Hydrophobic DES Based on Menthol and Natural Organic Acids for Use in Antifouling Marine Coatings
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2023 |
| Outros Autores: | , , , , , , |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
| Texto Completo: | http://hdl.handle.net/10362/159302 |
Resumo: | Publisher Copyright: © 2023 The Authors. Published by American Chemical Society. |
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Hydrophobic DES Based on Menthol and Natural Organic Acids for Use in Antifouling Marine Coatingsantibiofilmantifoulingbiocide-freecoatings and paintseco-friendlyhydrophobic deep eutectic systems (HDES)marine fouling controlnatural productsnon-toxicChemistry(all)Environmental ChemistryChemical Engineering(all)Renewable Energy, Sustainability and the EnvironmentSDG 9 - Industry, Innovation, and InfrastructureSDG 14 - Life Below WaterSDG 7 - Affordable and Clean EnergySDG 13 - Climate ActionPublisher Copyright: © 2023 The Authors. Published by American Chemical Society.Marine biofouling negatively impacts industries with off-shore infrastructures, such as naval, oil, and aquaculture. To date, there are no ideal sustainable, economic, and environmentally benign solutions to deal with this phenomenon. The advances achieved in green solvents, as well as its application in different industries, such as pharmaceutical and biotechnology, have promoted the emergence of deep eutectic systems (DES). These eutectic systems have applications in various fields and can be revolutionary in the marine-based industrial sector. In this study, the main objective was to investigate the potential use of hydrophobic DES (HDES) based on menthol and natural organic acids for their use as marine antifouling coatings. Our strategy encompassed the physicochemical characterization of different formulations, which allowed us to identify the most appropriate molar ratio and intermolecular interactions for HDES formations. The miscibility of the resulting HDES with the marine coating has been evaluated and proven to be successful. The Men/OL (1:1) system proved to be the most promising in terms of cost-production and thus was the one used in subsequent antifouling tests. The cytotoxicity of this HDES was evaluated using an in vitro cell model (HaCat cells) showing no significant toxicity. Furthermore, the application of this system incorporated into coatings that are used in marine structures was also studied using marine species (Mytilus edulis mussels and Patella vulgata limpets) to evaluate both their antifouling and ecotoxicity effects. HDES Men/OL (1:1) incorporated in marine coatings was promising in reducing marine macrofouling and also proved to be effective at the level of microfouling without viability impairment of the tested marine species. It was revealed to be more efficient than using copper oxide, metallic copper, or ivermectin as antifouling agents. Biochemical assays performed on marine species showed that this HDES does not induce oxidative stress in the tested species. These results are a strong indication of the potential of this HDES to be sustainable and efficiently used in marine fouling control technologies.LAQV@REQUIMTEUCIBIO - Applied Molecular Biosciences UnitDQ - Departamento de QuímicaDCV - Departamento de Ciências da VidaRUNValente, SaraOliveira, FilipeFerreira, Inês JoãoPaiva, AlexandreSobral, Rita G.Diniz, Mário S.Gaudêncio, Susana P.Duarte, Ana Rita Cruz2023-10-26T22:19:35Z2023-07-102023-07-10T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article12application/pdfhttp://hdl.handle.net/10362/159302eng2168-0485PURE: 74737131https://doi.org/10.1021/acssuschemeng.3c01120info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:41:44Zoai:run.unl.pt:10362/159302Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:57:28.643706Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
| dc.title.none.fl_str_mv |
Hydrophobic DES Based on Menthol and Natural Organic Acids for Use in Antifouling Marine Coatings |
| title |
Hydrophobic DES Based on Menthol and Natural Organic Acids for Use in Antifouling Marine Coatings |
| spellingShingle |
Hydrophobic DES Based on Menthol and Natural Organic Acids for Use in Antifouling Marine Coatings Valente, Sara antibiofilm antifouling biocide-free coatings and paints eco-friendly hydrophobic deep eutectic systems (HDES) marine fouling control natural products non-toxic Chemistry(all) Environmental Chemistry Chemical Engineering(all) Renewable Energy, Sustainability and the Environment SDG 9 - Industry, Innovation, and Infrastructure SDG 14 - Life Below Water SDG 7 - Affordable and Clean Energy SDG 13 - Climate Action |
| title_short |
Hydrophobic DES Based on Menthol and Natural Organic Acids for Use in Antifouling Marine Coatings |
| title_full |
Hydrophobic DES Based on Menthol and Natural Organic Acids for Use in Antifouling Marine Coatings |
| title_fullStr |
Hydrophobic DES Based on Menthol and Natural Organic Acids for Use in Antifouling Marine Coatings |
| title_full_unstemmed |
Hydrophobic DES Based on Menthol and Natural Organic Acids for Use in Antifouling Marine Coatings |
| title_sort |
Hydrophobic DES Based on Menthol and Natural Organic Acids for Use in Antifouling Marine Coatings |
| author |
Valente, Sara |
| author_facet |
Valente, Sara Oliveira, Filipe Ferreira, Inês João Paiva, Alexandre Sobral, Rita G. Diniz, Mário S. Gaudêncio, Susana P. Duarte, Ana Rita Cruz |
| author_role |
author |
| author2 |
Oliveira, Filipe Ferreira, Inês João Paiva, Alexandre Sobral, Rita G. Diniz, Mário S. Gaudêncio, Susana P. Duarte, Ana Rita Cruz |
| author2_role |
author author author author author author author |
| dc.contributor.none.fl_str_mv |
LAQV@REQUIMTE UCIBIO - Applied Molecular Biosciences Unit DQ - Departamento de Química DCV - Departamento de Ciências da Vida RUN |
| dc.contributor.author.fl_str_mv |
Valente, Sara Oliveira, Filipe Ferreira, Inês João Paiva, Alexandre Sobral, Rita G. Diniz, Mário S. Gaudêncio, Susana P. Duarte, Ana Rita Cruz |
| dc.subject.por.fl_str_mv |
antibiofilm antifouling biocide-free coatings and paints eco-friendly hydrophobic deep eutectic systems (HDES) marine fouling control natural products non-toxic Chemistry(all) Environmental Chemistry Chemical Engineering(all) Renewable Energy, Sustainability and the Environment SDG 9 - Industry, Innovation, and Infrastructure SDG 14 - Life Below Water SDG 7 - Affordable and Clean Energy SDG 13 - Climate Action |
| topic |
antibiofilm antifouling biocide-free coatings and paints eco-friendly hydrophobic deep eutectic systems (HDES) marine fouling control natural products non-toxic Chemistry(all) Environmental Chemistry Chemical Engineering(all) Renewable Energy, Sustainability and the Environment SDG 9 - Industry, Innovation, and Infrastructure SDG 14 - Life Below Water SDG 7 - Affordable and Clean Energy SDG 13 - Climate Action |
| description |
Publisher Copyright: © 2023 The Authors. Published by American Chemical Society. |
| publishDate |
2023 |
| dc.date.none.fl_str_mv |
2023-10-26T22:19:35Z 2023-07-10 2023-07-10T00:00:00Z |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/159302 |
| url |
http://hdl.handle.net/10362/159302 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
2168-0485 PURE: 74737131 https://doi.org/10.1021/acssuschemeng.3c01120 |
| dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
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openAccess |
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12 application/pdf |
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reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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