Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity
Autor(a) principal: | |
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Data de Publicação: | 2022 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | https://hdl.handle.net/1822/82088 |
Resumo: | Piezoelectric polymers allow transducing a mechanical stimulus into an electrical voltage, and vice-versa, leading to a large variety of sensor and actuator applications. Further, biodegradable platforms are increasingly needed in the environmental and biotechnological areas. In this context, this work reports on electrospun fiber based membranes with tailored physical properties and morphology, through the combination of the piezoelectric and biodegradable poly(3- hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) polymer with poly(ethylene oxide) (PEO). The use of a binary polymer mixture and a binary solvent system of chloroform and dimethylformamide allows these materials to have their external and internal morphologies tailored. The porosity of the neat and blend fibers ranges between 79 and 93%. The produced materials demonstrated huge potential for environmental and biotechnological applications that require piezoelectricity, biodegradability and porosity. |
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Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosityPoly(3-hydroxybutyrate-co-3-hydroxyvalerate);Porous fibersElectrospinning, biotechnological applications.biotechnological applicationselectrospinningScience & TechnologyPiezoelectric polymers allow transducing a mechanical stimulus into an electrical voltage, and vice-versa, leading to a large variety of sensor and actuator applications. Further, biodegradable platforms are increasingly needed in the environmental and biotechnological areas. In this context, this work reports on electrospun fiber based membranes with tailored physical properties and morphology, through the combination of the piezoelectric and biodegradable poly(3- hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) polymer with poly(ethylene oxide) (PEO). The use of a binary polymer mixture and a binary solvent system of chloroform and dimethylformamide allows these materials to have their external and internal morphologies tailored. The porosity of the neat and blend fibers ranges between 79 and 93%. The produced materials demonstrated huge potential for environmental and biotechnological applications that require piezoelectricity, biodegradability and porosity.This work was supported by national funds through the Fundação para a Ciência e Tecnologia (FCT) and by ERDF through COMPETE2020 - Programa Operacional Competitividade e Internacionalização (POCI) in the framework of the Strategic Programs UID/FIS/04650/2020 and project PTDC/BTM-MAT/28237/2017. The authors thank FCT for the research grant: SFRH/BD/141136/2018 (TMA), SFRH/BD /145345/2019 (LCF), and SFRH/BPD/121526/2016 (DMC), and CR thanks the FCT for the contract under the Stimulus of Scientific Employment, Individual Support (CEECIND) – 3rd Edition (2020.04163.CEECIND). Finally, the authors acknowledge funding by Spanish State Research Agency (AEI) and the European Regional Development Fund (ERFD) through the project PID2019-106099RB C43/AEI/10.13039/501100011033 and from the Basque Government Industry Departments under the ELKARTEK program.WileyUniversidade do MinhoAlmeida, Teresa MarquesFernandes, Liliana C.Correia, Daniela M.Tubio, Carmen R.Lanceros-Méndez, S.Ribeiro, Clarisse Marta Oliveira20222025-01-01T00:00:00Z2022-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/1822/82088eng1099-158110.1002/pat.5582https://doi.org/10.1002/pat.5582info:eu-repo/semantics/embargoedAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:02:35Zoai:repositorium.sdum.uminho.pt:1822/82088Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T18:52:35.340409Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity |
title |
Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity |
spellingShingle |
Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity Almeida, Teresa Marques Poly(3-hydroxybutyrate-co-3-hydroxyvalerate); Porous fibers Electrospinning, biotechnological applications. biotechnological applications electrospinning Science & Technology |
title_short |
Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity |
title_full |
Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity |
title_fullStr |
Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity |
title_full_unstemmed |
Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity |
title_sort |
Piezoelectric biodegradable poly(3-hydroxybutyrate-co-3-hydroxyvalerate) based electrospun fiber mats with tailored porosity |
author |
Almeida, Teresa Marques |
author_facet |
Almeida, Teresa Marques Fernandes, Liliana C. Correia, Daniela M. Tubio, Carmen R. Lanceros-Méndez, S. Ribeiro, Clarisse Marta Oliveira |
author_role |
author |
author2 |
Fernandes, Liliana C. Correia, Daniela M. Tubio, Carmen R. Lanceros-Méndez, S. Ribeiro, Clarisse Marta Oliveira |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Universidade do Minho |
dc.contributor.author.fl_str_mv |
Almeida, Teresa Marques Fernandes, Liliana C. Correia, Daniela M. Tubio, Carmen R. Lanceros-Méndez, S. Ribeiro, Clarisse Marta Oliveira |
dc.subject.por.fl_str_mv |
Poly(3-hydroxybutyrate-co-3-hydroxyvalerate); Porous fibers Electrospinning, biotechnological applications. biotechnological applications electrospinning Science & Technology |
topic |
Poly(3-hydroxybutyrate-co-3-hydroxyvalerate); Porous fibers Electrospinning, biotechnological applications. biotechnological applications electrospinning Science & Technology |
description |
Piezoelectric polymers allow transducing a mechanical stimulus into an electrical voltage, and vice-versa, leading to a large variety of sensor and actuator applications. Further, biodegradable platforms are increasingly needed in the environmental and biotechnological areas. In this context, this work reports on electrospun fiber based membranes with tailored physical properties and morphology, through the combination of the piezoelectric and biodegradable poly(3- hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) polymer with poly(ethylene oxide) (PEO). The use of a binary polymer mixture and a binary solvent system of chloroform and dimethylformamide allows these materials to have their external and internal morphologies tailored. The porosity of the neat and blend fibers ranges between 79 and 93%. The produced materials demonstrated huge potential for environmental and biotechnological applications that require piezoelectricity, biodegradability and porosity. |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022 2022-01-01T00:00:00Z 2025-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://hdl.handle.net/1822/82088 |
url |
https://hdl.handle.net/1822/82088 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
1099-1581 10.1002/pat.5582 https://doi.org/10.1002/pat.5582 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/embargoedAccess |
eu_rights_str_mv |
embargoedAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Wiley |
publisher.none.fl_str_mv |
Wiley |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799132302253490177 |