Characterization of Active Sites on Carbon Catalysts

Detalhes bibliográficos
Autor(a) principal: Figueiredo, José L.
Data de Publicação: 2007
Outros Autores: Pereira, Manuel F. R., Freitas, Maria M. A., Órfão, José J. M.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.22/10057
Resumo: A method based on the deconvolution of TPD spectra is proposed for the characterization of surface oxygen groups, which can act as the active sites on carbon catalysts. The method, which was previously used to characterize activated carbons oxidized in the gas phase, has been extended and applied to other materials, carbons oxidized in the liquid phase. It is shown that this method fits quite well the TPD experimental data of the original activated carbon as well as the gas-phase and liquid-phase oxidized materials and is suitable to estimate the amounts of each type of oxygen surface groups.
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spelling Characterization of Active Sites on Carbon CatalystsA method based on the deconvolution of TPD spectra is proposed for the characterization of surface oxygen groups, which can act as the active sites on carbon catalysts. The method, which was previously used to characterize activated carbons oxidized in the gas phase, has been extended and applied to other materials, carbons oxidized in the liquid phase. It is shown that this method fits quite well the TPD experimental data of the original activated carbon as well as the gas-phase and liquid-phase oxidized materials and is suitable to estimate the amounts of each type of oxygen surface groups.ACS PublicationsRepositório Científico do Instituto Politécnico do PortoFigueiredo, José L.Pereira, Manuel F. R.Freitas, Maria M. A.Órfão, José J. M.2017-07-13T13:49:11Z20072007-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.22/10057eng10.1021/ie061071vinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-03-13T12:51:29Zoai:recipp.ipp.pt:10400.22/10057Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T17:30:28.190284Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Characterization of Active Sites on Carbon Catalysts
title Characterization of Active Sites on Carbon Catalysts
spellingShingle Characterization of Active Sites on Carbon Catalysts
Figueiredo, José L.
title_short Characterization of Active Sites on Carbon Catalysts
title_full Characterization of Active Sites on Carbon Catalysts
title_fullStr Characterization of Active Sites on Carbon Catalysts
title_full_unstemmed Characterization of Active Sites on Carbon Catalysts
title_sort Characterization of Active Sites on Carbon Catalysts
author Figueiredo, José L.
author_facet Figueiredo, José L.
Pereira, Manuel F. R.
Freitas, Maria M. A.
Órfão, José J. M.
author_role author
author2 Pereira, Manuel F. R.
Freitas, Maria M. A.
Órfão, José J. M.
author2_role author
author
author
dc.contributor.none.fl_str_mv Repositório Científico do Instituto Politécnico do Porto
dc.contributor.author.fl_str_mv Figueiredo, José L.
Pereira, Manuel F. R.
Freitas, Maria M. A.
Órfão, José J. M.
description A method based on the deconvolution of TPD spectra is proposed for the characterization of surface oxygen groups, which can act as the active sites on carbon catalysts. The method, which was previously used to characterize activated carbons oxidized in the gas phase, has been extended and applied to other materials, carbons oxidized in the liquid phase. It is shown that this method fits quite well the TPD experimental data of the original activated carbon as well as the gas-phase and liquid-phase oxidized materials and is suitable to estimate the amounts of each type of oxygen surface groups.
publishDate 2007
dc.date.none.fl_str_mv 2007
2007-01-01T00:00:00Z
2017-07-13T13:49:11Z
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dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.22/10057
url http://hdl.handle.net/10400.22/10057
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1021/ie061071v
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dc.publisher.none.fl_str_mv ACS Publications
publisher.none.fl_str_mv ACS Publications
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
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