes a wide range of valuable chemical applications, with many works describing vanadium complexes as suitable catalysts towards sustainable process chemistry. But, given the complexity of these mechanisms, it is not always easy to sort out efficient examples for streamlining sustainable processes and tuning product optimization. In this review, we provide an update on major works of tunable vanadium-catalyzed epoxidations, with a focus on sustainable optimization routes. After presenting the current mechanistic view on vanadium catalysts for small alkenes and allylic alcohols’ epoxidation, we argue the key challenges in green process development by highlighting the value of updated kinetic and mechanistic studies, along with essential computational studies.The authors thank the Fundação para a Ciência e Tecnologia (FCT/MCTES) support to LAQV-REQUIMTE (UIDP/50006/2020). José Ferraz-Caetano’s PhD Fellowship is supported by a doctoral Grant (SFRH/BD/151159/2021) financed by the FCT, with funds from the Portuguese State and EU Budget, through the Social European Fund and Programa Por_Centro, under the MIT Portugal Program.Multidisciplinary Digital Publishing Institute (MDPI)Universidade do MinhoFerraz-Caetano, JoséTeixeira, FilipeCordeiro, Maria Natália Dias Soeiro2023-08-012023-08-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/1822/87063engFerraz-Caetano, J.; Teixeira, F.; Cordeiro, M.N.D.S. Systematic Development of Vanadium Catalysts for Sustainable Epoxidation of Small Alkenes and Allylic Alcohols. Int. J. Mol. Sci. 2023, 24, 12299. https://doi.org/10.3390/ijms2415122991661-65961422-006710.3390/ijms2415122993756967312299https://www.mdpi.com/1422-0067/24/15/12299info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-11T06:14:59Zoai:repositorium.sdum.uminho.pt:1822/87063Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-11T06:14:59Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Systematic development of vanadium catalysts for sustainable epoxidation of small alkenes and allylic alcohols
title Systematic development of vanadium catalysts for sustainable epoxidation of small alkenes and allylic alcohols
spellingShingle Systematic development of vanadium catalysts for sustainable epoxidation of small alkenes and allylic alcohols
Ferraz-Caetano, José
Alkene epoxidation
Allylic alcohol epoxidation
Vanadium catalysts
Sustainable chemistry
title_short Systematic development of vanadium catalysts for sustainable epoxidation of small alkenes and allylic alcohols
title_full Systematic development of vanadium catalysts for sustainable epoxidation of small alkenes and allylic alcohols
title_fullStr Systematic development of vanadium catalysts for sustainable epoxidation of small alkenes and allylic alcohols
title_full_unstemmed Systematic development of vanadium catalysts for sustainable epoxidation of small alkenes and allylic alcohols
title_sort Systematic development of vanadium catalysts for sustainable epoxidation of small alkenes and allylic alcohols
author Ferraz-Caetano, José
author_facet Ferraz-Caetano, José
Teixeira, Filipe
Cordeiro, Maria Natália Dias Soeiro
author_role author
author2 Teixeira, Filipe
Cordeiro, Maria Natália Dias Soeiro
author2_role author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Ferraz-Caetano, José
Teixeira, Filipe
Cordeiro, Maria Natália Dias Soeiro
dc.subject.por.fl_str_mv Alkene epoxidation
Allylic alcohol epoxidation
Vanadium catalysts
Sustainable chemistry
topic Alkene epoxidation
Allylic alcohol epoxidation
Vanadium catalysts
Sustainable chemistry
description The catalytic epoxidation of small alkenes and allylic alcohols includes a wide range of valuable chemical applications, with many works describing vanadium complexes as suitable catalysts towards sustainable process chemistry. But, given the complexity of these mechanisms, it is not always easy to sort out efficient examples for streamlining sustainable processes and tuning product optimization. In this review, we provide an update on major works of tunable vanadium-catalyzed epoxidations, with a focus on sustainable optimization routes. After presenting the current mechanistic view on vanadium catalysts for small alkenes and allylic alcohols’ epoxidation, we argue the key challenges in green process development by highlighting the value of updated kinetic and mechanistic studies, along with essential computational studies.
publishDate 2023
dc.date.none.fl_str_mv 2023-08-01
2023-08-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://hdl.handle.net/1822/87063
url https://hdl.handle.net/1822/87063
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Ferraz-Caetano, J.; Teixeira, F.; Cordeiro, M.N.D.S. Systematic Development of Vanadium Catalysts for Sustainable Epoxidation of Small Alkenes and Allylic Alcohols. Int. J. Mol. Sci. 2023, 24, 12299. https://doi.org/10.3390/ijms241512299
1661-6596
1422-0067
10.3390/ijms241512299
37569673
12299
https://www.mdpi.com/1422-0067/24/15/12299
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute (MDPI)
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute (MDPI)
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
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