Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity

Detalhes bibliográficos
Autor(a) principal: Almeida, Teresa Marques
Data de Publicação: 2022
Outros Autores: Fernandes, Liliana C., Correia, Daniela M., Tubio, Carmen R., Lanceros-Méndez, S., Ribeiro, Clarisse Marta Oliveira
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: https://hdl.handle.net/1822/82088
Resumo: Piezoelectric polymers allow transducing a mechanical stimulus into an electrical voltage, and vice-versa, leading to a large variety of sensor and actuator applications. Further, biodegradable platforms are increasingly needed in the environmental and biotechnological areas. In this context, this work reports on electrospun fiber based membranes with tailored physical properties and morphology, through the combination of the piezoelectric and biodegradable poly(3- hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) polymer with poly(ethylene oxide) (PEO). The use of a binary polymer mixture and a binary solvent system of chloroform and dimethylformamide allows these materials to have their external and internal morphologies tailored. The porosity of the neat and blend fibers ranges between 79 and 93%. The produced materials demonstrated huge potential for environmental and biotechnological applications that require piezoelectricity, biodegradability and porosity.
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spelling Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosityPoly(3-hydroxybutyrate-co-3-hydroxyvalerate);Porous fibersElectrospinning, biotechnological applications.biotechnological applicationselectrospinningScience & TechnologyPiezoelectric polymers allow transducing a mechanical stimulus into an electrical voltage, and vice-versa, leading to a large variety of sensor and actuator applications. Further, biodegradable platforms are increasingly needed in the environmental and biotechnological areas. In this context, this work reports on electrospun fiber based membranes with tailored physical properties and morphology, through the combination of the piezoelectric and biodegradable poly(3- hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) polymer with poly(ethylene oxide) (PEO). The use of a binary polymer mixture and a binary solvent system of chloroform and dimethylformamide allows these materials to have their external and internal morphologies tailored. The porosity of the neat and blend fibers ranges between 79 and 93%. The produced materials demonstrated huge potential for environmental and biotechnological applications that require piezoelectricity, biodegradability and porosity.This work was supported by national funds through the Fundação para a Ciência e Tecnologia (FCT) and by ERDF through COMPETE2020 - Programa Operacional Competitividade e Internacionalização (POCI) in the framework of the Strategic Programs UID/FIS/04650/2020 and project PTDC/BTM-MAT/28237/2017. The authors thank FCT for the research grant: SFRH/BD/141136/2018 (TMA), SFRH/BD /145345/2019 (LCF), and SFRH/BPD/121526/2016 (DMC), and CR thanks the FCT for the contract under the Stimulus of Scientific Employment, Individual Support (CEECIND) – 3rd Edition (2020.04163.CEECIND). Finally, the authors acknowledge funding by Spanish State Research Agency (AEI) and the European Regional Development Fund (ERFD) through the project PID2019-106099RB C43/AEI/10.13039/501100011033 and from the Basque Government Industry Departments under the ELKARTEK program.WileyUniversidade do MinhoAlmeida, Teresa MarquesFernandes, Liliana C.Correia, Daniela M.Tubio, Carmen R.Lanceros-Méndez, S.Ribeiro, Clarisse Marta Oliveira20222025-01-01T00:00:00Z2022-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/1822/82088eng1099-158110.1002/pat.5582https://doi.org/10.1002/pat.5582info:eu-repo/semantics/embargoedAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:02:35Zoai:repositorium.sdum.uminho.pt:1822/82088Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T18:52:35.340409Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity
title Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity
spellingShingle Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity
Almeida, Teresa Marques
Poly(3-hydroxybutyrate-co-3-hydroxyvalerate);
Porous fibers
Electrospinning, biotechnological applications.
biotechnological applications
electrospinning
Science & Technology
title_short Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity
title_full Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity
title_fullStr Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity
title_full_unstemmed Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity
title_sort Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity
author Almeida, Teresa Marques
author_facet Almeida, Teresa Marques
Fernandes, Liliana C.
Correia, Daniela M.
Tubio, Carmen R.
Lanceros-Méndez, S.
Ribeiro, Clarisse Marta Oliveira
author_role author
author2 Fernandes, Liliana C.
Correia, Daniela M.
Tubio, Carmen R.
Lanceros-Méndez, S.
Ribeiro, Clarisse Marta Oliveira
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Almeida, Teresa Marques
Fernandes, Liliana C.
Correia, Daniela M.
Tubio, Carmen R.
Lanceros-Méndez, S.
Ribeiro, Clarisse Marta Oliveira
dc.subject.por.fl_str_mv Poly(3-hydroxybutyrate-co-3-hydroxyvalerate);
Porous fibers
Electrospinning, biotechnological applications.
biotechnological applications
electrospinning
Science & Technology
topic Poly(3-hydroxybutyrate-co-3-hydroxyvalerate);
Porous fibers
Electrospinning, biotechnological applications.
biotechnological applications
electrospinning
Science & Technology
description Piezoelectric polymers allow transducing a mechanical stimulus into an electrical voltage, and vice-versa, leading to a large variety of sensor and actuator applications. Further, biodegradable platforms are increasingly needed in the environmental and biotechnological areas. In this context, this work reports on electrospun fiber based membranes with tailored physical properties and morphology, through the combination of the piezoelectric and biodegradable poly(3- hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) polymer with poly(ethylene oxide) (PEO). The use of a binary polymer mixture and a binary solvent system of chloroform and dimethylformamide allows these materials to have their external and internal morphologies tailored. The porosity of the neat and blend fibers ranges between 79 and 93%. The produced materials demonstrated huge potential for environmental and biotechnological applications that require piezoelectricity, biodegradability and porosity.
publishDate 2022
dc.date.none.fl_str_mv 2022
2022-01-01T00:00:00Z
2025-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://hdl.handle.net/1822/82088
url https://hdl.handle.net/1822/82088
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1099-1581
10.1002/pat.5582
https://doi.org/10.1002/pat.5582
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eu_rights_str_mv embargoedAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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