Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide

Detalhes bibliográficos
Autor(a) principal: Inês, Massuquinini
Data de Publicação: 2009
Outros Autores: Mendonça, António, Esteves, Ana P., Mendonça, Dina, Medeiros, Maria J.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.6/12312
Resumo: Electroepoxidation of synthetic alkenes (styrene, trans-stilbene and trans-b-methylstyrene) and of some natural terpenes (limonene, terpinolene, geraniol, a-terpinene, g-terpinene and a-terpineol) mediated by sodium bromide was performed in MeCN:H2O (4:1) at platinum electrodes. The indirect electrochemical oxidation of the olefins led to the corresponding epoxides in yields ranging from 23% to 79%.
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spelling Electroepoxidation of natural and synthetic alkenes mediated by sodium bromideElectrochemical epoxidationSodium bromideAlkenesTerpenesElectroepoxidation of synthetic alkenes (styrene, trans-stilbene and trans-b-methylstyrene) and of some natural terpenes (limonene, terpinolene, geraniol, a-terpinene, g-terpinene and a-terpineol) mediated by sodium bromide was performed in MeCN:H2O (4:1) at platinum electrodes. The indirect electrochemical oxidation of the olefins led to the corresponding epoxides in yields ranging from 23% to 79%.Elsevier Masson SASuBibliorumInês, MassuquininiMendonça, AntónioEsteves, Ana P.Mendonça, DinaMedeiros, Maria J.2022-08-24T10:14:57Z2009-01-082009-01-08T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.6/12312engInês, M., Mendonça, A. J., Esteves, A. P., Mendonça, D. I., & Medeiros, M. J. (2009). Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide. Comptes Rendus Chimie, 12(8), 841-849. doi:10.1016/j.crci.2008.10.01410.1016/j.crci.2008.10.014metadata only accessinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-12-15T09:55:26Zoai:ubibliorum.ubi.pt:10400.6/12312Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T00:51:57.013419Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
title Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
spellingShingle Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
Inês, Massuquinini
Electrochemical epoxidation
Sodium bromide
Alkenes
Terpenes
title_short Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
title_full Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
title_fullStr Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
title_full_unstemmed Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
title_sort Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide
author Inês, Massuquinini
author_facet Inês, Massuquinini
Mendonça, António
Esteves, Ana P.
Mendonça, Dina
Medeiros, Maria J.
author_role author
author2 Mendonça, António
Esteves, Ana P.
Mendonça, Dina
Medeiros, Maria J.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv uBibliorum
dc.contributor.author.fl_str_mv Inês, Massuquinini
Mendonça, António
Esteves, Ana P.
Mendonça, Dina
Medeiros, Maria J.
dc.subject.por.fl_str_mv Electrochemical epoxidation
Sodium bromide
Alkenes
Terpenes
topic Electrochemical epoxidation
Sodium bromide
Alkenes
Terpenes
description Electroepoxidation of synthetic alkenes (styrene, trans-stilbene and trans-b-methylstyrene) and of some natural terpenes (limonene, terpinolene, geraniol, a-terpinene, g-terpinene and a-terpineol) mediated by sodium bromide was performed in MeCN:H2O (4:1) at platinum electrodes. The indirect electrochemical oxidation of the olefins led to the corresponding epoxides in yields ranging from 23% to 79%.
publishDate 2009
dc.date.none.fl_str_mv 2009-01-08
2009-01-08T00:00:00Z
2022-08-24T10:14:57Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.6/12312
url http://hdl.handle.net/10400.6/12312
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Inês, M., Mendonça, A. J., Esteves, A. P., Mendonça, D. I., & Medeiros, M. J. (2009). Electroepoxidation of natural and synthetic alkenes mediated by sodium bromide. Comptes Rendus Chimie, 12(8), 841-849. doi:10.1016/j.crci.2008.10.014
10.1016/j.crci.2008.10.014
dc.rights.driver.fl_str_mv metadata only access
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rights_invalid_str_mv metadata only access
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dc.publisher.none.fl_str_mv Elsevier Masson SAS
publisher.none.fl_str_mv Elsevier Masson SAS
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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