Characterization of Active Sites on Carbon Catalysts
Autor(a) principal: | |
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Data de Publicação: | 2007 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10400.22/10057 |
Resumo: | A method based on the deconvolution of TPD spectra is proposed for the characterization of surface oxygen groups, which can act as the active sites on carbon catalysts. The method, which was previously used to characterize activated carbons oxidized in the gas phase, has been extended and applied to other materials, carbons oxidized in the liquid phase. It is shown that this method fits quite well the TPD experimental data of the original activated carbon as well as the gas-phase and liquid-phase oxidized materials and is suitable to estimate the amounts of each type of oxygen surface groups. |
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Characterization of Active Sites on Carbon CatalystsA method based on the deconvolution of TPD spectra is proposed for the characterization of surface oxygen groups, which can act as the active sites on carbon catalysts. The method, which was previously used to characterize activated carbons oxidized in the gas phase, has been extended and applied to other materials, carbons oxidized in the liquid phase. It is shown that this method fits quite well the TPD experimental data of the original activated carbon as well as the gas-phase and liquid-phase oxidized materials and is suitable to estimate the amounts of each type of oxygen surface groups.ACS PublicationsRepositório Científico do Instituto Politécnico do PortoFigueiredo, José L.Pereira, Manuel F. R.Freitas, Maria M. A.Órfão, José J. M.2017-07-13T13:49:11Z20072007-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.22/10057eng10.1021/ie061071vinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-03-13T12:51:29Zoai:recipp.ipp.pt:10400.22/10057Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T17:30:28.190284Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Characterization of Active Sites on Carbon Catalysts |
title |
Characterization of Active Sites on Carbon Catalysts |
spellingShingle |
Characterization of Active Sites on Carbon Catalysts Figueiredo, José L. |
title_short |
Characterization of Active Sites on Carbon Catalysts |
title_full |
Characterization of Active Sites on Carbon Catalysts |
title_fullStr |
Characterization of Active Sites on Carbon Catalysts |
title_full_unstemmed |
Characterization of Active Sites on Carbon Catalysts |
title_sort |
Characterization of Active Sites on Carbon Catalysts |
author |
Figueiredo, José L. |
author_facet |
Figueiredo, José L. Pereira, Manuel F. R. Freitas, Maria M. A. Órfão, José J. M. |
author_role |
author |
author2 |
Pereira, Manuel F. R. Freitas, Maria M. A. Órfão, José J. M. |
author2_role |
author author author |
dc.contributor.none.fl_str_mv |
Repositório Científico do Instituto Politécnico do Porto |
dc.contributor.author.fl_str_mv |
Figueiredo, José L. Pereira, Manuel F. R. Freitas, Maria M. A. Órfão, José J. M. |
description |
A method based on the deconvolution of TPD spectra is proposed for the characterization of surface oxygen groups, which can act as the active sites on carbon catalysts. The method, which was previously used to characterize activated carbons oxidized in the gas phase, has been extended and applied to other materials, carbons oxidized in the liquid phase. It is shown that this method fits quite well the TPD experimental data of the original activated carbon as well as the gas-phase and liquid-phase oxidized materials and is suitable to estimate the amounts of each type of oxygen surface groups. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007 2007-01-01T00:00:00Z 2017-07-13T13:49:11Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10400.22/10057 |
url |
http://hdl.handle.net/10400.22/10057 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1021/ie061071v |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
ACS Publications |
publisher.none.fl_str_mv |
ACS Publications |
dc.source.none.fl_str_mv |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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