Numerical Modeling on Non-enzymatic, Potentiometric Glucose Sensor
Autor(a) principal: | |
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Data de Publicação: | 2012 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042012000400006 |
Resumo: | A novel, enzymeless electrochemical sensing mechanism for glucose based on potentiometric measurement was proposed using the mediator hexacyanoferrate. In this methodology, EMF of the cell exclusively depends on glucose concentration and independent on reference half-cell electrode potential or mediator concentration or any other interfering factors. Electrochemical as well as mathematical models were proposed. Numerical computations along with boundary conditions were evaluated for the proposed models, to reduce the deviation in the interpolated results. Molar ratio of mediator to glucose was correlated with EMF cell. Numerical simulations, Legendre polynomials and Lagrange coefficients iterations can be executed through computer programs. |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Numerical Modeling on Non-enzymatic, Potentiometric Glucose Sensorpotentiometric glucose sensorsmathematical modelingnon-enzymatic glucose sensorsA novel, enzymeless electrochemical sensing mechanism for glucose based on potentiometric measurement was proposed using the mediator hexacyanoferrate. In this methodology, EMF of the cell exclusively depends on glucose concentration and independent on reference half-cell electrode potential or mediator concentration or any other interfering factors. Electrochemical as well as mathematical models were proposed. Numerical computations along with boundary conditions were evaluated for the proposed models, to reduce the deviation in the interpolated results. Molar ratio of mediator to glucose was correlated with EMF cell. Numerical simulations, Legendre polynomials and Lagrange coefficients iterations can be executed through computer programs.Sociedade Portuguesa de Electroquímica2012-07-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042012000400006Portugaliae Electrochimica Acta v.30 n.4 2012reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAPenghttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042012000400006Kanagasabapathy,M.Ramesh Bapu,G.N.K.Lingac,PraveenGnanamuthud,R.M.info:eu-repo/semantics/openAccess2024-02-06T17:07:11Zoai:scielo:S0872-19042012000400006Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:20:12.811894Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Numerical Modeling on Non-enzymatic, Potentiometric Glucose Sensor |
title |
Numerical Modeling on Non-enzymatic, Potentiometric Glucose Sensor |
spellingShingle |
Numerical Modeling on Non-enzymatic, Potentiometric Glucose Sensor Kanagasabapathy,M. potentiometric glucose sensors mathematical modeling non-enzymatic glucose sensors |
title_short |
Numerical Modeling on Non-enzymatic, Potentiometric Glucose Sensor |
title_full |
Numerical Modeling on Non-enzymatic, Potentiometric Glucose Sensor |
title_fullStr |
Numerical Modeling on Non-enzymatic, Potentiometric Glucose Sensor |
title_full_unstemmed |
Numerical Modeling on Non-enzymatic, Potentiometric Glucose Sensor |
title_sort |
Numerical Modeling on Non-enzymatic, Potentiometric Glucose Sensor |
author |
Kanagasabapathy,M. |
author_facet |
Kanagasabapathy,M. Ramesh Bapu,G.N.K. Lingac,Praveen Gnanamuthud,R.M. |
author_role |
author |
author2 |
Ramesh Bapu,G.N.K. Lingac,Praveen Gnanamuthud,R.M. |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Kanagasabapathy,M. Ramesh Bapu,G.N.K. Lingac,Praveen Gnanamuthud,R.M. |
dc.subject.por.fl_str_mv |
potentiometric glucose sensors mathematical modeling non-enzymatic glucose sensors |
topic |
potentiometric glucose sensors mathematical modeling non-enzymatic glucose sensors |
description |
A novel, enzymeless electrochemical sensing mechanism for glucose based on potentiometric measurement was proposed using the mediator hexacyanoferrate. In this methodology, EMF of the cell exclusively depends on glucose concentration and independent on reference half-cell electrode potential or mediator concentration or any other interfering factors. Electrochemical as well as mathematical models were proposed. Numerical computations along with boundary conditions were evaluated for the proposed models, to reduce the deviation in the interpolated results. Molar ratio of mediator to glucose was correlated with EMF cell. Numerical simulations, Legendre polynomials and Lagrange coefficients iterations can be executed through computer programs. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-07-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042012000400006 |
url |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042012000400006 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042012000400006 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
dc.source.none.fl_str_mv |
Portugaliae Electrochimica Acta v.30 n.4 2012 reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
|
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1799137290930356224 |